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化学进展 2010, Vol. 22 Issue (11): 2079-2088   后一篇

• 特约稿 •

原子转移自由基聚合的最新研究进展*

李强   张丽芬   柏良久   缪洁   程振平**   朱秀林**   

  1. ( 苏州大学材料与化学化工学部 高分子化学与物理研究所   苏州  215123)
  • 收稿日期:2010-05-17 修回日期:2010-07-07 出版日期:2010-11-24 发布日期:2010-10-20
  • 通讯作者: 程振平 E-mail:sudaczp@hotmail.com
  • 基金资助:

    国家自然科学基金

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Atom Transfer Radical Polymerization

Li  Qiang   Zhang Lifen  Bai Liangjiu  Miao Jie    Cheng Zhenping**   Zhu Xiulin**   

  1. (College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123,China)
  • Received:2010-05-17 Revised:2010-07-07 Online:2010-11-24 Published:2010-10-20
  • Contact: Cheng Zhenping E-mail:sudaczp@hotmail.com

原子转移自由基聚合(ATRP)是目前为止最具工业化应用前景的“活性”/可控自由基聚合之一。近年来对其广泛的研究使这一技术逐渐向着“提高可操作性”与“尽可能地减少金属催化剂用量”方面发展；与此同时，诞生了不同催化体系的ATRP衍生技术，如反向原子转移自由基聚合(RATRP)、正向反向同时引发的原子转移自由基聚合(SR&NI ATRP)、引发剂连续再生催化剂原子转移自由基聚合(ICAR ATRP)、电子转移生成催化剂的原子转移自由基聚合(AGET ATRP)和电子转移再生催化剂原子转移自由基聚合(ARGET ATRP)等多种基于ATRP的新方法。本文概述了这几种ATRP体系的发展历程与基本原理，并对其国内外的最新研究进展进行了综述。

关键词： 原子转移自由聚合, “活性”可控自由基聚合, 反向原子转移自由基聚合

Atom transfer radical polymerization (ATR)is one of the most promising industrial application methods of “living”/controlled radical polymerization. For recent years, the extensive research on ATRP has been focusing on “simplifying the operation of polymerization” and “minimizing the amount of metal catalyst”. Several new ATRP techniques with different catalyst systems have been developed at the same time, such as, reverse atom transfer radical polymerization (RATRP), simultaneous reverse and normal initiation ATRP (SR&NI ATRP), initiators for continuous activator regeneration ATRP (ICAR ATRP), activators generated by electron transfer for ATRP (AGET ATRP) and activators regenerated by electron transfer for ATRP (ARGET ATRP). This paper reviewed the development and basic principles of these ATRP systems.

Contents
1. Introduction
2. Overview of ATRP
2.1. Normal ATRP
2.2. RATRP
2.3. SR&NI ATRP
2.4. ICAR ATRP
2.5. AGET ATRP
2.6. ARGET ATRP
3. Conclusion

