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化学进展 2010, Vol. 22 Issue (12): 2298-2308 前一篇   后一篇

• 综述与评论 •

贵金属纳米粒子修饰碳纳米管的研究

夏文健1,2, 孟令杰2, 刘丽1, 路庆华2   

  1. 1. 上海大学材料科学与工程学院 上海 20007;
    2. 上海交通大学化学化工学院 上海 200240
  • 出版日期:2010-12-24 发布日期:2010-11-04
  • 作者简介:e-mail:menglingjie@sjtu.edu.cn; liuli@staff.shu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20874059,20904030),国家高技术发展计划(863)项目(No.2009AA03Z329)和上海市重点学科建设项目(B202)资助

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Carbon Nanotubes Decorated with Noble Metal Nanoparticles

Xia Wenjian1,2, Meng Lingjie2, Liu Li1, Lu Qinghua2   

  1. 1. School of Materials Science and Engineering, Shanghai University, Shanghai 20007;
    2. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Online:2010-12-24 Published:2010-11-04

碳纳米管具有独特的一维管状结构和优异的电、光、热和力学性能,是药物和纳米催化剂的理想载体。将具有独特光、电、磁和催化性能的贵金属纳米粒子负载在碳纳米管的表面,形成的碳纳米管/贵金属纳米粒子复合物不仅兼有两种纳米材料的优异性能,还可能产生新的特性,在催化、储能、燃料电池、电子器件和传感器等领域均有广阔的应用前景。本文主要从共价修饰和非共价修饰两种策略出发,综述了贵金属纳米粒子修饰碳纳米管的制备方法和研究进展。其中用天然高分子包覆的碳纳米管表面具有很好的贵金属配位结合能力,得到的纳米复合物具有良好的水分散性和生物相容性,在载药、生物传感器和肿瘤诊断治疗等生物领域具有明显的优势。

关键词： 贵金属纳米粒子(NMNPs), 碳纳米管(CNTs), 共价, 非共价, 天然高分子

One-dimensional carbon nanotubes (CNTs) have a unique tubular structure and excellent electrical, optical, thermal and mechanical properties. Meanwhile, zero-dimensional noble metal nanoparticles (NMNPs) also exhibit unique optical, electrical, magnetic and catalytic properties. Combined these two nano-materials together through supporting metal nanoparticles on the surface of carbon nanotubes, a new kind of nano-hybrid of metal and nonmetal are created,this nano-hybrid can not only possess their intrinsic outstanding performance, but also will give birth to some extraordinary characteristics, significantly having potential applications in the fields of chemical catalysis, hydrogen storage, direct alcohol fuel cells, electronic devices and bio-sensors. In this review, the suggested methods about the decoration of NMNPs on CNTs are generally discussed, primarily including the covalent modification and non-covalent modification. In particular, the techniques about the functionalization of carbon nanotubes with the natural polymer (such as DNA, polypeptides, polysaccharides and DNA) are additionally introduced, and the modified CNTs actually exhibit not only good biocompatibility, but also may effectively facilitate the dispersion of the CNTs in most solvents and improve the amount of NMNPs decorated on nanotubes, therefore, the as-prepared CNTs/NMNPs nano-hybrids have obvious advantages for some biological applications such as drug delivery, bio-sensors, immobilization and separation of proteins and cancer diagnosis or treatment.

Contents
1 Introduction
2 Strategies for modification
2.1 Directly covalent modification of CNTs
2.2 Covalent modification on the functional groups of CNTs
2.3 Non-covalent wrapping of CNTs
3 Research progress of the CNTs/NMNPs nano- hybirds
3.1 In situ precipitation method
3.2 Covalent modification of CNTs
3.3 Non-covalent modification of CNTs
3.4 Natural polymer wrapping CNTs
4 Conclusion

Key words: noble metal nanoparticles (NMNPs), carbon nanotubes (CNTs), covalent, non-covalent, natural polymer

中图分类号: 

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[1] Iijima S. Nature, 1991, 354:56—58

[2] Lijima S, Lchihashi T. Nature, 1993, 363:603—605

[3] Ebbesen T W, Ajayan P M. Nature, 1992, 358 (6383):220—222

[4] Guo T, Nikolaev P, Thess A, Colbert D T, Smalley R E. Chem. Phys. Lett., 1995, 243:49—54

