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化学进展 2010, Vol. 22 Issue (0203): 309-314 前一篇   后一篇

• 综述与评论 •

基于Eyring反应速率理论的溶液粘度模型

房升*   

  1. (浙江工商大学食品与生物工程学院    杭州310035)
  • 收稿日期:2009-04-15 修回日期:2009-06-18 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 房升 E-mail:fszjgsu@gmail.com
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Viscosity Model for Mixtures Based on Eyring’s Absolute Reaction Theory

Fang Sheng*   

  1. (College of Food Science and Biotechnology Engineering, Zhejiang Gongshang University, Hangzhou 310035, China)
  • Received:2009-04-15 Revised:2009-06-18 Online:2010-03-24 Published:2010-03-18
  • Contact: Fang Sheng E-mail:fszjgsu@gmail.com

溶液粘度的关联、预测模型和理论研究，在化学工程和溶液热力学理论中占有重要的地位。本文对基于Eyring反应速率理论的溶液粘度模型研究进行了概述。在基于Eyring粘度方程的基础上，分别介绍了通过溶液相平衡关系、基团贡献法和过量函数模型来计算混合物粘度的方法。最后对这3方面进行展望，提出了进一步发展基于Eyring理论的粘度模型研究建议。

关键词： Eyring反应速率理论, 粘度, 热力学, 基团贡献法, 过量函数

The correlation and prediction of viscosity for mixtures play an important role in the chemical engineering and solution thermodynamic studies. In this work, the development of viscosity models for mixtures based on Erying’s absolute reaction theory is reviewed. These models include prediction methods based on the relationship between the free energy of activation for viscous flow and the phase equilibrium properties for mixtures, the group contribution UNIFAC-VISCO and ASOG-VISCO methods. The correlation models based on the using of numerous Gibbs free energy approach to calculate free energy of activation for viscous flow in Erying’s viscosity equation are also introduced. An outlook on the future development of viscosity model based on Erying’s absolute reaction theory is given at last.

Contents
1 Introduction
2 Eyring’s theory of liquid viscosity
3 Model for calculating viscosities of liquid mixtures
3.1 Prediction of viscosities using phase equilibrium data
3.2 Group contribution methods for predicting kinematic viscosities
3.3 Correlation models based on Eyring’s theory and excess Gibbs free energy eqautions
4 Suggestions and future work
4.1 Improving the quantitative relationship between transport and thermodynamic properties
4.2 Extension of the group contribution methods
4.3 Improving the correlation methods with simplicity and accuracy

Key words: Eyring’s absolute rate theory, viscosity, thermodynamics, group contribution, excess Gibbs free energy function

中图分类号: 

