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化学进展 2010, Vol. 22 Issue (0203): 500-514 前一篇   后一篇

• 综述与评论 •

HOx自由基的实地测量及其化学机制解析*

陆克定;张远航**   

  1. (北京大学环境科学与工程学院 北京100871)
  • 收稿日期:2009-03-09 修回日期:2009-04-15 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 张远航 E-mail:yhzhang@pku.edu.cn
  • 基金资助:

    国家重点基础研究发展计划（973）项目;国家自然科学基金

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Observations of HOx Radical in Field Studies and the Analysisi of Its Chemical Mechanism

Lu Keding; Zhang Yuanhang**   

  1. (College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China)
  • Received:2009-03-09 Revised:2009-04-15 Online:2010-03-24 Published:2010-03-18
  • Contact: Zhang Yuanhang E-mail:yhzhang@pku.edu.cn
  • Supported by:

    Major State Basic Research Program of China;National Natural Science Foundation of China

HOx大气化学机制的研究对于理解全球气候的变化和区域空气污染的控制具有重要意义。在现阶段，推进这项研究的关键环节之一就是开展包括HOx直接测量的综合性野外观测。由于HOx化学寿命很短、浓度极低，使其测量成为迄今为止大气化学领域最富挑战性的工作之一。本文就综述了目前能够直接测量HOx浓度的技术方法，总结了历次野外观测中测量到的浓度水平，阐述了当前大气HOx化学机制的概念框架和历次观测对于它的贡献，评述了此项研究中尚待解决的关键问题。另外，本文还综述了HOx大气化学机制在我国的研究进展，指出了一些可能的重点研究方向。

关键词： HOx, 测量技术, 外场观测, 大气化学, 大气氧化性, 闭合实验

Researches on HOx radical chemistry would provide theoretical support for understanding the global climate change and regional air pollution control. At present stage, comprehensive field campaign including HOx radial measurements is one of the critical approaches to advance it. However, due to the very short lifetime and extremely low concentration in the atmosphere, direct measurement of HOx radical is one of most challenged works in atmospheric chemistry. This paper reviews the direct measurement techniques of the HOx radical, summarizes the observed dynamics range of its concentrations, introduces the current schematic view of the HOx radical chemistry and the important contributions from previous field studies, and discusses the main scientific questions that need further researches. Besides, the progress of the HOx radical chemistry within China is reviewed, and several potentially important research directions are pointed out.

Contents
1 Introduction
2 Measurement techniques of HOx radical
2.1 Measurement techniques of OH
2.2 Measurement techniques of HO2
2.3 Calibrations
3 Observations of HOx radical in field studies and researches on its chemical mechanism
3.1 Observed HOx concentrations in typical conditions
3.2 Schematic diagram of the HOx radical chemistry and lessons from the previous campaign
3.3 Closure studies
4 Progresses of HOx radical chemistry in China
5 Conclusion and outlook

Key words: HOx, measurement technique, field measurements, atmospheric chemistry, atmospheric oxidation, closure study

中图分类号: 

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