[5] Endo M, Takeuchi K, Igarashi S, Kobori K, Shiraishi M, Kroto H W. J. Phys. Chem. Solids., 1993, 54 (12):1841—1848 6] Baughman R H, Zakhidov A A, Heer W A. Science, 2002, 297 (5582):787—792

[7] Evseeva L E, Tanaeva S A. Mech. Compos. Mater., 2008, 44 (1):87—92

[8] Tans S J, Devoret M H, Dai H J, Thess A, Smalley R E, Geerligs L J, Dekker C. Nature, 1997, 386 (6624):474—477

[9] Meng L J, Fu C L, Lu Q H. Prog. Natur. Sci., 2009, 19:801—810

[10] Nadja C B, Alexander E. Phil. Trans. R. Soc. A, 2010, 368:1385—1404

[11] Kahrama M, Zamaleeva A I, Fakhrullin R F, Culha M. Anal. Bioanal. Chem., 2009, 395:2559—2567

[12] Li L, Xing Y C. J. Phys. Chem. C, 2007, 111:2803—2808

[13] Chu H B, Wang J Y, Ding L, Yuan D N, Zhang Y, Liu J, Li Y. J. Am. Chem. Soc., 2009, 131:14310—14316

[14] Oldenburg S J, Averitt R D, Westcott S L, Halas N J. Chem. Phys. Lett., 1998, 288:243—247

[15] Daniel M C, Astruc D. Chem. Rev., 2004, 104:293—346

[16] Pileni M P. Nat. Mater., 2003, 2 (3):145—150

[17] Sun Y G, Xia Y N. Science, 2002, 298 (5601):2176—2179

[18] Du J M, Han B X, Liu Z M. Cryst. Growth Des., 2007, 7 (5):900—904

[19] Voorhees P W. J. Statist. Phys., 1985, 38 (1/2):231—252

[20] Gutiérrez M C, Hortigüela M J, Amarilla J M, Jiménez R, Ferrer M L, Monte F D. J. Phys. Chem. C, 2007, 111 (15):5557—5560

[21] Kim J W, Galanzha E L, Shashkov E V, Moon H M, Zharov V P. Nat. Nanotech., 2009, 4:688—694

[22] Zheng L F, Li S D, Burke P J. Proc. SPIE, 2004, 5515:117—124

[23] Banerjee S, Benny T H, Wong S S. Adv. Mater., 2005, 17 (1):17—29

[24] Shi J, Wang Z, Li H L. J. Nanoparticle Research, 2006, 8:743—747

[25] Fischer J E. Acc. Chem. Res., 2002, 35:1079—1086

[26] Planeix J M, Coustel N, Coq B, Brotons V, Kumbhar P S, Dutartre R, Geneste P, Bernier P, Ajayan P M. J. Am. Chem. Soc., 1996, 116:7935—7936

[27] Kim D S, Lee T, Geckeler K E. Angew. Chem. Int. Ed., 2006, 45:104—107

[28] Zanella R, Basiuk E V, Santiago P, Basiuk V A, Mireles E, Lee I P, Saniger J M. J. Phys. Chem. B, 2005, 109:16290—16295

[29] Balasubramanian K, Burghard M. Small, 2005, 1 (2):180—192

[30] Zhang D S, Shi L Y, Fang J H. Mater. Lett., 2005, 59 (29):4044—4047

[31] Yu J G, Huang K L, Liu S Q. Chinese Journal of Chemistry, 2008, 26 (3):560—563

[32] Vogel S R, Muller K, Plutowski U. Phy. Status Solid B, 2007, 244 (11):4026—4029

[33] Fullam S, Cottell D, Rensmo H, Fitzmaurice D. Adv. Mater., 2000, 12 (19):1430—1432

[34] Planeix J M, Coustel N, Coq B, Brotons V, Kumbhar P S, Dutartre R, Geneste P, Bernier P, Ajayan P M. J. Am. Chem. Soc., 1994, 116:7935—7936

[35] Chetty R, Kundu S, Xia W, Bron M, Schuhmann W, Chirila V, Brandi W, Reinecke T, Muhler M. Electrochimica Acta, 2009, 54:4208—4215

[36] Suarez-Martinez I, Bittencourt C, Ke X, Felten A, Pireaux J J, Chihsen J, Drube W, Tendeloo G V, Ewels C P. Carbon, 2009, 47:1549—1554

