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化学进展 2010, Vol. 22 Issue (11): 2089-2098 前一篇   后一篇

所属专题： 金属有机框架材料

• 综述与评论 •

MOF基上创立活性位的方法及其催化应用*

刘丽丽   张鑫**  徐春明**   

  1. (中国石油大学 重质油国家重点实验室  北京  102249)
  • 收稿日期:2010-03-22 修回日期:2010-05-11 出版日期:2010-11-24 发布日期:2010-10-20
  • 通讯作者: 张鑫 E-mail:zhangxin@cup.edu.cn
  • 基金资助:

    国家自然科学基金；新世纪优秀人才支持计划

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Methods of Creating Active sites in MOF and Catalytic Explorations

liu lili   zhang Xin**   Xu Chunming**   

  1. （State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing Changping, 102249）
  • Received:2010-03-22 Revised:2010-05-11 Online:2010-11-24 Published:2010-10-20
  • Contact: zhang Xin E-mail:zhangxin@cup.edu.cn

近年来金属有机骨架（MOF）以其独特的结构特点（高比表面积、织构性质可调以及暴露的金属离子可以100%利用）引起了催化学者的极大重视，本文评述了与传统催化材料（如分子筛）相比，金属有机骨架作为催化材料的优点与不足，针对多数MOF中处于节点的金属离子被配体配位饱和而不具备催化活性这一弊端，本文基于对这一问题的最新研究进展总结了在MOF上创立催化活性位的4种方法：即前合成法、后合成共价修饰法、浸渍法以及沉淀法，讨论了这4种方法各自的优缺点，并详细介绍了这些方法在催化反应中的探索和应用，指出了MOF在催化领域需要重视的问题和未来的研究方向，以期对MOF在催化领域的研究和开发提供参考。

关键词： 金属有机骨架, 活性位, 催化, 催化反应

Due to its unique structural characteristics (the high specific surface area, tailoring structure properties and 100% utilization of exposed metal ions), metal organic framework (MOF) materials have drawn great attention on catalysis in recent years. However, the drawbacks of no open metal ions and poor thermal stability limit their application in catalysis. This tutorial review presents recent developments of the emerging field of MOF based catalysis. We summarize four distinct strategies: pre-synthesis method, post-synthesis modification, impregnation method and precipitation method, which have been utilized to create catalytic active sites in MOF. Examples of the catalytic reactions based on the created active sites in the MOF are then followed. It has been shown that the pre-synthesis method has been widely used in creating catalytic active sites in the MOF. MOF with active sites created by the pre-synthesis and the post-synthesis modification method in the MOF may act as “shape selective catalysis” as zeolite. Usually as a Lewis acid catalyst, MOFs are capable of being very active for many reactions, especially at temperatures below 100 oC. A critical comment on these methods and catalytic explorations has been addressed in order to guide the newcomer to this field.

 Contents
1 Introduction
2 The method of creating active sites in MOF and its application in catalysis
2.1 Pre-synthesis method and catalytic explorations
2.2 Post-synthesis modification and catalytic explorations
2.3 Impregnation method and catalytic explorations
2.4 Precipitation method and catalytic explorations
3 Conclusion and outlook

Key words: metal-organic framework (MOF), active sites, catalysis, catalytic reactions

中图分类号: 

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