English
往期目录
新闻公告
More
化学进展 2010, Vol. 22 Issue (01): 19-31 前一篇   后一篇

• 综述与评论 •

低温燃料电池氧电极催化剂*

原鲜霞**;夏小芸;曾鑫;张慧娟;马紫峰   

  1. (上海交通大学化学工程系 上海 200240)
  • 收稿日期:2009-03-03 修回日期:2009-05-26 出版日期:2010-01-24 发布日期:2010-01-07
  • 通讯作者: 原鲜霞 E-mail:yuanxx@sjtu.edu.cn
  • 基金资助:

    国家973项目 (国家重点基础研究发展计划);国家自然科学基金

下载PDF ( 1678 ) 引用
导出

Catalysts for Oxygen Electrode of Low Temperature Fuel Cells

Yuan Xianxia**; Xia Xiaoyun; Zeng Xin; Zhang Huijuan; Ma Zifeng   

  1. (Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China)
  • Received:2009-03-03 Revised:2009-05-26 Online:2010-01-24 Published:2010-01-07
  • Contact: Yuan Xianxia E-mail:yuanxx@sjtu.edu.cn
  • Supported by:

    National Basic Research Program of China;National Natural Science Foundation of China

氧电极催化剂及缓慢的阴极氧还原动力学是制约低温燃料电池商业化的关键瓶颈因素之一。为此，国内外研究者近年来从提高低温燃料电池氧电极催化剂的催化活性和稳定性、降低催化剂的成本、发展非贵金属氧还原催化剂等方面开展了大量的研究工作，有力地促进了低温燃料电池的发展进程。本文在简要介绍低温燃料电池氧电极反应机理的基础上，从催化剂载体、贵金属及其合金催化剂、金属大环化合物及M-N/C类催化剂和过渡金属硫族化合物类催化剂等方面详细综述了低温燃料电池氧电极催化剂近年来的主要研究进展，并指出了各类催化剂目前尚待解决的问题和发展方向。

关键词： 低温燃料电池, 氧还原反应, 氧电极, 催化剂

The slow kinetics of oxygen reduction reaction (ORR) at cathode electrode of low temperature fuel cells (LTFCs) and the electro-catalysts are main factors impeding the commercialization of LTFCs. In recent years, worldwide researchers have maken much effort to improve the activity and durability of the cathode catalysts, to decrease cost of the catalysts, and to develop non-noble-metal electro-catalysts for LTFCs. In the present paper, research progress of catalyst support, noble-metal and alloyed catalysts, and non-noble-metal catalysts including metal-macrocyclic-compound, M-N/C catalysts and transitional-metal-chalcogenide for the oxygen electrode in LTFCs have been systematically reviewed in addition to a brief introduction of the reaction mechanism of ORR at cathode electrode of LTFCs. The urgent problems and future research focuses for each kind of catalysts have been proposed.

Contents
1 Introduction
2 Reaction mechanism of oxygen electrode in low temperature fuel cells
3 Research of catalysts for oxygen electrode in low temperature fuel cells
3.1 Catalyst support
3.2 Noble-metal and the alloyed catalysts
3.3 Non-noble-metal catalysts
4 Summary

Key words: low temperature fuel cells(LTFCs), oxygen reduction reaction(ORR), oxygen electrode, catalysts

中图分类号: 

()

