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蜂窝状有序膜功能化研究进展*
- 金晶 万灵书** 柯蓓蓓 徐志康
作者信息
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Functionlization of Honeycomb-Patterned Films
- Jin Jing Wan Ling-Shu** Ke Beibei Xu ZhiKang
Author information
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文章历史
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摘要
水滴模板法是近年来引人瞩目的一种制备有序微结构材料的方法，所制备的蜂窝状有序膜在微容器和微反应器、图案化模板、细胞培养支架、光学材料、超疏水表面、分离膜等领域具有十分重要的应用前景。本文对蜂窝状有序膜功能化研究的最新进展进行了系统总结，详细介绍和分析了原位多层次自组装、表面接枝、生物活性分子固定、交联、模板法成膜以及表面填充等蜂窝状有序膜的功能化方法。
Abstract
Honeycomb-patterned films by breath figure method have received considerable interest in recent years. This method is based on evaporative cooling and subsequent water-droplet templating to form an ordered array of breath figures, which has many advantages, for example, it is simple and cost-saving, and no extra steps are needed to remove the water templates. This review comprehensively summarizes the advances in the functionalization of honeycomb-patterned films. A series of methods are highlighted, which include hierarchical self-assembly, controlled surface grafting, immobilization of bioactive molecules, ultraviolet-induced and chemical crosslinking, template-guided film formation, and surface filling. The functionalized honeycomb-patterned films have been found great potential applications in various fields, such as microreactor, picoliter beaker, template, cell culture media, separation membrane, superhydrophobic surface, refractive-index materials, and photovoltaic materials.
Contents
1 Introduction
2 Functionalization methods for honeycomb-patterned films
2.1 In-situ hierarchical self-assembly
2.2 Controlled surface grafting
2.3 Immobilization of bioactive molecules
2.4 Ultraviolet-induced and chemical crosslinking
2.5 Template-guided film formation
2.6 Surface filling
2.7 Other methods
3 Conclusion and outlook
关键词
蜂窝状有序膜 / 水滴模板法 / 功能化 / 自组装 {{custom_keyword}} /
Key words
honeycomb-patterned films / breath figure method / funtionalization / self-assembly {{custom_keyword}} /
中图分类号：
O631
TB324
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脚注
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基金
国家杰出青年基金;国家杰出青年科学基金
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