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化学进展 2010, Vol. 22 Issue (0203): 376-383 前一篇   后一篇

• 综述与评论 •

白光LED用氮（氧）化合物荧光粉*

张梅1,2**;何鑫1;丁唯嘉3;王静2   

  1. (1. 五邑大学功能材料研究所 江门 529030；2. 中山大学化学与化学工程学院 广州 510275；3. 华南农业大学理学院 广州 510642)
  • 收稿日期:2009-04-01 修回日期:2009-04-28 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 张梅 E-mail:zmjenny@163.com
  • 基金资助:

    白光发光二极管（LED）用稀土掺杂复合氮氧化物的合成及发光性质的研究

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Oxynitride and Nitride Phosphors for White LEDs

Zhang Mei 1,2**; He Xin 1;  Ding Wei Jia 3;  Wang Jing2   

  1. (1. Institute of Functional materials, WuYi University, Jiangmen 529020, China; 2. School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China; 3. College of Science, South China Agricultural University, Guangzhou 510642, China )
  • Received:2009-04-01 Revised:2009-04-28 Online:2010-03-24 Published:2010-03-18
  • Contact: Zhang Mei E-mail:zmjenny@163.com

本文综合评述近年来氮（氧）化合物荧光粉的制备方法、发光性质、机理及其在白光LED中的应用情况。这类荧光粉因其结构的多样性和电子云扩大效应的影响，一般在紫外-蓝光区具有高的吸收效率，并且随着基质和激活离子的改变，发射光谱可覆盖整个可见光区域，因此它们适用于荧光粉转换型白光LED。利用氮（氧）化合物封装的白光LED具有高的发光效率、色坐标稳定性、显色指数和可调节的色温，进一步表明它们将是一类在白光LED上非常适用的材料。最后本文指出了氮（氧）化合物荧光粉研究中尚未解决的问题。

关键词： 氮化物, 氮氧化合物, 荧光粉, 白光发光二极管

In this paper, we introduce the preparation, crystal structure, Luminescence properties and applications for white light-emitting diodes (LEDs) of nitride and oxynitride phosphors. These phosphors strongly absorb UV-to-Blue light, and can emit blue-to-red light because of their structural versatility and the nephelauxetic effect. Thus, they are suitable for white LEDs fabricated with near ultraviolet and blue LED. The nitride and oxynitride phosphors has been proved its superior suitability for white LEDs and can be used in bichromatic or multichromatic LEDs with excellent properties of high luminous efficacy, chromatic stability, rending index and tuning color temperature. The trends of research and development of nitride and oxynitride phosphors are also indicated in this review.

Contents
1 Introduction
2 Synthesis methods of oxynitride and nitride phosphors
2.1 High-temperature solid-state reaction
2.2 Gas-reduction and nitridation
2.3 Carbothermal reduction and nitridation
2.4 Reducing agents reduction and nitridation
3 The luminescence properties of oxynitride and nitride phosphors, and application in white LED
3.1 Metal nitridosilicates phosphors
3.2 Metal oxonitridosilicates phosphors
3.3 Metal nitridoaluminosilicates phosphors
3.4 Metal oxonitridoaluminosilicates phosphors
4 Summary and prospects

Key words: nitride, oxynitride, phosphors, white LED

中图分类号: 

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摘要

白光LED用氮（氧）化合物荧光粉*