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化学进展 2010, Vol. 22 Issue (11): 2248-2253 前一篇   

• 综述与评论 •

柔性染料敏化太阳能电池*

兰章**  吴季怀   

  1. (华侨大学材料物理化学研究所 泉州362021)
  • 收稿日期:2010-02-24 修回日期:2010-05-21 出版日期:2010-11-24 发布日期:2010-10-20
  • 通讯作者: 兰章 E-mail:lanzhang@hqu.edu.cn
  • 基金资助:

    国家高技术发展计划；国家自然科学基金；华侨大学科研启动基金

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Recent Progress in Flexible Dye-Sensitized Solar Cells

Lan Zhang** Wu Jihuai   

  1. (Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou 362021, China)
  • Received:2010-02-24 Revised:2010-05-21 Online:2010-11-24 Published:2010-10-20
  • Contact: Lan Zhang E-mail:lanzhang@hqu.edu.cn

本文介绍了染料敏化太阳能电池的工作原理，对其重要研究方向——柔性染料敏化太阳能电池的关键组成部分：光阳极、对电极和电解质等的国内外研究进展进行了评述，分析当前研究过程中存在的问题，并提出提高柔性染料敏化太阳能电池光电转换效率和长期稳定性的对策，对其未来的发展进行了展望.

关键词： 染料敏化太阳能电池, 柔性, 聚合物基板, 金属基板, 电解质

Although the highest energy conversion efficiency about 11 % of dye-sensitized solar cell (DSSC) based on the transparent oxide conductive glass (TCO) has been obtained, the heavy, rigid, and expensive TCO substrate need to be substituted with flexible materials such as plastic or metal substrates in order to both decrease the production costs and enlarge the application range. The key problem with plastic substrates is their low temperature tolerance, so some novel fabricating methods need to be developed to enhance the quality of flexible photo electrodes. Whereas with metal substrates, the above problem is not existed due to the high temperature tolerance of them, while a few kinds of metals such as stainless steel, titanium are suitable for substrates owing to the corrosion of iodine-containing electrolyte typically used in DSSC. The key problem for fabricating flexible DSSC with metal substrate photo electrodes is to fabricate the high transparent counter electrodes and use some kinds of low light absorption electrolytes. Taking these accounts in mind, researchers have obtained some significant progresses. Another important research challenge on flexible DSSC is to improve the long-term stability of the cells to suit for consumer applications. Some kinds of quasi or all solid state electrolytes have been used in TCO based DSSC and show excellent long-term stability, if they can be transferred to the flexible DSSC successfully, the problem can be solved.

Contents
1 Introduction
2 Flexible photo electrode
3 Flexible counter electrode
4 Electrolyte
5 Conclusions and outlook

Key words: dye-sensitized solar cell, flexible, plastic substrate, Metal substrate, electrolyte

中图分类号: 

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摘要

柔性染料敏化太阳能电池*