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化学进展 2010, Vol. 22 Issue (01): 32-43 前一篇   后一篇

• 综述与评论 •

介孔氧化铝的制备及应用*

杨泠;冯炫;刘应亮**   

  1. （暨南大学化学系 广州  510632）
  • 收稿日期:2008-12-14 修回日期:2009-04-09 出版日期:2010-01-24 发布日期:2010-01-07
  • 通讯作者: 刘应亮 E-mail:tliuyl@jnu.edu.cn
  • 基金资助:

    广东省自然科学基金团队项目(No. 05200555)资助;省级资助

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Preparation and Application of Mesoporous Alumina

Yang Ling;  Feng Xuan;  Liu Yingliang**   

  1. (Department of Chemistry, Jinan University, Guangzhou 510632, China)
  • Received:2008-12-14 Revised:2009-04-09 Online:2010-01-24 Published:2010-01-07
  • Contact: Liu Yingliang E-mail:tliuyl@jnu.edu.cn

本文介绍了介孔氧化铝（MA）的各种制备方法，概括了 MA 制备的分析表征方法，如 TEM、SAED、XRD、LAXRD、气体吸附-脱附、DT-TGA 等。通过平均孔径、比表面积、MA 形貌等因素，讨论和总结了制备方法、铝源、模板剂、反应物配比、pH值和后处理方法等对 MA 制备和热稳定性的影响，综述了近年来 MA 的研究和应用进展，并对今后的研究方向进行了展望。

关键词： 介孔氧化铝, 制备, 热稳定性, 比表面积

This paper has reviewed recent progress in preparation, characterization and application of mesoporous alumina (MA). We introduce the preparation methods of MA contrastively and respectively, and overview the post treatment method of precursors. Subsequently, by contrasting the average pore size, specific surface areas and morphology of MA, we discuss the influence factors on the preparation and thermal stability of MA, which involve preparation method, aluminum sources, template, reactant ratio, pH value, post treatment method of precursors and so on. In addition, analysis and characterization methods utilized in preparation of MA, including transmission electron microscopy(TEM) and selected area electron diffraction(SAED), X-ray powder diffraction(XRD) and low angle X-ray powder diffraction(LAXRD), gas adsorption-desorption method, different thermal and thermo gravimetry analysis(DT-TGA) and 27Al magic angle spinning nuclear magnetic resonance(27Al MAS NMR), are introduced in detail. Meanwhile, the development trend of preparation and application of MA for the field of catalytic, adsorption, optics and other fields is prospected.

Contents
1 Introduction
2 Preparation methods of MA
2.1 Hydrothermal method
2.2 Sol-gel method
2.3 Precipitation method
2.4 Micro-emulsion method
2.5 Ionic liquid method
2.6 Hard template method
2.7 Other methods and some combinatory methods
2.8 Post treatment method
3 Influence factors in preparation of MA and thermal stability of MA
3.1 Influence of different reaction conditions
3.2 Thermal stability of MA
3.3 Control of morphology
4 Analysis and characterization methods
4.1 Transmission electron microscope (TEM) and selected area electron diffraction(SAED)
4.2 X-ray powder diffraction (XRD) and low angle X-ray powder diffraction (LAXRD)
4.3 Gas adsorption-desorption method
4.4 Different thermal and thermo gravimetry analysis (DT-TGA)
4.5 27Al magic angle spinning nuclear magnetic resonance (27Al MAS NMR)
5 Application of MA
5.1 Application in catalytic field
5.2 Application in adsorption field
5.3 Application in optical field
5.4 Application in other fields
6 Prospects

Key words: mesoporous alumina, preparation, thermal stability, specific surface area

中图分类号: 

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摘要

介孔氧化铝的制备及应用*