English
往期目录
新闻公告
More
化学进展 2010, Vol. 22 Issue (12): 2268-2275 前一篇   后一篇

• 综述与评论 •

含氧有机物作为锂电池正极材料

赵磊1, 王维坤2, 王安邦2, 余仲宝2, 陈实1, 杨裕生1,2   

  1. 1. 北京理工大学化工与环境学院 北京 100081;
    2. 防化研究院军用化学电源研究与发展中心 北京 100191
  • 出版日期:2010-12-24 发布日期:2010-11-04
  • 作者简介:e-mail:wangweikun2002@163.com
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2009CB220100)资助

下载PDF ( 1322 ) 引用
导出 被引次数 ( 28 | 2 )

Oxocarbon Organic Compound Cathode Materials for Lithium Secondary Batteries

Zhao Lei1, Wang Weikun2, Wang Anbang2, Yu Zhongbao2, Chen Shi1, Yang Yusheng1,2   

  1. 1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081;
    2. Military Power Sources Research and Development Center, Research Institute of Chemical Defense, Beijing 100191, China
  • Online:2010-12-24 Published:2010-11-04

有机物作为锂电池正极材料具有理论比容量高、原料丰富、环境友好、体系安全的优点,近年来受到关注。本文综述了含氧有机物正极材料的研究进展,概括了醌类、酸酐和硝基化合物等材料的结构特征、电化学性能以及充放电机理,比较了各种材料的优势与不足,并对比了不同有机物材料的放电电位和比容量,同时对该类材料的研究方向进行了展望。

关键词： 锂二次电池, 正极材料, 含氧有机物, 醌类聚合物

The organic compounds as the cathode materials of lithium secondary batteries have attracted wide attention because of their high specific capacity, abundant resources, environmental friendliness and safe system in recent years. The progress in oxocarbon organic cathode materials, including quinines, acid anhydride, nitrocompound, etc. is summarized. Their structures, electrochemical properties and the discharge and charge mechanism are introduced. Meanwhile, their advantages and disadvantages are discussed. The discharge potential and specific capacity of organic cathode materials are also compared. Finally, the future research focuse for the oxocarbon organic cathode materials are proposed.

Contents
1 Introduction
2 Small molecular quinone compound
3 Quinone polymer
4 Other oxocarbon organic compound
5 Outlook

Key words: lithium secondary batteries, cathode materials, oxocarbon organic compounds, quinone polymers

中图分类号: 

()


[1] Chen H, Armand M, Demailly G, Dolhem F, Poizot P, Tarascon J M. Chemsuschem, 2008, 1(4): 348—355

[2] Nigrey P J, Macinnes D, Nairns D P, Macdiarmid A G, Heeger A J. Journal of the Electrochemical Society, 1981, 128(8): 1651—1654

[3] Kaufman J H, Chung T C, Heeger A J, Wudl F. Journal of the Electrochemical Society, 1984, 131(9): 2092—2093

[4] 任丽(Ren L), 成国祥(Cheng G X), 朱嫦娥(Zhu C E), 王立新(Wang L X). 高分子材料科学与工程(Polymer Materials Science and Engineering), 2006, (1): 222—225

[5] Kang S G, Kim K M, Park N G, Ryu K S, Chang S H. Journal of Power Sources, 2004, 133(2): 263—267

[6] Lira-Cantu M, Gomez-Romero P. Journal of the Electrochemical Society, 1999, 146(6): 2029—2033

[7] Fedorkova A, Wiemhofer H D, Orinakova R, Orinak A, Stan M C, Winter M, Kaniansky D, Alejos A N. Journal of Solid State Electrochemistry, 2009, 13(12): 1867—1872

[8] Novak P, Muller K, Santhanam K S V, Haas O. Chemical Reviews, 1997, 97(1): 207—282

[9] Desilvestro J, Scheifele W, Haas O. Journal of the Electrochemical Society, 1992, 139(10): 2727—2736

[10] Ren X M, Pickup P G. J. Phys. Chem., 1993, 97(20): 5356—5362

[11] Pope J M, Sato T, Shoji E, Oyama N, White K C, Buttry D A. Journal of the Electrochemical Society, 2002, 149(7): A939—A952

[12] Tatsuma T, Matsui H, Shouji E, Oyama N. The Journal of Physical Chemistry, 1996, 100(33): 14016—14021

[13] Oyama N, Hatozaki O. Macromolecular Symposia, 2000, 156(1): 171—178

[14] 徐国祥(Xu G X), 其鲁(Qi L), 闻雷(Wen L). 电池(Battery Bimonthly), 2005, (3): 178—179

[15] 杨裕生(Yang Y S), 王维坤(Wang W K), 苑克国(Yuan K G), 曹高萍(Cao G P), 王安邦(Wang A B). 电池(Battery Bimonthly), 2002, (S1): 1—5