[ 1 ] 　Kinoshita K. Electrochemical Oxygen Technology. New York:Wiley, 1992. 19—112
[ 2 ] 　杜娟(Du J) , 原鲜霞( Yuan X X) , 巢亚军(Chao Y J )等.稀有金属材料与工程(RareMetalMaterials and Engineering) .
[ 3 ] 　James R D, Summervlle D A, Basolo F. Chemical Reviews,1979, 79: 139—179
[ 4 ] 　Landsman D A, Luczak F J. Handbook of Fuel Cells ( eds.VielstichW, Lamm A, Gasteiger H A) , vol. 4. New York: Wi-ley, 2003
[ 5 ] 　Kim M, Park J N, Kim H, et al. Journal of Power Sources,2006, 163: 93—97
[ 6 ] 　Matsumoto T, Komatsu T, Arai K, et al. Chemical Communications, 2004, 840—841
[ 7 ] 　Wang X, LiW, Chen Z, et al. Journal of Power Sources, 2006,158: 154—159
[ 8 ] 　VillersD, Sun S H, ServentiA, et al. Journal of Physical Chemistry B, 2006, 110: 25916—25925
[ 9 ] 　Ismagilov Z R, KerzhentsevM A, Shikina N V, et al. Catalysis Today, 2005, 102 /103: 58—66
[ 10 ] 　Yuan F, Ryu H. Nanotechnology, 2004, 15 (10) : S596—S602
[ 11 ] 　Charreteur C, Jaouen F, Ruggeri S, et al. Electrochimica Acta,2008, 53: 2925—2938
[ 12 ] 　Du H, Gan L, Li B, et al. Journal of Physical Chemistry C,2007, 111: 2040—2043
[ 13 ] 　Yuan X, Chao Y J, Ma Z F, et al. Electrochemistry Communications, 2007, 9 (10) : 2591—2595
[ 14 ] 　Yoshitake T, Shimakawa Y, Kuroshima S, et al. Physica B-CondensedMatter, 2002, 323: 124—126
[ 15 ] 　Hyeon T, Han S, Sung Y E, et al. Angewandte Chemie International Edition, 2003, 42: 4352—4356
[ 16 ] 　Yu J S, Kang S, Yoon S B, et al. Journal of the American Chemical Society, 2002, 124: 9382—9383
[ 17 ] 　Ambrosio E P, Francia C, ManzoliM, et al. International Journal of Hydrogen Energy, 2008, 33 (12) : 3142—3145
[ 18 ] 　Fang B, Kim J K, Lee C, et al. Journal of Physical Chemistry C, 2008, 112 (2) : 639—645
[ 19 ] 　RajalakshmiN, Ryu H, ShaijumonMM, et al. Journal of Power Sources, 2005, 140: 250—257
[ 20 ] 　Matsumoto T, Komatsu T, Nakano H, et al. Catalysis Today,2004, 90: 277—281
[ 21 ] 　Li X, Hsing IM. Electrochimica Acta, 2006, 51: 5250—5258
[ 22 ] 　Shioyama H, Yamada Y, Ueda A, et al. Carbon, 2005, 43:2374—2378
[ 23 ] 　Shioyama H, Honjo K, Kiuchi M, et al. Journal of Power Sources, 2006, 161: 836—838
[ 24 ] 　Tran TD, Langer S H. Electrochimica Acta, 1993, 38: 1551—1554
[ 25 ] 　Wang H, Cote R, Faubert G, et al. Journal of Physical Chemistry B, 1999, 103: 2042—2049
[ 26 ] 　谢先宇(Xie X Y) , 马紫峰(Ma Z F) , 麻晓霞(Ma X X)等.无机化学学报( Chinese Journal of Inorganic Chemistry) ,2007, 23 (1) : 34—40
[ 27 ] 　Xie X Y, Ma Z F, Wu X, et al. Electrochimica Acta, 2007,52: 2091—2096
[ 28 ] 　George P P, Pol V G, Gedanken A, et al. Journal of Fuel Cell Science and Technology, 2008, 5 (4) : art. no. 041012
[ 29 ] 　Bashyam R, Zelenay P. Nature, 2006, 443 (7) : 63—66
[ 30 ] 　GiacominiM T, BalasubramanianM, Khalid S, et al. Journal of the Electrochemical Society, 2003, 150 (5) : A588—A593
[ 31 ] 　Ye S, Vijh A K. International Journal of Hydrogen Energy,2005, 30: 1011—1015
