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化学进展 2010, Vol. 22 Issue (0203): 472-481 前一篇   后一篇

• 综述与评论 •

生物质资源研究的新视野——木质纤维素全溶体系*

袁同琦;何静;许凤**;孙润仓**   

  1. （北京林业大学生物质化学与技术研究所 北京 100083）
  • 收稿日期:2009-03-09 修回日期:2009-04-12 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 许凤;孙润仓 E-mail:xfx315@bjfu.edu.cn; rcsun3@bjfu.edu.cn
  • 基金资助:

    国家自然科学基金项目;教育部项目;国家林业局项目

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A New Vision in the Research of Biomass Resources: Complete-Lignocellulose-Dissolution System

Yuan Tongqi; He Jing; Xu Feng**; Sun Runcang**   

  1. (Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083, China)
  • Received:2009-03-09 Revised:2009-04-12 Online:2010-03-24 Published:2010-03-18
  • Contact: Xu Feng;Sun Runcang E-mail:xfx315@bjfu.edu.cn; rcsun3@bjfu.edu.cn
  • Supported by:

    National Natural Science Foundation of China

木质纤维素全溶体系是指具有氢键破坏能力，从而导致木质纤维素溶解的一类特殊溶剂体系。包括有机溶剂全溶体系和离子液体全溶体系。前者主要是基于二甲基亚砜的全溶体系，具体可分为二甲基亚砜/四丁基氟化铵、二甲基亚砜/ N-甲基咪唑和二甲基亚砜/氯化锂3种全溶体系。后者则主要是基于咪唑基离子液体的全溶体系，种类较多。这一全新概念的提出为更加便捷的对木质纤维素进行结构鉴定、化学改性和高效利用提供了一个可靠平台，本文首次对木质纤维素全溶体系的最新研究成果进行了综述。

关键词： 木质纤维素, 全溶体系, 二甲基亚砜, 咪唑基离子液体

Complete-lignocellulose-dissolution system is a kind of special solvent system with having hydrogen-bond-disrupting ability, including two complete dissolution systems, organic solvents and ionic liquids. Organic solvents, which are based on dimethylsulfoxide, may be divided into three organic systems: dimethylsulfoxide/ tetrabutylammonium fluoride, dimethylsulfoxide/ N-methylimidazole and dimethylsulfoxide/ lithium chloride. Ionic liquids comprise many sorts, but all based on imidazolium-based ionic liquids. The emerging of this new system sets up a reliable platform for conveniently analyzing the structure, chemical modification and high efficient application of lignocellulose. In this article, the latest research results about this new system are reviewed for the first time.

Contents
1 Introduction
2 Organic solvent complete dissolution systems
2.1 DMSO/TBAF organic system
2.2 DMSO/NMI organic system
2.3 DMSO/LiCl organic system
3 Ionic liquids complete dissolution systems
3.1 Dissolution of lignocellulose
3.2 Modification and application of lignocellulose
3.3 Structural characterization of lignocellulose
3.4 Recyclability of ionic liquids
4 Conclusion

Key words: lignocellulose, complete dissolution system, dimethylsulfoxid(DMSO), imidazolium-based ionic liquids

中图分类号: 