[16] Wang W K, Wang A B, Cao G P, Yang Y S. Acta Phys. Chim. Sin., 2004, 20(12): 1440—1444

[17] 王维坤(Wang W K), 王安邦(Wang A B), 曹高萍(Cao G P), 杨裕生(Yang Y S). 物理化学学报(Acta Physico-Chimica Sinica), 2004, (12): 1440—1444

[18] 王维坤(Wang W K), 王安邦(Wang A B), 曹高萍(Cao G P), 杨裕生(Yang Y S). 应用化学(Chinese Journal of Applied Chemistry), 2005, (4): 367—371

[19] 王维坤(Wang W K), 王安邦(Wang A B), 曹高萍(Cao G P), 杨裕生(Yang Y S). 高等学校化学学报(Chemical Journal of Chinese Universities), 2005, (5): 918—920

[20] 苑克国(Yuan K G), 王安邦(Wang A B), 曹高萍(Cao G P), 杨裕生(Yang Y S). 高等学校化学学报(Chemical Journal of Chinese Universities), 2005, (11): 2117—2121

[21] 李晓林(Li X L), 李琰(Li Y), 王维坤(Wang W K), 余仲宝(Yu Z B), 王安邦(Wang A B). 北京化工大学学报(自然科学版)(Journal of Beijing University of Chemical Technology(Natural Science Edition)), 2007, (4): 401—404

[22] Jeftic L, Manning G. Journal of Electroanalytical Chemistry, 1970, 26(2/3): 195—200

[23] Boschi T, Pappa R, Pistoia G, Tocci M. Journal of Electroanalytical Chemistry, 1984, 176(1/2): 235—242

[24] Pasquali M, Pistoia G, Boschi T, Tagliatesta P. Solid State Ionics, 1987, 23(4): 261—266

[25] Seo E T, Nelson R F, Fritsch J M, Marcoux L S, Leedy D W, Adams R N. J. Am. Chem. Soc., 1966, 88(15): 3498—3503

[26] Jeftic L, Adams R N. J. Am. Chem. Soc., 1970, 92(5): 1332—1337

[27] Kuder J E, Pochan J M, Turner S R, Hinman D F. Journal of the Electrochemical Society, 1978, 125(11): 1750—1758

[28] Alt H, Binder H, Kohling A, Sandstede G. Electrochimica Acta, 1972, 17(5): 873—887

[29] Forkner M W, Miller L L, Rak S F. Synthetic Metals, 1990, 36(1): 65—73

[30] West R, Powell D L. J. Am. Chem. Soc., 1963, 85(17): 2577—2579

[31] Ravet N, Michot C, Armand M. Materials Research Society Symposia Proceedings, 1998, 496: 263—273

[32] Armand M, Tarascon J M. Nature, 2008, 451(7179): 652—657

[33] Chen H Y, Armand M, Courty M, Jiang M, Grey C P, Dolhem F, Tarascon J M, Poizot P. J. Am. Chem. Soc., 2009, 131(25): 8984—8988

[34] Chen H Y, Poizot P, Dolhem F, Basir N I, Mentre O, Tarascon J M. Electrochem. Solid State Lett., 2009, 12(5): A102—A106

[35] 王维坤(Wang W K), 张勇勇(Zhang Y Y), 王安邦(Wang A B), 余仲宝(Yu Z B), 韩敏芳(Han M F), 杨裕生(Yang Y S). 物理化学学报(Acta Physico-Chimica Sinica), 2010, 26(1): 47—50

[36] 张勇勇(Zhang Y Y), 王维坤(Wang W K), 王安邦(Wang A B), 余仲宝(Yu Z B), 韩敏芳(Han M F). 15届全国电化学会议(长春)(15th National Conference on Electrochemistry(Changchun)), 2009: B—P33

[37] Gall T L, Reiman K H, Grossel M C, Owen J R. Journal of Power Sources, 2003, 119: 316—320

[38] Pham M C, Piro B, Bazzaoui E A, Hedayatullah M, Lacroix J C, Novák P, Haas O. Synthetic Metals, 1998, 92(3): 197—205

[39] Haringer D, Novak P, Haas O, Piro B, Pham M C. Journal of the Electrochemical Society, 1999, 146(7): 2393—2396

[40] 唐致远(Tang Z Y), 徐国祥(Xu G X). 物理化学学报(Acta Physico-Chimica Sinica), 2003, (4): 307—310