Key words: atom transfer radical polymerization( ATRP), “living”/controlled radical polymerization, Reverse atom transfer radical polymerization (RATRP)
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[1] Otsu T, Yoshida M. Macromol. Chem. Rapid Commun., 1982, 3: 123—127
[2] Otsu T. J. Polym. Sci., Part A: Polym. Chem., 2000, 38: 2121—2136
[3] Georges M K, Vergin R P N, Kazmaier P M, Harmer G K. Macromolecules, 1993, 26: 2987—2988
[4] Hawker C J, Bosman A W, Harth E. Chem. Rev., 2001, 101: 3661—3688
[5] Sciannamea V, Jerome R, Detrembleur C. Chem. Rev., 2008, 108: 1104—1126
[6] Chiefari J, Chong Y K, Ercole F, Krstina J, Jeffry J, Le T P, Rezzardo E, Thang S H. Macromolecules, 1998, 31: 5559—5562
[7] Moad G, Rizzardo E, Thang S H. Polymer, 2008, 49: 1079—1131
[8] Boyer C, Bulmus V, Davis T P, Ladmiral V, Liu J Q, Perrier S. Chem. Rev., 2009, 109: 5402—5436
[9] Wang J S, Matyjaszewski K. J. Am. Chem. Soc., 1995, 117: 5614—5165
[10] Percec V, Narboiu B. Macromolecules, 1995, 28: 7970—7972
[11] Matyjaszewski K, Tsarevsky N V. Nature Chem., 2009, 1: 276—288
[12] Shen Y Q, Tang H D, Ding S J. Prog. Polym. Sci., 2004, 29: 1053—1078
[13] Tsarevsky N V, Matyjaszewski K. Chem. Rev., 2007, 107: 2270—2299
[14] Chen Z P, Zhu X L, Chen G J, Xu W J, Lu J M. J. Polym. Sci. Part A: Polym. Chem., 2002, 40: 3823—3834
[15] Kato M, Kamigaito M, Sawamoto M, Higashimura T. Macromolecules, 1995, 28: 1721—1723
[16] Wang J S, Matyjaszewski K. Macromolecules, 1995, 28: 7572—7573
[17] Gromada J, Matyjaszewski K. Macromolecules, 2001, 34: 7664—7671
[18] Matyjaszewski K, Jakubowski W, Min K, Tang W, Huang J, Braunecker W A, Tsarevsky N V. PNAS, 2006, 103: 15309—15314
[19] Jakubowski W, Matyjaszewski K. Macromolecules, 2005, 38: 4139—4146
[20] Jakubowski W, Min K, Matyjaszewski K. Macromolecules, 2006, 39: 39—45
[21] Zhang M, Ray W H. J. Appl. Polym. Sci., 2002, 86: 1630—1662
[22] Wu T, Mei Y, Cabral J T, Xu C, Beers K L. J. Am. Chem. Soc., 2004, 126: 9880—9881
[23] Schork F J, Smulders W J. Appl. Polym. Sci., 2004, 92: 539—542
[24] Matyjaszewski K, Xia J H. Chem. Rev., 2001, 101: 2921—2990
[25] Ouchi M, Terashima T, Sawamoto M. Chem. Rev., 2009, 109: 4963—5050
[26] Cunningham M F. Prog. Polym. Sci., 2008, 33: 365—398
[27] Zetterlund P B, Kagawa Y, Okubo M. Chem. Rev., 2008, 108: 3747—3794
[28] Gao H F, Matyjaszewski K. Prog. Polym. Sci., 2009, 34: 317—350
[29] Shen Y Q, Zhu S P, Pelton R. Macromol. Rapid Commun., 2000, 21: 956—959
[30] Shen Y Q, Zhu S P. AIChE J., 2002, 48: 2609—2619
[31] Chan N, Boutti S, Cunningham M F, Hutchinson R A. Macromol. React. Eng., 2009, 3: 222—231
[32] Wu T, Mei Y, Xu C, Byrd H C M, Beers K L. Macromol. Rapid Commun., 2005, 26: 1037—1042
[33] Noda T, Grice A J, Levere M E, Haddleton D M. Eur. Polym. J., 2007, 43: 2321—2330
[34] Müller M, Cunningham M F, Hutchinson R A. Macromol. React. Eng., 2008, 2: 31—36
