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化学进展 2010, Vol. 22 Issue (0203): 515-521 前一篇   后一篇

• 综述与评论 •

镁二次电池正极材料和电解液研究*

沈健;彭博;陶占良;陈军**   

  1. （南开大学新能源材料化学研究所 教育部高效储能工程研究中心 天津 300071）
  • 收稿日期:2009-03-24 修回日期:2009-05-21 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 陈军 E-mail:chenabc@nankai.edu.cn
  • 基金资助:

    国家自然科学基金项目-镁二次电池新型电极材料研究;973项目-纳米新能源材料能量转化的新规律及在高端电池中的应用

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Cathode Materials and Electrolytes for Magnesium Secondary Batteries

Shen Jian; Peng Bo; Tao Zhanliang; Chen Jun**   

  1. (Institute of New Energy Material Chemistry and Engineering, Research Center of Energy Storage & Conversion, Ministry of Education, Nankai University, Tianjin 300071, China)
  • Received:2009-03-24 Revised:2009-05-21 Online:2010-03-24 Published:2010-03-18
  • Contact: Chen Jun E-mail:chenabc@nankai.edu.cn

镁二次电池作为一种很有潜力的大负荷蓄电池而逐渐受到人们的重视，但由于难以找到合适的正极嵌入材料和非水电解液，使其发展受到了阻碍。本文对镁二次电池正极材料和电解液的最新研究进展作了较为全面的阐述，其中着重介绍了性能最佳的Mo6S8型正极材料和Mg(AX3-nRn'R'n")2/THF型电解液（A = Al、B、Sn等；X = Cl、Br；R、R' =烷基或芳基；0<n<4；n'+n" = n），其组装的镁二次电池的正极材料放电容量可达100mAh·g-1。探讨了当前存在的问题及研究的方向，并对其应用前景进行了展望。

关键词： 镁二次电池, 正极材料, 电解液

Magnesium secondary batteries have recently attracted much attention as a potential candidate for heavy load batteries. However, the development of Mg secondary batteries has been hindered because it is difficult to find the appropriate cathode materials and non-aqueous electrolyte. In this paper, the recent research advances of key technologies on Mg secondary batteries are reviewed with details of cathode materials and electrolyte, especially on Mo6S8 cathode material and Mg(AX3-nRn'R'n")2/THF electrolyte with favorable performance(A=Al, B, Sn, etc. ; X=Cl, Br; R, R'=alkyl or aryl; 0<n<4; n'+n" = n). The specific capacity is ~100mAh·g-1 for the above cathode material in the Mg secondary batteries. Furthermore, the current problems as well as the corresponding research directions are discussed, and the possible application prospects is also proposed.

Contents
1 Introduction
2 Cathode materials
2.1 Transition metal oxides
2.2 Transition metal sulfides
2.3 Other intercalation materials
3 Electrolytes
3.1 Grignard reagents and its derivatives
3.2 Other electrolyte systems
4 Conclusion and outlook

Key words: magnesium secondary batteries, cathode materials, electrolytes

中图分类号: 

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