[37] Yu R Q, Chen L W, Liu Q P, Lin J Y, Tan K L, Ng S C, Chan H S O, Xu G Q, Hor T S A. Chem. Mater., 1998, 10 (3):718—722

[38] Li W Z, Liang C H, Zhou W J. Carbon, 2004, 42 (2):436—439

[39] Kim D S, Lee T, Geckeler K E. Angew. Chem. Int. Ed., 2006, 45:104—107

[40] Choi H C, Shim M, Bangsaruntip S, Dai H J. J. Am. Chem. Soc., 2002, 124:9058—9059

[41] Wang J S, Pan H B, Chien M. J. Nanosci. Nanotech., 2006, 6 (7):2025—2030

[42] Sun Z Y, Liu Z M, Han B X, Miao S D, Miao Z J, An G M. J. Col. Inter. Sci., 2006, 304:323—328

[43] Fási A, Pálinkó I, Seo J W, Kónya Z, Hernadi K, Kiricsi I. Chem. Phy. Lett., 2003, 272:848—852

[44] Satishkumar B C, Vogl E M, Govindaraj A, Rao C N R. J. Phys. D: Appl. Phys., 1996, 29:3173—3176

[45] Raghuveer M S, Agrawal S, Bishop N, Ramannath G. Chem. Mater., 2006, 18 (6):1390—1393

[46] Liu J, Rinzler A G, Dai H, Hafner J H, Bradley R K, Boul P J, Lu A, Iverson T, Shelimov K, Huffman C B, Macias F R, Shon Y S, Lee T R, Colbert D T, Smalley R E. Science, 280 (5367):1253—1256

[47] Niyogi S, Hamon M A, Hu H, Zhao B, Bhowmik P, Sen R, Itkis M E, Haddon R C. Acc. Chem. Res., 2002, 35 (12):1105—1113

[48] Chiu P W, Duesberg G S, Dettlaff U, Roth S. Appl. Phys. Lett., 2002, 80 (20):811—3813

[49] Banerjee S, Wong S S. Nano Lett., 2002, 2 (3):195—200

[50] Zanella R, Basiuk E V, Santiago P, Basiuk V A, Mireles E, Lee I P, Saniger J M. J. Phys. Chem. B, 2005, 109:16290—16295

[51] Basiuk E V, Basiuk V A, Baňuelos J G, Saniger J M, Pokrovskiy V A, Gromovoy T Y, Mischanchuk A V, Mischanchuk B G. J. Phys. Chem. B, 2002, 106 (7):588—1597

[52] Kim K S, Demberelnyamba D, Lee H. Langmuir, 2004, 20:556—560

[53] Wang Z, Zhang Q, Kuehner D, Xu X, Ivaska A, Niu L. Carbon, 2008, 46 (13):1687—1692

[54] Gao C, Vo C D, Jin Y Z, Li W W, Armes S P. Macromolecules, 2005, 38 (21):8634—8648

[55] Reddy K R, Sin B C, Ryu K S, Kim J C, Chung H, Lee Y. Synthetic Metals, 2009, 159:595—603

[56] Lou X D, Daussin R, Cuenot S, Duwez A, Pagnoulle C, Detrembleur C, Bailly C, Jérǒme R. Chem. Mater., 2004, 16:4005—4011

[57] Chen R J, Zhang Y G, Wang D W, Dai H J. J. Am. Chem. Soc., 2001, 123 (16):3838—3839

[58] Wei G, Pan C J, Reichert J, Jandt K D. Carbon, 2010, 48:645—653

[59] Yeh J M, Huang K Y, Lin S Y, Wu Y Y, Huang C C, Liou S J. J. Nanotechnology, 2009, 2009 art. no. 217469

[60] Liu L Q, Wang T X, Li J X, Guo Z X, Dai L M, Zhang D Q, Zhu D B. Chem. Phy. Lett., 2003, 367:747—752

[61] Guldi D M, Rahman G M A, Jux N, et al. Angewandte Chemie-International Edition, 2004, 43 (41):5526—5530

[62] Lou X D, Daussin R, Cuenot S, Duwez A, Pagnoulle C, Detrembleur C, Bailly C, Jérǒme R. Chem. Mater., 2004, 16:4005—4011

