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化学进展 2010, Vol. 22 Issue (07): 1295-1309 前一篇   后一篇

• 特约稿 •

温控液/液两相催化进展*

金子林*   刘宁   刘春   

  1. ( 大连理工大学精细化工国家重点实验室    大连  116012 )
  • 收稿日期:2010-02-25 出版日期:2010-07-24 发布日期:2010-07-02
  • 通讯作者: 金子林 E-mail:zilinjin@126.com
  • 基金资助:

    国家自然科学基金

Thermoregulated Liquid/Liquid Biphasic Catalysis

Jin Zilin**    Liu Ning    Liu Chun   

  1. ( State Key Laboratory of Fine Chemical, Dalian University of Technology, Dalian, 116012, China )
  • Received:2010-02-25 Online:2010-07-24 Published:2010-07-02
  • Contact: Jin Zilin E-mail:zilinjin@126.com

本文以作者在温控水/有机两相及温控非水液/液两相催化领域的研究工作为主线,对这一领域的研究进展作一评述,重点是环绕经典水/有机两相催化体系存在“应用范围受底物水溶性限制”的根本问题展开。特别是对“温控相转移催化”作了较为详细的介绍,同时,按体系介质不同,对氟两相体系、PEG两相体系、离子液体两相体系等非水液/液两相体系以及温控相分离催化分别作了阐述。

This paper reviews the recent progress in biphasic catalysis based on our research in the fields of thermoregulated aqueous-organic biphasic catalysis and thermoregulated non-aqueous liquid-liquid biphasic catalysis, in which the authors aim at the solution to the limitation in the application of the classic aqueous-organic biphasic catalysis due to the low water-solubility of the substrates. Especially, the authors discuss the thermoregulated phase transfter catalysis (TRPTC) in detail. Moreover, various non-aqueous biphasic systems clarified by the reaction medium, including the fluorous biphasic system, the PEG biphasic system, the ionic liquid biphasic system,as well as the thermoregulated phase-separable catalysis have been also reviewed.

Contents 
1 Introduction
2 Aqueous-organic biphasic and thermoregulated phase transfer catalysis
2.1 Aqueous-organic biphasic catalysIS
2.2 Thermoregulated phase transfer catalysis
3 Thermoregulated non-aqueous liquid/liquid biphasic catalysis
3.1 Fluorous biphasic system 
3.2 Organic liquid/liquid biphasic catalysis 
3.3 Thermoregulated ionic liquid biphasic catalysis 
4 Thermoregulated phase-separable catalysis 
5 Conclusions and outlook

 

中图分类号: 

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[1] 冯翠兰 王艳华 金子林. 液/液两相催化高碳烯烃氢甲酰化反应*[J]. 化学进展, 2005, 17(02): 209-216.
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摘要

温控液/液两相催化进展*