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化学进展 2010, Vol. 22 Issue (01): 51-57 前一篇   后一篇

• 综述与评论 •

含钒无机有机杂化材料的合成、结构与性质

刘金丽;周荫庄*   

  1. (首都师范大学化学系  北京100048)
  • 收稿日期:2009-02-16 修回日期:2009-04-06 出版日期:2010-01-24 发布日期:2010-01-07
  • 通讯作者: 周荫庄 E-mail:zhouyz7813@x263.net
  • 基金资助:

    北京市教育委员会科技发展计划面上项目

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Synthesis, Structures and Properties of Inorganic-Organic Hybrid Polyoxovanadate

Liu Jinli;  Zhou Yinzhuang*   

  1. (Department of Chemistry, Capital Normal University, Beijing 100048, China)
  • Received:2009-02-16 Revised:2009-04-06 Online:2010-01-24 Published:2010-01-07
  • Contact: Zhou Yinzhuang E-mail:zhouyz7813@x263.net
  • Supported by:

    Project Supported by Scientific Research Common Program of Beijing Municipal Commission of Education

含钒无机有机杂化材料的结构复杂多样，在吸附、氧化还原、电化学、催化、光学、磁学以及多孔、手性材料研究等方面应用前景广阔，引起人们广泛关注。本文综述了含钒无机有机杂化材料研究的最新进展，介绍了合成含钒无机有机杂化材料的主要方法，按照有机组分与无机骨架作用的方式分类总结了含钒无机有机杂化材料的结构，介绍了其在离子交换、电化学、磁学、光学、催化等方面的应用，并展望了该类材料的研究前景和意义。

关键词： 钒多酸, 无机有机杂化材料, 合成, 结构, 性质

Inorganic-organic hybrid polyoxovanadate have various structures, and considerable efforts have been devoted to the research of these compounds due to their wide potential applications to material science as adsorption, redox, electronic, catalytic, luminescent, magnetic, porous, and chiral materials. The research progress of inorganic-organic hybrid polyoxovanadate are reviewed in this paper. The synthesis methods of these complexes are introduced. The structures are summarized according to the mode of organic components and inorganic framework. The potential applications in ion exchange, electrochemistry, magnetism, luminescent material and catalyst are commented. The research of these materials are also prospected.

Contents
1 The synthesis of inorganic-organic hybrid polyoxovanadate
2 The structures of inorganic-organic hybrid polyoxovanadate
2.1 Organic components as charge compensating cations, template agents, or structure directing agents
2.2 Organic components as ligands coordinated to metal centers to decorate/connect the framework
2.3 Phosphonic acids and carboxylic acids as ligands coordinated to metal centers to form hybrid framework
3 Properties of inorganic-organic hybrid polyoxovanadate
4 The outlook of inorganic-organic hybrid polyoxovanadate

Key words: polyoxovanadate, inorganic-organic hybrid, synthesis, structure, properties

中图分类号: 

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