[ 32 ] 　Seger B, Kongkanand A, Vinodgopal K, et al. Journal of Electroanalytical Chemistry, 2008, 621: 198—204
[ 33 ] 　Ioroi T, Senoh H, Yamazaki S, et al. Journal of the Electrochemical Society, 2008, 155 (4) : B321—B326
[ 34 ] 　Park KW, Seol K S. Electrochemistry Communications, 2007,9: 2256—2260
[ 35 ] 　Koh S, ToneyM F, Strasser P. Electrochimica Acta, 2007, 52:2765—2774
[ 36 ] 　WatanabeM, Tsurumi K, Mizukami T, et al. Journal of the Electrochemical Society, 1994, 141: 2659—2668
[ 37 ] 　Xiong L, Manthiram A. Journal ofMaterials Chemistry, 2004,14: 1454—1460
[ 38 ] 　Xiong L, Manthiram A. Journal of the Electrochemical Society,2005, 152 (4) : A697—A703[ 39 ] 　Mukerjee S, Srinivasan S, Soriaga M P, et al. Journal of theElectrochemical Society, 1995, 142: 1409—1422
[ 40 ] 　MinM, Cho J, Cho K, et al. Electrochimica Acta, 2000, 45:4211—4217
[ 41 ] 　Antolini E, Salgado J R C, GizM J, et al. International Journal of Hydrogen Energy, 2005, 30: 1213—1220
[ 42 ] 　PaulusU A, Wokaun A, Scherer G G, et al. Electrochimica Acta, 2002, 47: 3787—3798
[ 43 ] 　Xiong L, Kannan A M, Manthiram A. Electrochemistry Communications, 2002, 4: 898—903
[ 44 ] 　Xiong L, He T. Electrochemistry Communication, 2006, 8:1671—1676
[ 45 ] 　Xie J, Wood D L, Wayne D M, et al. Journal of the Electrochemical Society, 2005, 152 (1) : A104—A113
[ 46 ] 　Yang H, Alonso-Vante N, Lamy C, et al. Journal of the Electrochemical Society, 2005, 152 (4) : A704—A709
[ 47 ] 　Yang H, Alonso-Vante N, Léger J M, et al. Journal of Physical Chemistry B, 2004, 108: 1938—1947
[ 48 ] 　Yang H, Coutanceau C, Léger JM, et al. Journal of Electroanalytical Chemistry, 2005, 576: 305—313
[ 49 ] 　YuanW, Scott K, Cheng H. Journal of Power Sources, 2006,163: 323—329
[ 50 ] 　Li H, Sun G, Li N, et al. Journal of Physical Chemistry C,2007, 111: 5605—5617
[ 51 ] 　Sode A, LiW, Yang Y, et al. Journal of the Physical Chemistry B, 2006, 110: 8715—8722
[ 52 ] 　Tseng C J, Lo S T, Lo S C, et al. Materials Chemistry and Physics, 2006, 100: 385—390
[ 53 ] 　Wang J, Yin G, Wang G, et al. Electrochemistry Communications, 2008, 10: 831—834
[ 54 ] 　Cambanis G, Chadwick D. App lied Catalysis, 1986, 25: 191—198
[ 55 ] 　Antolini E, Passos R R, Ticianelli E A. Electrochimica Acta,2002, 48: 263—270
[ 56 ] 　RohW, Cho J, Kim H. Journal of App lied Electrochemistry,1996, 26: 623—630
[ 57 ] 　Luczak F J, Landsman D A. US 4447506, 1984
[ 58 ] 　Tamizhmani G, Capuano GA. Journal of the Electrochemical Society, 1994, 141 (4) : 968—975
[ 59 ] 　Shukla A K, NeergatM, Bera P, et al. Journal of Electroanalytical Chemistry, 2001, 504: 111—119
[ 60 ] 　Luo J, KariukiN, Han L, et al. Electrochimica Acta, 2006, 51:4821—4827
[ 61 ] 　Lin Y, Cui X, Ye X. Electrochemisty Communications, 2005,7: 267—274
[ 62 ] 　Pattabiraman R. App lied CatalysisA: General, 1997, 153: 9—20