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[ 1 ] 　RagauskasA J, Williams C K, Davison B H, et al. Science,2006, 311 (5760) : 484—489
[ 2 ] 　Huber G W, Dumesic J A. Catal. Today, 2006, 111: 119—132
[ 3 ] 　Huber G W, Iborra S, Corma A. Chem. Rev. , 2006, 106:4044—4098
[ 4 ] 　Valenzuela M B, Jones C W, Agrawal P K. Energ. Fuel, 2006,20: 1744—1752
[ 5 ] 　余权英(Yu Q Y) . 化学进展( Progress in Chemistry) , 1996, 8(4) : 331—339
[ 6 ] 　罗民(Luo M) , 高积强(Gao J Q) , 乔冠军(Qiao G J )等. 化学进展( Progress in Chemistry) , 2008, 20 (6) : 989—1000
[ 7 ] 　Kim H, Ralph J, Akiyama T. Bioenerg. Res. , 2008, 1:56—66
[ 8 ] 　Wu S B, Argyropoulos D S. J. Pulp. Pap. Sci. , 2003, 29:235—240
[ 9 ] 　Xu F, Sun R C, Zhai M Z, et al. J. App l. Poly. , 2008, 108:1158—1168
[ 10 ] 　Lv F C, Ralph J. Plant Journal, 2003, 35: 535—544
[ 11 ] 　Heinze T, Dicke R, Koschella1 A, et al. Macromol. Chem.Phys. , 2000, 201: 627—631
[ 12 ] 　Gerasimowicz W V, Hicks K B, Pfeffer P E. Macromolecules,1984, 17: 2597—2603
[ 13 ] 　Ralph J, Lv F C. Org. Biomol. Chem. , 2004, 2: 2714—2715
[ 14 ] 　Holtman K M, Chang H M, Kadla J F. J. Wood Chem.Technol. , 2007, 27: 179—200
[ 15 ] 　Fasching M, Schrêder P, Wollboldt R P, et al. Holzforschung,2008, 62: 15—23
[ 16 ] 　Hu Z J, Yeh T F, Chang H M, et al. Holzforschung, 2006, 60:389—397
[ 17 ] 　Guerra A, Filpponen I, Lucia L A, et al. J. Agr. Food Chem. ,2006, 54: 5939—5947
[ 18 ] 　Guerra A, Filpponen I, Lucia L A, et al. J. Agr. Food Chem. ,2006, 54: 9696—9705
[ 19 ] 　Fujimoto A, Matsumoto Y J, Chang H M, et al. J. Wood Chem.Technol. , 2005, 51: 89—91
[ 20 ] 　Wang Z G, Yokoyama T, Chang H M, et al. Proceeding of International Conference on Pulp ing, Papermaking and Biotechnology 2008 ( Eds. Jin Y C, Zhai H M, Li Z Z) . Nanjing: China Scientific and Cultural Publishing House, 20081 664—668
[ 21 ] 　杨雅立(Yang Y L) , 王晓化(Wang X H) , 寇元(Kou Y)等.化学进展( Progress in Chemistry) , 2003, 15 (6) : 471—476
[ 22 ] 　来婧娟(Lai J J ) , 周建华( Zhou J H) , 郑敏刚( Zheng M G)等. 化学进展( Progress in Chemistry ) , 2008, 20 ( 6 ) :899—907
[ 23 ] 　赵大成( Zhao D C) , 徐海涛(Xu H T) , 徐鹏(Xu P)等. 化学进展( Progress in Chemistry) , 2005, 17 (4) : 700—705
[ 24 ] 　刘庆彬( Zhang Q B) , 张占辉( Zhang Z H) , 张福军( Zhang F J) . 化学进展( Progress in Chemistry ) , 2005, 17 ( 6 ) :1060—1066
[ 25 ] 　夏咏梅(Xia Y M) , 吴红平(Wu H P) , 张玥( Zhang Y)等. 化学进展( Progress in Chemistry) , 2006, 18 (12) : 1660—1667
[ 26 ] 　肖小华(Xiao X H) , 刘淑娟(Liu S J) , 刘霞(Liu X)等. 分析化学(Chinese Journal of Analytical Chemistry) , 2005, 33 ( 4) :569—574
[ 27 ] 　曹洁明(Cao J M) , 房宝青( Fang B Q) , 王军(Wang J)等. 化学进展( Progress in Chemistry) , 2005, 17 (6) : 1028—1033
[ 28 ] 　寇元(Kou Y) , 何玲(He L) . 化学进展( Progress in Chemistry) , 2008, 20 (1) : 5—10
[ 29 ] 　El-Seoud O A, Koschella A, Fidale L C, et al. Biomacromolecules, 2007, 8: 2629—2647
