水滴模板法构筑蜂窝状有序多孔膜*

孙航 吴立新

化学进展 ›› 2010, Vol. 22 ›› Issue (09) : 1784-1798.

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化学进展 ›› 2010, Vol. 22 ›› Issue (09) : 1784-1798.
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引用本文
孙航 吴立新. 水滴模板法构筑蜂窝状有序多孔膜*[J]. 化学进展, 2010, 22(09): 1784-1798
Ordered Honeycomb-Patterned Films via Breath Figures[J]. Progress in Chemistry, 2010, 22(09): 1784-1798
综述与评论

水滴模板法构筑蜂窝状有序多孔膜*

  • 孙航  吴立新**
作者信息 +

Ordered Honeycomb-Patterned Films via Breath Figures

  • Sun Hang   Wu Lixin**
Author information +
文章历史 +

摘要

水滴模板法是利用凝结并自组织有序排列的水滴为模板构筑有序蜂窝状多孔薄膜的方法。这种方法具有方便、快速、廉价、作为模板的水滴可以自然蒸发而除去,且孔洞的尺寸可以通过改变相关的实验参数方便的进行调控的优点,因而近年来受到了人们的广泛关注。本文介绍了利用水滴模板法构筑有序多孔薄膜的实验方法,探讨了形成机理和相关实验条件对多孔薄膜结构的影响,并结合当前的研究热点针对多孔薄膜的进一步应用,着重综述了水滴模板法在不同性质的成膜材料体系的应用、多孔薄膜中亚有序结构的引入以及提高多孔薄膜稳定性的方法。最后,本文展望了利用水滴模板法构筑有序多孔薄膜这一研究领域的发展前景。

Abstract

Ordered honeycomb-patterned films have important applications in patterned templates, photonic or optoelectronic devices, catalysis, sensors, and so on. Among those techniques for the fabrication of honeycomb structured films, the breath figure is proved to be an effective dynamic template method through providing a humid condition to the surface of polymer solution in a volatile solvent. The condensed water droplets caused by rapid cooling due to solvent evaporation self-organize into a well ordered hexagonal array that acts as the template directing the formation of ordered honeycomb-patterned structure. The breath figure technique has attracted considerable attention over recent years due to its facility, speedness, cheapness, and the automatic remove of the condensed water droplets. And the size of the pore structure can be easily adjusted by changing the correlative experimental parameters. This paper reviews the breath figure method, discusses the formation mechanism and the effects of the correlative experimental parameters on the structures of the formed honeycomb-patterned films, and summarizes the diverse functional materials applied in this breath figure method, the methods used to enhance the stability of the porous films, the introduction of substructures into the honeycomb-patterned films in view of the further applications of the honeycomb-patterned films. Finally, the development trend of this breath figure method for the preparation of ordered honeycomb-patterned films is prospected.

Contents 
1 Introduction
2 Method and mechanism
3 Influence factors
4 Applied materials
4.1 Polymers
4.2 Nanomaterials
4.3 Biomaterials and biocompatible polymers
4.4 Organometallic materials
5 Honeycomb-patterned films with substructure
5.1 Amphiphilic block copolymers
5.2 Mixtures
6 Enhancement of the stability
7 Applications
7.1 Template
7.2 Superhydrophobic surface
7.3 Cell growth substrate
8 Conclusions and outlook

关键词

多孔膜 / 水滴模板法 / 功能薄膜 / 自组装

Key words

honeycomb-patterned film / breath figures / functional film / self-assembly

中图分类号: O631    TB383   

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基金

国家重点基础研究发展计划(973);国家自然科学基金项目


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