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化学进展 2010, Vol. 22 Issue (0203): 388-399 前一篇   后一篇

• 综述与评论 •

两亲性杯芳烃的超分子自组装*

梁清;官冰;江明**   

  1. （聚合物分子工程教育部重点实验室 复旦大学高分子科学系 上海 200433）
  • 收稿日期:2009-08-06 修回日期:2009-09-04 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 江明 E-mail:mjiang@fudan.edu.cn
  • 基金资助:

    基于主客体分子识别的超分子聚合与大分子自组装;基于包结络合作用的金纳米粒子的可逆聚集及与高分子的自组装

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Supramolecular Self-Assembly of Amphiphilic Calixarenes

Liang Qing; Guan Bing; Jiang Ming**   

  1. (The Key Laboratory of Molecular Engineering of Polymers , Ministry of Education , Department of Macromolecular Science , Fudan University , Shanghai 200433 , China)
  • Received:2009-08-06 Revised:2009-09-04 Online:2010-03-24 Published:2010-03-18
  • Contact: Jiang Ming E-mail:mjiang@fudan.edu.cn

本文综述了两亲性杯芳烃分子在不同维数下的组装研究的进展，主要包括零维组装（囊泡、胶束、树枝状分子和分子箱）、一维组装（纳米管，纳米线及纤维）和二维组装（LB膜、超薄分离膜及界面组装）；探讨了不同维数下组装体的形成机理和驱动力，主要包括氢键作用、金属配位作用、静电作用、包结络合作用以及疏水相互作用；控制和调节不同维数下组装体的转变，有助于组装体材料的多方面的应用。

关键词： 杯芳烃, 自组装, 维数, 纳米尺度

Recent progress in self-assembly of calixarene derivatives in different dimensions has been reviewed. It mainly includes zero dimension assembly leading to capsules, micelles, dendrimers and molecular boxes, one dimension assembly to nanofibers, nanotubes and two dimension assembly to ultra-thin membranes and assemblies on interfaces, etc. The mechanisms and driving forces, which include hydrogen bonding, metal–ligand, electrostatic, host-guest and hydrophobic interactions, for the assembly and the transitions between assemblies with different dimensions have been discussed. The transitions can be controlled in order to meet the requirements in varies applications of the assembled materials.

Contens
1 Introduction
2 Zero dimension assembly of calixarene derivatives
2.1 The assembly based on hydrogen bonding interaction
2.2 The assembly based on metal-ligand interaction
2.3 The assembly based on hydrophobic interaction
3 One dimension assembly of calixarene derivatives
3.1 Nanofibers formed by metal-ligand interaction
3.2 Supramolecular polymers formed by host-guest interaction
3.3 One dimension assembly based on other interactions
4 Two dimension assembly of calixarene derivatives
4.1 Membrane assembly based on electrostatic interaction
4.2 Interface assembly based on host-guest interaction
4.3 Interface assembly based on other interactions
5 The transitions among different dimension assemblies of calixarene derivatives
5.1 The transition due to solvent polarity
5.2 The transition due to competitive guests
5.3 The transition due to concentration changes
5.4 The transition due to changes in chemical structures
6 Expectations

Key words: calixarene, self-assembly, dimension, nanoscale

中图分类号: 

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摘要

两亲性杯芳烃的超分子自组装*