[35] Tsarevsky N V, Matyjaszewski K. J. Polym. Sci., Part A: Polym. Chem., 2006, 44: 5098—5112
[36] Tsarevsky N V, Matyjaszewski K. Chem. Rev., 2007, 107: 2270—2299
[37] Xu F J, Neoh K G, Kang E T. Prog. Polym. Sci., 2009, 34: 719—761
[38] Coessens V, Pintauer T, Matyjaszewski K. Prog. Polym. Sci., 2001, 26: 337—377
[39] Bajpai A K, Shukla S K, Bhanu S, Kankane S. Prog. Polym. Sci., 2008, 33: 1088—1118
[40] McCormick C L, Kirkland S E, York A W. Polym. Rev., 2006, 46: 421—443
[41] Barbey R, Lavanant L, Paripovic D, Schüwer N, Sugnaux C, Tugulu S, Klok H A. Chem. Rev., 2009, 109: 5437—5527
[42] Kamigaito M, Ando T, Sawamoto M. Chem. Rev., 2001, 101: 3689—3745
[43] Saikia P J, Goswami A, Baruah S D. J. Appl. Polym. Sci., 2002, 86: 386—394
[44] Li M, Min K, Matyjaszewski K. Macromolecules, 2004, 37: 2106—2112
[45] Li M, Jahed N M, Min K, Matyjaszewski K. Macromolecules, 2004, 37: 2434—2441
[46] Braunecker W A, Matyjaszewski K. Prog. Polym. Sci., 2007, 32: 93—146
[47] Mueller L, Jakubowski W, Tang W, Matyjaszewski K. Macromolecules, 2007, 40: 6464—6472
[48] Plichta A, Li W W, Matyjaszewski K. Macromolecules, 2009, 42: 2330—2332
[49] Zhang L F, Miao J, Cheng Z P, Zhu X L. Macromol. Rapid Commun., 2010, 31: 275—280
[50] Min K, Gao H F, Matyjaszewski K. J. Am. Chem. Soc., 2005, 127: 3825—3830
[51] Min K, Jakubowski W, Matyjaszewski K. Macromol. Rapid Commun., 2006, 27: 594—598
[52] Matyjaszewski K, Coca S, Gaynor S G, Wei M L, Woodworth B E. Macromolecules, 1997, 30: 7348—7350
[53] De V A, Klumperman B, De Wet—Roos D, Sanderson R D. Macromol. Chem. Phys., 2001, 202: 1645—1648
[54] Gnanou Y, Hizal G J. Polym. Sci., Part A: Polym., Chem. 2004, 42: 351—359
[55] Min K, Matyjaszewski K. Macromolecules, 2005, 38: 8131—8134
[56] Min K, Yu S, Lee H, Mueller L, Sheiko S, Matyjaszewski K. Macromolecules, 2007, 40: 6557—6563
[57] Gao H F, Min K, Matyjaszewski, K. Macromol. Chem. Phys., 2006, 207: 1709—1717
[58] Li W, Min K, Matyjaszewski K, Stoffelbach F, Charleux B. Macromolecules, 2008, 41: 6387—6392
[59] Stoffelbach F, Belardi B, Santos J M R C A, Tessier L, Matyjaszewski K, Charleux B. Macromolecules, 2007, 40: 8813—8816
[60] Stoffelbach F, Griffete N, Buiab C, Charleux B. Chem. Commun., 2008, 4807—4809
[61] Dong H C, Mantha V, Matyjaszewski K. Chem. Mater., 2009, 21: 3965—3972
[62] Oh J K, Perineau F, Charleux B, Matyjaszewski K. J. Polym. Sci., Part A: Polym. Chem., 2009, 47: 1771—1781
[63] Tang H D, Radosz M, Shen Y Q. Macromol. Rapid Commun., 2006, 27: 1127—1131
[64] Oh J K, Matyjaszewski K. J. Polym. Sci., Part A: Polym. Chem., 2006, 44: 3787—3796
[65] Kwiatkowski P, Jurczak J, Pietrasik J, Jakubowski W, Mueller L, Matyjaszewski K. Macromolecules, 2008, 41: 1067—1069
[66] Oh J K, Min K, Matyjaszewski K. Macromolecules, 2006, 39: 3161—3167
[67] Grignard B, Jérme C, Calberg C, Jérme R, Wang W X, Howdle S M, Detrembleur C. Macromolecules, 2008, 41: 8575—8583
[68] Hu Z Q, Shen X R, Qiu H Y, Lai G Q, Wu J R, Li W Q. Eur. Polym. J., 2009, 45: 2313—2318