[41] 徐国祥(Xu G X), 其鲁(Qi L), 闻雷(Wen L), 刘国强(Liu G Q), 慈云祥(Ci Y X). 高分子学报(Acta Polymerica Sinica), 2006, (6): 795—799

[42] Song Z P, Zhan H, Zhou Y H. Chem. Commun., 2009, (4): 448—450

[43] 刘凯(Liu K), 郑建明(Zheng J M), 钟贵明(Zhong G M), 杨勇(Yang Y). 电化学(Electrochemistry), 2009, (3): 245—249

[44] Xiang J F, Chang C X, Li M, Wu S M, Yuan L J, Sun J T. Crystal Growth & Design, 2008, 8(1): 280—282

[45] Ohzuku T, Wakamatsu H, Takehara Z, Yoshizawa S. Electrochimica Acta, 1979, 24(6): 723—726

[46] Williams D L, Byrne J J, Driscoll J S. Journal of the Electrochemical Society, 1969, 116(1): 2—4

[47] Tobishima S, Yamaki J, Yamaji A. Journal of the Electrochemical Society, 1984, 131(1): 57—63

[48] 崔月芝(Cui Y Z), 华寿南(Hua S N). 山东师大学报(自然科学版)(Journal of Shandong Normal University(Natural Science)), 2000, 15(2): 157—161

[49] Han X Y, Chang C X, Yuan L J, Sun T L, Sun J T. Advanced Materials, 2007, 19(12): 1616—1621

[50] 邓凌峰(Deng L F), 李新海(Li X H), 肖立新(Xiao L X), 张云河(Zhang Y H). 高分子学报(Acta Polymerica Sinica), 2004, (1): 8—12
[1] 李婧婧, 李洪基, 黄强, 陈哲. 掺杂对钠离子电池正极材料性能影响机制的研究[J]. 化学进展, 2022, 34(4): 857-869.
[2] 冯小琼, 马云龙, 宁红, 张世英, 安长胜, 李劲风. 铝离子电池中过渡金属硫族化合物正极材料[J]. 化学进展, 2022, 34(2): 319-327.
[3] 蔡克迪, 严爽, 徐天野, 郎笑石, 王振华. 锂离子电容电池关键电极材料[J]. 化学进展, 2021, 33(8): 1404-1413.
[4] 李文涛, 钟海, 麦耀华. 锂二次电池中的原位聚合电解质[J]. 化学进展, 2021, 33(6): 988-997.
[5] 周世昊, 吴贤文, 向延鸿, 朱岭, 刘志雄, 赵才贤. 水系锌离子电池锰基正极材料[J]. 化学进展, 2021, 33(4): 649-669.
[6] 刘建文, 姜贺阳, 孙驰航, 骆文彬, 毛景, 代克化. P2结构层状复合金属氧化物钠离子电池正极材料[J]. 化学进展, 2020, 32(6): 803-816.
[7] 王官格, 张华宁, 吴彤, 刘博睿, 黄擎, 苏岳锋. 废旧锂离子电池正极材料资源化回收与再生[J]. 化学进展, 2020, 32(12): 2064-2074.
[8] 鲁志远, 刘燕妮, 廖世军. 锂离子电池富锂锰基层状正极材料的稳定性[J]. 化学进展, 2020, 32(10): 1504-1514.
[9] 刘燕晨, 黄斌, 邵奕嘉, 沈牧原, 杜丽, 廖世军. 钾离子电池及其最新研究进展[J]. 化学进展, 2019, 31(9): 1329-1340.
[10] 邵奕嘉, 黄斌, 刘全兵, 廖世军. 三元镍钴锰正极材料的制备及改性[J]. 化学进展, 2018, 30(4): 410-419.
[11] 杨蓉, 李兰, 任冰, 陈丹, 陈利萍, 燕映霖. 锂硫电池中的石墨烯掺杂[J]. 化学进展, 2018, 30(11): 1681-1691.
[12] 张松涛, 郑明波, 曹洁明, 庞欢. 锂硫电池用多孔碳/硫复合正极材料的研究[J]. 化学进展, 2016, 28(8): 1148-1155.
[13] 易罗财, 次素琴, 孙成丽, 温珍海. 非水系锂氧气电池正极材料研究现状[J]. 化学进展, 2016, 28(8): 1251-1264.
[14] 陈军, 丁能文, 李之峰, 张骞, 钟盛文. 锂离子电池有机正极材料[J]. 化学进展, 2015, 27(9): 1291-1301.
[15] 蔡克迪, 赵雪, 仝钰进, 肖尧, 高勇, 王诚. 锂氧电池关键技术研究[J]. 化学进展, 2015, 27(12): 1722-1731.
阅读次数
全文


摘要

含氧有机物作为锂电池正极材料