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[ 1 ] 　Poling B E, Prausnitz J M, O'Connell J P. Properties of Gases and Liquids. 5 th ed. NY: McGraw Hill, 2001
[ 2 ] 　Monnery W D, Svrcek W Y, Mehrotra A K. Canadian Journal of Chemical Engineering, 1995, 73: 3—40
[ 3 ] 　Mehrotra A K, Monnery W D, SvrcekW Y. Fluid Phase Equi libria, 1996, 117: 344—355
[ 4 ] 　Eyring H. J. Chem. Phys. , 1936, 4: 283—291
[ 5 ] 　Glasstone S, Laidler K J, Eyring H. The Theory of Rate Processes: The Kinetics of Chemical Reactions, Viscosity, Diffusion and Electrochemical Phenomena. NY: McGraw-Hill, 1941
[ 6 ] 　Rother M, Bittrich H J. Z. Phys. Chem. , 1967, 235:159—204
[ 7 ] 　岑沛霖(Cen P L) , 朱自强( Zhu Z Z) . 浙江大学学报( Journal of Zhejiang University) , 1984, 18 (4) : 1—7
[ 8 ] 　李学民(Li X M) , 陈钟秀(Chen Z X) . 化学工程(Chemical Engineering) , 1999, 27 (4) : 52—54
[ 9 ] 　Wei I C, Rowley R L. Chem. Eng. Sci. , 1985, 40: 401—408
[ 10 ] 　Cao W, Knudsen K, Fredenslund A, Rasmussen P. Ind. Eng.Chem. Res. , 1993, 32: 2088—2092
[ 11 ] 　Chevalier J L, Petrino P, Gaston-Bonhomme Y. Chem. Eng.Sci. , 1988, 43: 1303—1309
[ 12 ] 　Gaston-Bonhomme Y, Petrino P, Chevalier J L. Chem. Eng.Sci. , 1994, 49: 1799—1806
[ 13 ] 　Rodriguez A, Canosa J, Domínguez A, Tojo J. Fluid Phase Equilibria, 2004, 216: 167—174
[ 14 ] 　González B, Domínguez A, Tojo J. J. Chem. Eng. Data, 2006,51: 1076—1087
[ 15 ] 　Yang C S, Lai H X, Liu Z G, Ma P S. J. Chem. Eng. Data,2006, 51: 1345—1351
[ 16 ] 　González B, Domínguez A, Tojo J. J. Chem. Thermodynamics,2006, 38: 707—716
[ 17 ] 　González B, Calvar N, Domínguez A, Tojo J. J. Chem. Thermodynamics, 2007, 39: 322—334
[ 18 ] 　Bandrés I, Lahuerta C, Villares A, Martín S, Lafuente C. Int.J. Thermophys. , 2008, 29: 457—467
[ 19 ] 　Tochigi K, Yoshino K, Rattan V K. Int. J. Thermophys. ,2005, 26: 413—419
[ 20 ] 　Petrino P J, Gaston-Bonhomme Y, Chevalier J L. J. Chem.Eng. Data, 1996, 40: 136—140
[ 21 ] 　González B, Calvar N, Gomez E, Domínguez A. J. Chem.Thermodyn. , 2007, 9: 1578—1588
[ 22 ] 　Safi A, Nicolas C, Neau E, Chevalier J L. J. Chem. Eng. Data, 2008, 53: 444—448
[ 23 ] 　Kijevcanin M L J, Kostic V Z, Radovic I R, Djordjevic B D,Serbanovic S P. Chemical Industry & Chemical Engineering Quarterly, 2008, 14: 223—226
[ 24 ] 　Schrodt J T, Akel R M. J. Chem. Eng. Data, 1989, 34: 8—13
[ 25 ] 　McAllister R A. A ICHE, 1960, 6: 427—431
[ 26 ] 　Heric E L. J. Chem. Eng. Data, 1966, 11: 67—68
[ 27 ] 　Martins R J, Márcio J E, Oswaldo E B. Ind. Eng. Chem.Res. , 2000, 39: 849—854
[ 28 ] 　Fang S, Zhao C X, He C H, Liu J Q, Sun J H. J. Chem. Eng.Data, 2008, 53: 2718—2720
[ 29 ] 　Martins R J, Márcio J E, CardosoM, Oswaldo E B. Ind. Eng.Chem. Res. , 2001, 40: 1271—1275
[ 30 ] 　Novak L T. Ind. Eng. Chem. Res. , 2003, 42: 1824 —1826
[ 31 ] 　Novak L T. Ind. Eng. Chem. Res. , 2004, 43: 2602—2604
[ 32 ] 　Novak L T, Chen C C, Song Y H. Ind. Eng. Chem. Res. ,2004, 43: 6231—6237
[ 33 ] 　Sadeghi R. J. Chem. Thermodyn. , 2005, 37: 445—448
[ 34 ] 　Bosse D, Bart H J. Ind. Eng. Chem. Res. , 2005, 44: 8428—8435
[ 35 ] 　牟天成(Mu T C) , Gmehling J. 化学进展( Progress in Chemistry) , 2008, 20 (10) : 1487—1494
[ 36 ] 　Peters M, Greiner L, Leonhard K. A IChE J. , 2008, 54:2729—2734
[ 37 ] 　周永祥( Zhou Y X) , 彭昌军( Peng C J ) , 黑恩成(Hei E C) ,刘洪来(Liu H L ) . 石油化工( Petrochemical Technology) ,2006, 35 (11) : 1063—1068
[ 38 ] 　Geng Y F, Chen S L, Wang T F, Yu D H, Peng C J, Liu H L,Hu Y. J. Mol. Liq. , 2008, 143: 100—108
[ 39 ] 　寇元(Kou Y) , 何玲(He L) . 化学进展( Progress in Chemistry) , 2008, 20 (1) : 5—10
[ 40 ] 　Plaquevent J C, Levillain J, Guillen F, Malhiac C, Gaumont A C. Chem. Rev. , 2008, 108: 5035—5060
[ 41 ] 　应安国(Ying A G) , 陈新志(Chen X Z) , 叶伟东(Ye W D) ,张定丰( Zhang D F) , 刘泺(Liu L) , 陈建辉(Chen J H) . 化学进展( Progress in Chemistry) , 2008, 20 (11) : 1642—1650
[ 42 ] 　Dong Q, Muzny C D, Kazakov A, Diky V, Magee J W, Wide gren J A, Chirico R D, Marsh K N, FrenkelM. J. Chem. Eng.Data, 2007, 52: 1151—1159
[ 43 ] 　Lee M J, Lin T K, Hwang S M. J. Chin. Inst. Chem. Eng. ,1998, 29: 73—83
[ 44 ] 　Lee M J, Chiu J Y, Hwang S M, Lin H M. Ind. Eng. Chem.Res. , 1999, 38: 2867—2876
[ 45 ] 　Lee L S, Lee Y S. Fluid Phase Equilibria, 2001, 181: 47—58
[ 46 ] 　Lei Q F, Hou Y C, Lin R S. Fluid Phase Equilibria. , 1999,140: 221—231
[ 47 ] 　Lei Q F, Hou Y C. Fluid Phase Equilibria. , 1999, 154: 153—163
[ 48 ] 　Ricardo M S, Fernando G S, Otilio H G. A IChE J. , 2003, 49:799—804
[ 49 ] 　Prausnitz J M, Lichtenthaler R N, De Azevedo E G. Molecular Thermodynamics of Fluid-Phase Equilibria. 3 rd ed. NJ: Prentice-Hall, 1998
[ 50 ] 　Gmehling J, Lohmann J, Jakob A, Li J D, Joh R. Ind. Eng.Chem. Res. , 1998, 37: 4876—4882
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