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化学进展 2010, Vol. 22 Issue (0203): 400-405 前一篇   后一篇

• 综述与评论 •

官能化硅烷及其配位化合物的研究

孙文艳;王灯旭;来庆玲;张洁;冯圣玉*   

  1. （山东大学化学与化工学院 济南 250100）
  • 收稿日期:2009-03-02 修回日期:2009-06-11 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 冯圣玉 E-mail:fsy@sdu.edu.cn
  • 基金资助:

    官能基硅杂炔类聚合物的设计合成、结构与性能;官能基硅-硅键聚合物的超分子组装基其光电性能研究

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导出 被引次数 ( 4 | 1 )

Functionalized Silanes and Their Metal Complexes

Sun Wenyan; Wang Dengxu; Lai Qingling; Zhang Jie; Feng Shengyu*   

  1. (School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China)
  • Received:2009-03-02 Revised:2009-06-11 Online:2010-03-24 Published:2010-03-18
  • Contact: Feng Shengyu E-mail:fsy@sdu.edu.cn

硅原子具有空的3d轨道，可以作为电子接受体，这样就赋予了有机硅化合物独特的性质。在硅原子上引入官能化基团的小分子化合物称为官能化硅烷。近年来官能化硅烷及其配位化合物引起了化学工作者的重视，在光学、电学、催化等方面得到广泛的应用。按照官能化基团的不同，官能化硅烷可以分为含烯基、炔基、芳环等基团的π型官能化硅烷和含N、O、P、S等杂原子的官能化硅烷两类。本文概括了官能化硅烷合成方法，总结了其配合物的制备途径及研究进展，并对其研究和发展方向进行了展望。

关键词： 官能化硅烷, 金属配合物, 配位聚合物, 含硅配合物

Silicon atom can be used as electron acceptor owing to the unoccupied 3d orbitals. This feature endowed organosilicon compounds with unique characters. Thus, functionalized silanes and their metal complexes have attracted much attention and have been extensively applied in many fields such as electronic, photoluminescence, catalytic and so on. Π-type and heteroatom-type functionalized silanes are introduced in this review. The former contains groups such as alkenyl, alkynyl, aromatic rings, etc., while the latter consists of nitrogen, oxygen, sulfur and phosphorus-containing functionalized silanes. The synthesis and progress of these two types functinalized silanes and their complexes are generalized in this article. The future of this research field is also prospected.

Contents
1 Π-type functionalized silanes and their complexes
2 Heteroatom-type functionalized silanes and their complexes
2.1 Nitrogen-containing functionalized silanes
2.2 Oxygen-containing functionalized silanes
2.3 Sulfur-containing functionalized silanes
2.4 Phosphorus-containing functionalized silanes
3 Conclusion and prospects

Key words: functionalized silanes, metal complexes, coordination polymers, silicon-containing complexes

中图分类号: 

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