[ 30 ] 　Swatloski R P, Spear S K, Holbrey J D, et al. J. Am. Chem.Soc. , 2002, 124: 4974—4975
[ 31 ] 　Zhang H, Wu J, Zhang J, et al. Macromolecules, 2005, 38:8272—8277
[ 32 ] 　Fukaya Y, Hayashi K, Wada M, et al. Green Chem. , 2008,10: 44—46
[ 33 ] 　Wu J, Zhang J, Zhang H, et al. Biomacromolecules, 2004, 5:266—268
[ 34 ] 　Liu C F, Sun R C, Zhang A P, et al. Carbohydr. Res. , 2007,342: 919—926
[ 35 ] 　Liu C F, Sun R C, Zhang A P, et al. Polym. Degrad. Stabil. ,2006, 91: 3040—3047
[ 36 ] 　Liu C F, Sun R C, Zhang A P, et al. J. Agric. Food Chem. ,2007, 55: 2399—2406
[ 37 ] 　Xie H L, Shi T J. Holzforschung, 2006, 60: 509—512
[ 38 ] 　Kilpeläinen I, Xie H B, King A, et al. J. Agric. Food Chem. ,2007, 55: 9142—9148
[ 39 ] 　Phillips D M, DrummyL F, Conrady D G, et al. J. Am. Chem.Soc. , 2004, 126: 14350—14351
[ 40 ] 　Xie H B, Zhang S B, Li S H. Green Chem. , 2006, 8:630—633
[ 41 ] 　Remsing R C, Swatloski R P, Rogers R D, et al. Chem. Commun. , 2006, 12: 1271—1273
[ 42 ] 　Chen Y R, Sarkanen S. Phytochem. Rev. , 2003, 2: 235—255
[ 43 ] 　Guerra A, Gaspar A R, Contreras S, et al. Phytochemistry,2007, 68: 2570—2583
[ 44 ] 　Anderson J L, Ding J, Welton T, et al. J. Am. Chem. Soc. ,2002, 124: 14253—14254
[ 45 ] 　Forsyth SA, MacFarlaneD R, Thomson R J. Chem. Commun. ,2002, 714—715
[ 46 ] 　Fort D A, Remsing R C, Swatloski R P, et al. Green Chem. ,2007, 9: 63—69
[ 47 ] 　Zavrel M, Bross D, Funke M, et al. Bioresour. Technol. ,2009, 100: 2580—2587
[ 48 ] 　Rayne S, Mazza G. Rap id Dissolution of Lignocellulosic Plant Materials in an Ionic Liquid. Nature Precedings, [ 2009-01 ] http://precedings.nature.com/documents/637/version/1
[ 49 ] 　Mai C, Militz H. Wood Sci. Technol. , 2004, 37: 339—348
[ 50 ] 　Fernandes E G, Pietrini M, Chiellini E. Biomacromolecules,2004, 5: 1200—1205
[ 51 ] 　Zhang Y L, Zhang S Y, Yang D Q, et al. J. App l. Polym.Sci. , 2006, 102: 5085—5094
[ 52 ] 　Xie H B, King A, Kilpeläinen I, et al. Biomacromolecules,2007, 8: 3740—3748
[ 53 ] 　Sun Y, Cheng J Y. Bioresour. Technol. , 2002, 83: 1—11
[ 54 ] 　Li C Z, Wang Q, Zhao Z B. Green Chem. , 2008, 10:177—182
[ 55 ] 　Himmel M E, Ding S Y, Johnson D K, et al. Science, 2007,315: 804—807
[ 56 ] 　Sivers M V, Zacchi G. Bioresour. Technol. , 1995, 51: 43—52
[ 57 ] 　Vlasenko E Y, Ding H, Labavitch JM, et al. Bioresour. Technol. , 1997, 59: 109—119
[ 58 ] 　Sievers C, Valenzuela-Olarte M B, Marzialetti T, et al. Ind.Eng. Chem. Res. , 2009, 48: 1277—1286
[ 59 ] 　刘传富(Liu C F) , 孙润仓( Sun R C) , 任俊莉(Ren J L) . 精细化工( Fine Chemicals) , 2006, 23 (4) : 318—321
[ 60 ] 　叶君(Ye J) , 赵星飞( Zhao X F) , 熊犍(Xiong J ) . 化学进展( Progress in Chemistry) , 2007, 19 (4) : 478—484
[ 61 ] 　Milkowski K, Clark J H, Doi S. Green Chem. , 2004, 6: 189—190
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