[69] Min K, Gao H F, Matyjaszewski K. J. Am. Chem. Soc., 2006, 128: 10521—10526
[70] Oh J K, Perineau F, Matyjaszewski K. Macromolecules, 2006, 39: 8003—8010
[71] Hizal G, Tunca U, Aras S, Mert H. J. Polym. Sci., Part A: Polym. Chem., 2006, 44: 77—87
[72] Tan Y, Yang Q B, Sheng D K, Su X F, Xu K, Song C L, Wang P X. e-Polymers, 2008, no. 025
[73] Wu D X, Yang Y F, Cheng X H, Liu L, Tian J, Zhao H Y. Macromolecules, 2006, 39: 7513—7519
[74] Jakubowski W, Matyjaszewski K. Macromol. Symp., 2006, 240: 213—223
[75] Yamamura Y, Matyjaszewski K. J. Macromol. Sci.: Part A: Pure and Appl. Chem., 2007, 44: 1035—1039
[76] Esteves A C C, Bombalski L, Trindade T, Matyjaszewski K, Barros-Timmons A. Small, 2007, 3: 1230—1236
[77] Zhao H Y, Kang X L, Liu L. Macromolecules, 2005, 38: 10619—10622
[78] Taniguchi T, Kasuya M, Kunisada Y, Miyai T, Nagasawa H, Nakahira T. Colloids and Surfaces B: Biointerfaces, 2009, 71: 194—199
[79] Qian H, He L. Anal. Chem., 2009, 81: 4536—4542
[80] Pintauer T, Matyjaszewski K. Chem. Soc. Rev., 2008, 37: 1087—1097
[81] Oh J K, Dong H, Zhang R, Matyjaszewski K, Schlaad H. J. Polym. Sci., Part A: Polym. Chem., 2007, 45: 4764—4772
[82] Zhang L F, Cheng Z P, Shi S P, Li Q H, Zhu X L. Polymer, 2008, 49: 3054—3059
[83] Zhang L F, Cheng Z P, Tang F, Li Q, Zhu X L. Macromol. Chem. Phys., 2008, 209: 1705—1713
[84] Luo R, Sen A. Macromolecules, 2008, 41: 4514—4518
[85] Bai L J, Zhang L F, Zhu J, Cheng Z P, Zhu X L. J. Polym. Sci., Part A: Polym. Chem., 2009, 47: 2002—2008
[86] Zhang L F, Cheng Z P, Lü Y T, Zhu X L. Macromol. Rapid Commun., 2009, 30: 543—547
[87] Tang F, Zhang L F, Zhu J, Cheng Z P, Zhu X L. Ind. Eng. Chem. Res., 2009, 48: 6216—6223
[88] Li Q, Zhang L F, Zhang Z B, Zhou N C, Cheng Z P, Zhu X L. J. Polym. Sci., Part A: Polym. Chem., 2010, 48: 2006—2015
[89] Jakubowski W, Matyjaszewski K. Angew. Chem. Int. Ed., 2006, 118: 4594—4598
[90] Min K, Gao H F, Matyjaszewski K. Macromolecules, 2007, 40: 1789—1791
[91] Jakubowski W, Kirci—Denizli B, Gil R R, Matyjaszewski K. Macromol. Chem. Phys., 2008, 209: 32—39
[92] Tanaka K, Matyjaszewski K. Macromolecules, 2007, 40: 5255—5260
[93] Chen H, Yang L X, Liang Y, Hao Z H, Lu Z X. J. Polym. Sci., Part A: Polym. Chem., 2009, 47: 3202—3207
[94] Dong H C, Matyjaszewski K. Macromolecules, 2008, 41: 6868—6870
[95] Matyjaszewski K, Dong H, Jakubowski W, Pietrasik J, Kusumo A. Langmuir, 2007, 23: 4528—4531
[96] Li W W, Gao H F, Matyjaszewski K. Macromolecules, 2009, 42: 927—932
[97] Jonsson M, Nystrm D, Nordin O, Malmstrm E. Eur. Polym. J., 2009, 45: 2374—2382
[98] Chan N, Cunningham M F, Hutchinson R A. Macromol. Chem. Phys., 2008, 209: 1797—1805
[99] Zhang L F, Tang H D, Tang J B, Shen Y Q, Meng L G, Radosz M, Arulsamy N. Macromolecules, 2009, 42: 4531—4538
[100] Kwak Y, Matyjaszewski K. Polym. Int., 2009, 58: 242—247
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