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化学进展 2010, Vol. 22 Issue (11): 2165-2172 前一篇   后一篇

• 综述与评论 •

多糖基分子印迹功能材料*

王红飞  张黎明**   

  1. (中山大学化学与化学工程学院 广州510275)
  • 收稿日期:2010-02-24 修回日期:2010-04-30 出版日期:2010-11-24 发布日期:2010-10-20
  • 通讯作者: 张黎明 E-mail:cedc61@zsu.edu.cn; ceszhlm@mail.sysu.edu.cn
  • 基金资助:

    国家自然科学基金；教育部高等学校博士点基金

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Molecularly Imprinted Functional Materials Based on Polysaccharides

Wang Hongfei  Zhang Liming**   

  1. (School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China)
  • Received:2010-02-24 Revised:2010-04-30 Online:2010-11-24 Published:2010-10-20
  • Contact: Zhang Liming E-mail:cedc61@zsu.edu.cn; ceszhlm@mail.sysu.edu.cn

多糖基分子印迹功能材料因具原料来源广泛、生物相容性和生物降解性好等优点，近年来引起国内外广泛关注。本文综述了利用环糊精、壳聚糖、纤维素、海藻酸、琼脂、淀粉等天然多糖制备分子印迹功能材料的主要方法，包括直接交联法、接枝共聚交联法和溶胶-凝胶技术，评述了其在分离、生物传感、药物传输、蛋白质复性等方面的应用，并对其未来的发展进行了展望。

关键词： 多糖, 分子印迹, 功能材料

In recent years, molecularly imprinted materials (MIMs) based on polysaccharides have attracted great attention due to their abundant raw materials, good biodegradability and biocompatibility. In this paper, the preparation methods of MIMs based on natural polysaccharides such as cyclodextrin, chitosan, cellulose, alginic acid, agarose and starch are reviewed, including direct crosslinking, graft-copolymerization crosslinking and sol-gel technique. Their applications in separation, solid phase extraction, biosensing, drug delivery and protein refolding are discussed. In addition, the development trend of polysaccharide-based MIMs is prospected.

Contents
1 Introduction
2 Preparation methods of MIMs
2.1 Direct crosslinking
2.2 Graft-copolymerization crosslinking
2.3 Sol-gel technique
3 Applications of MIMs
3.1 Metal ion separation
3.2 Chiral separation
3.3 Peptide and protein separation
3.4 Solid phase extraction
3.5 Biosensing
3.6 Drug delivery
3.7 Protein refolding
4 Prospect

Key words: polysaccharides, molecular imprinting, functional materials

中图分类号: 

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摘要

多糖基分子印迹功能材料*