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化学进展 2010, Vol. 22 Issue (11): 2106-2118 前一篇   后一篇

• 综述与评论 •

石墨烯基无机纳米复合材料*

柏嵩  沈小平**   

  1. （江苏大学化学化工学院 镇江212013）
  • 收稿日期:2010-03-03 修回日期:2010-04-26 出版日期:2010-11-24 发布日期:2010-10-20
  • 通讯作者: 沈小平 E-mail:xiaopingshen@163.com
  • 基金资助:

    江苏省自然科学基金；江苏大学高级人才基金

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Graphene-based Inorganic Nanocomposites

Bai Song  Shen Xiaoping**   

  1. (School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212003, China)
  • Received:2010-03-03 Revised:2010-04-26 Online:2010-11-24 Published:2010-10-20
  • Contact: Shen Xiaoping E-mail:xiaopingshen@163.com

石墨烯(graphene)是近年被发现和合成的一种新型二维平面纳米碳质材料。由于其新奇的物理和化学性质，石墨烯已经成为了备受瞩目的科学新星，是纳米材料领域的一大研究热点。在石墨烯的研究中，基于石墨烯的无机纳米复合材料是石墨烯迈向实际应用的一个重要方向。本文在简要介绍石墨烯的结构、性质和制备方法的基础上，重点就近年来以石墨烯为基体的无机物（主要包括金属和半导体）纳米复合材料的合成和应用作一述评，并对石墨烯基无机纳米复合材料的研究和发展方向作了展望。

关键词： 石墨烯, 纳米复合材料, 金属, 半导体, 合成

In past few years, we have witnessed the discovery and synthesis of graphene — a kind of ideal two-dimensional flat carbon nanomaterials. Owing to its novel and unique physical and chemical properties, graphene has been attracting more and more attention from scientific community and nowadays has become a sparkling rising star on the horizon of nanomaterials science. The graphene-based inorganic nanocomposites, derived from the decoration of graphene sheets with inorganic nanoparticles, are emerging as a new class of exciting materials that hold promise for many applications. So far, numerous inorganic nanocomposites based on graphene have been successfully synthesized and show desirable combinations of these properties that are not found in the individual components. Herein, we briefly introduce the structure, properties and preparation methods of graphene, and then highlight the advance in the synthesis of inorganic nanomaterials/graphene composites, especially focusing on the metal/graphene and semiconductor/graphene nanocomposites. The potential applications of these nanocomposites are also discussed. These results underscore the exciting opportunities of developing next-generation graphene-based inorganic nanocomposites.

Contents
1 Introduction
2 Preparation of graphene
3 Metal/graphene nanocomposites
3.1 Composites of graphene sheets and platinum metals
3.2 Composites of graphene sheets and silver
3.3 Composites of graphene sheets and gold
3.4 Composites of graphene sheets and other metal
4 Semiconductor/graphene nanocomposites
4.1 Composites of graphene sheets and titanium dioxide
4.2 Composites of graphene sheets and cobalt oxide
4.3 Composites of graphene sheets and tin oxide
4.4 Composites of graphene sheets and zinc oxide
4.5 Composites of graphene sheets and sulfide semiconductor
4.6 Composites of graphene sheets and other semiconductor
5 Graphene/ceramic nanocomposites
6 Graphene-based magnetic nanocomposites
7 Carbon/graphene nanocomposites
8 Conclusions and outlook

Key words: graphene, nanocomposite, metals, semiconductor, synthesis

中图分类号: 

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摘要

石墨烯基无机纳米复合材料*