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化学进展 2010, Vol. 22 Issue (0203): 406-416 前一篇   后一篇

• 综述与评论 •

点击化学与功能有机/聚合物材料*

陈琳;石乃恩;钱妍;解令海**;范曲立;黄维**   

  1. (江苏省有机电子与信息显示重点实验室-省部共建国家重点实验室培育基地 南京邮电大学信息材料与纳米技术研究院 南京 210046)
  • 收稿日期:2009-04-14 修回日期:2009-05-16 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 解令海;黄维 E-mail:iamlhxie@njupt.edu.cn; iamwhuang@njupt.edu.cn
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Click Chemistry and Functional Organic/ Polymeric Materials

Chen Lin; Shi Naien; Qian Yan; Xie Linghai**; Fan Quli; Huang Wei**   

  1. (Key Laboratory for Organic Electronics & Information Displays(KLOEID), Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing 210046, China)
  • Received:2009-04-14 Revised:2009-05-16 Online:2010-03-24 Published:2010-03-18
  • Contact: Xie Linghai; Huang Wei E-mail:iamlhxie@njupt.edu.cn; iamwhuang@njupt.edu.cn

点击化学是以杂原子连接单元C—X—C为基础的组合化学新方法，其作为现代可持续绿色有机化学方法的典范正成为构建功能有机/聚合物材料的重要工具，受到材料科学家的广泛关注。本文介绍了点击化学的基本原理与分类，系统论述在构筑有机/聚合物光电材料、超分子聚集体与分子自组装、分子机器系统以及分子识别与传感等方面的最新进展，最后提出了傅克点击反应并展望了其发展前景。

关键词： 点击化学, 有机/聚合物光电材料, 超分子组装, 分子机器, 分子识别与传感

Click chemistry is combinatorial synthesis on the basis of heteroatom links C—X—C. As a typical example of sustainable and green organic synthetic strategy for constructing functional organic/polymeric materials, it has aroused extensive interest among researchers in recent years. In this review, some basic conceptions of click chemistry and its category are introduced, and various organic/polymeric optoelectrical materials, supramolecular assemblies, molecular machine and recognition systems, as well as stimuli-responsive systems are summarized in detail. Finally, Friedel-Crafts type click chemistry and its future trend are prospected.

Contents
1 Introduction
2 Reaction types of click chemistry
2.1 Cycloaddition reaction
2.2 Strained heterocyclic ring-openning reaction
2.3 Addition reaction of carbon-carbon multiple bonds
2.4 Condensation reaction of carbonyl compounds
3 The applications of click chemisty
3.1 The applications in optoelectrical functional molecular materials
3.2 The applications in organic functional supramolecular structure and information system
4 Conclusion and outlook

Key words: click chemistry, organic/polymeric optoelectrical materials, supramolecular assembly, molecular machine, molecular recognition and sensor

中图分类号: 

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