[63] Ou Y Y, Huang M H. J. Phys. Chem. B, 2006, 110 (5):2031—2036

[64] Georgakilas V, Tzitzios V, Gournis D, Petridis D. Chem. Mater., 2005, 17 (7):1613—1617

[65] Yang Z, Chen X H, Chen C S, Li W H, Zhang H, Xu L S, Yi B. Polymer Composites, 2007:36—41

[66] Chen S H, Yuan R, Chai Y Q, Zhang L Y, Wang N, Li X L. Biosensors and Bioelectronics, 2007, 22 :1268—1274

[67] Wu B H, Hu D, Kuang Y J, Liu B, Zhang X H, Chen J H. Angew. Chem. Int. Ed., 2009, 48:4751—4754

[68] Jiang K Y, Eitan A, Schadler L S, Ajayan P M, Siegel R W. Nano Lett., 2003, 3 (3):275—277

[69] Kim B, Sigmurd W M. Langmuir, 2004, 20 (19):8239—8242

[70] Zhang M N, Su L, Mao L Q. Carbon, 2006, 44:276—283

[71] Liu Y, Jiang W, Li S, Li F S. App. Sur. Sci., 2009, 255:7999—8002

[72] Jiang L Q, Gao L. Carbon, 2003, 41:2923—2929

[73] Ragupathy D, Gopalan A I, Lee K P. Electrochem. Commun., 2009, 11:397—401

[74] Huang H Z, Yang X R. Coll. surf. A: Physicochem. Eng. Aspects, 2003, 226:77—86

[75] Ellis A V, Vijayamohanan K, Goswami R, Chakrapani N, Ramanathan L S, Ajayan P M, Ramanath G. Nano Lett., 2003, 3 (3):279—282

[76] Wang D, Li Z C, Chen L W. J. Am. Chem. Soc., 2006, 128:15078—15079

[77] Han L, Wu W, Kirk F L, Luo J, Maye M M, Kariuki N N, Lin Y H, Wang C M, Zhong C J. Langmuir, 2004, 20 (14):6019—6025

[78] Numata M, Asai M, Kaneko K J, Bae A H, Hasegawa T, Sakurao K, Shinkai S. J. Am. Chem. Soc., 2005, 127 (16):5875—5884

[79] Li H Y, Park S H, Relf J H, LaBean T H, Yan H. J. Am. Chem. Soc., 2004, 126 (2):418—419

[80] Sharma J, Chhabra R, Cheng A, Brownell J, Liu Y, Yan H. Science, 2009, 323 (112):112—116

[81] Zheng M, Jagota A, Strano M S, Santos A P, Barone P, Chou S G, Diner B A, Dresselhaus M S, Mclean R S, Onoa B, Samsonidze G G, Semke E D, Usrey M, Walls D J. Science, 2003, 302 (5650):1545—1548

[82] Liu Z, Winters M, Holodniy M, Dai H J. Angew. Chem. Int. Ed., 2007, 46:2023—2027

[83] Ostojic G N, Ireland J R, Hersam M C. Langmuir, 2008, 24:9784—9789

[84] Chen Y, Liu H P, Ye T, Kim J, Mao C D. J. Am. Chem. Soc., 2007, 129:8696—8697

[85] Li B, Li L Y, Wang B B, Li C Y. Nat. Nanotech., 2009, 4:358—362

[86] Karajanagi S S, Yan H C, Asuri P, Sellitto E, Dordick J S, Kane R S. Langmuir, 2006, 22 (4):1392—1395

[87] Poenitzsch V Z, Winters D C, Hui X, Dieckmann G R, Dalton A B, Musselman I H. J. Am. Chem. Soc., 2007, 129 (47):14724—14732

[88] Kumar N A, Bund A, Cho B G, Lim K T, Jeong Y T. Nanotechnology, 2009, 20 art. no. 225608

[89] Kim O K, Je J, Baldwin J W, Kooi S, Pehrsson P E, Buckley L J. J. Am. Chem. Soc., 2003, 125 (15):4426—4427

[90] Fu C L, Meng L J, Lu Q H, Zhang X K, Gao C. Macromol. Rapid Commun., 2007, 28:2180—2184

[91] Jiang H J, Zhao Y, Yang H, Akins D L. Mater. Chem. Phys., 2009, 114:879—883

[92] Zhang X K, Meng L J, Lu Q H. ACS Nano, 2009, 3 (10):3200—3206
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