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化学进展 2010, Vol. 22 Issue (12): 2309-2315 前一篇   后一篇

• 综述与评论 •

二维多环全苯芳烃的合成、性能及应用

顾盾寅, 黄美荣, 李新贵   

  1. 同济大学材料学院 先进土木工程材料教育部重点实验室 材料化学研究所 上海 200092
  • 出版日期:2010-12-24 发布日期:2010-11-04
  • 作者简介:e-mail:huangmeirong@tongji.edu.cn
  • 基金资助:

    国家自然科学基金项目(50873077)资助

下载PDF ( 1136 ) 引用
导出 被引次数 ( 6 | 2 )

Synthesis, Properties and Applications of the 2-D Polycyclic all-Benzenoid Aromatic Hydrocarbons

Gu Dunyin, Huang Meirong, Li Xingui   

  1. Institute of Materials Chemistry, Key Laboratory of Advanced Civil Engineering Materials of the Ministry of Education, College of Materials Science and Engineering, Tongji University, Shanghai 200092, China
  • Online:2010-12-24 Published:2010-11-04

二维多环全苯芳香烃(PBAH)具有类似于石墨的结构形态,拥有良好的稳定性,被视作一种理想的导电材料,自问世以来受到了广泛关注。本文详细总结了由树枝形聚苯前驱体平面化而制得PBAH的合成方法, 指出了PBAH的表征难点,阐述了PBAH的多功能性如热致液晶性、导电性以及光学性能,展示了PBAH在电子传输材料、场效应晶体管、光伏电池、发光二极管、二次电池等方面的应用前景。特别指出了带有柔性侧链的PBAH分子可以形成碟状的液晶态,从而呈现有序的超分子结构,在各种PBAH光电材料的应用中占据领先地位。

关键词： 二维多环全苯芳烃, 合成, 液晶性, 导电性

The 2-D polycyclic all-benzenoid aromatic hydrocarbons (PBAH), which are considered as a kind of ideal electric conductive materials because of their graphite-like structures and excellent stability, have attracted considerable intersts since their invention. The syntheses of the PBAH via planarization of the polyphenylene dendrimers are elaborated and the difficulties in the characterization of the PBAH are indicated in this review. Properties of the PBAH are discussed, such as thermotropic liquid crystallinity, electric conductivity and optical characteristics. The applications of the PBAH in the production of electron transport materails, field effect transistors, photovoltaic cells, light emitting diodes and secondary batteries are also presented. In particular, the PBAH bearing flexible side groups has the ability to form an ordered disc supramolecular structure in liquid crystalline state, which makes them lead the way in potential applications as a variety of optoelectric materials.

Contents
1 Introduction
2 Synthesis of PBAH
2.1 Synthesis of the precursor-PD
2.2 Cyclodehydrogenation of PD
3 Mass characterization of PBAH
4 Properties of PBAH
4.1 Thermotropic liquid crystallinity of PBAH[ZK)]
4.2 Optical performances of PBAH
4.3 Transportation of carriers in PBAH
5 Applications of PBAH
5.1 Electron-transporting materials
5.2 FET
5.3 Photovoltaic cell
5.4 LED
5.5 Rechargeable battery
6 Conclusion and outlook

Key words: 2-D polycyclic all-benzenoid aromatic hydrocarbon, synthesis, liquid crystallinity, electronic conductivity

中图分类号: 

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