[ 63 ] 　Fernandez J L, Walsh D A, Bard A J. Journal of American Chemical Society, 2005, 127: 357—365
[ 64 ] 　MustainW E, Kep ler K, Prakash J. Electrochemistry Communications, 2006, 8: 406—410
[ 65 ] 　Savadogo O, Lee K, Oishi K, et al. Electrochemistry Communications, 2004, 6: 105—109
[ 66 ] 　TarasevichM R, Chalykh A E, BogdanovskayaV A, et al. Electrochimica Acta, 2006, 51: 4455—4462
[ 67 ] 　Demarconnay L, Coutanceau C, Leger J M. Electrochimica Acta, 2004, 49: 4513—4521
[ 68 ] 　Meng H, Shen P K. Electrochemistry Communications, 2006,8: 588—594
[ 69 ] 　Aoun S B, Dursun Z, Sotomura T, et al. Electrochemistry Communications, 2004, 6: 747—752
[ 70 ] 　El2DeabM S, Sotomura T, Ohsaka T. Electrochemistry Communications, 2005, 7: 29—34
[ 71 ] 　Yagi I, Ishida T, Uosaki K. Electrochemistry Communications,2004, 6: 773—779
[ 72 ] 　Prakash J, Joachin H. Electrochimica Acta, 2000, 45:2289—2296
[ 73 ] 　Michell D, Rand D A J, Woods R. Journal of Electroanalytical Chemistry, 1978, 89: 11—27
[ 74 ] 　Galizzioli D, Tantardini F, Trasatti S. Journal of App lied Electrochemistry, 1974, 4: 57—67
[ 75 ] 　Tributsch H, BronM, HilgendorffM, et al. Journal of App lied Electrochemistry, 2001, 31: 739—748
[ 76 ] 　Liu L, Lee J W, Popov B N. Journal of Power Sources, 2006,162: 1099—1103
[ 77 ] 　Song E, Shi C, Anson F C. Langmuir, 1998, 14: 4315—4312
[ 78 ] 　Yu H Z, Baskin J S, Steiger B, et al. Journal of the American Chemical Society, 1999, 121: 484—485
[ 79 ] 　Biloul A, Gouèrec P, SavyM, et al. Journal ofApp lied Electrochemistry, 1996, 26: 1139—1146
[ 80 ] 　Faubert G, CétéR, GuayD, et al. Electrochimica Acta, 1998,43 (3 /4) : 341—353
[ 81 ] 　Lalande G, Tamizhmani G, CétéR, et al. Journal of the Electrochemical Society, 1995, 142 (4) : 1162—1168
[ 82 ] 　Yuasa M, Yamaguchi A, Oyaizu K, et al. Polymers for Advanced Technologies, 2005, 16: 702—705
[ 83 ] 　Okada T, FokitaM, YuasaM, et al. Journal of the Electrochemical Society, 1998, 145: 815—822
[ 84 ] 　Gouèrec P, Biloul A, Contamin O, et al. Journal of Electroanalytical Chemistry, 1997, 422: 61—75
[ 85 ] 　Gojkovic S L, Gup ta S, Sanvinell R F. Journal of Electroanalytical Chemistry, 1999, 462: 63—72
[ 86 ] 　Faubert G, Lahande G, CétéR, et al. Electrochimica Acta,1996, 41: 1689—1701
[ 87 ] 　Lalande G, CétéR, Tamizhmani G, et al. Electrochimica Acta,1995, 40: 2635—2646
[ 88 ] 　Martins-AlvesM C, Dodelet J P, GuayD, et al. Journal of Physical Chemistry, 1992, 96: 10898—10905
[ 89 ] 　LadouceurM, Lalande G, GuayD, et al. Journal of the Electrochemistry Society, 1993, 140: 1974—1981
[ 90 ] 　Lalande G, Faubert G, CétéR, et al. Journal of Power Sources,1996, 61: 227—237
[ 91 ] 　Zhang H J, Yuan X, WenW, et al. Electrochemistry Communications, 2009, 11: 206—208
[ 92 ] 　Kadish KM, Frémond L, Ou Z, et al. Journal of the American Chemical Society, 2005, 127: 5625—5631
[ 93 ] 　Kadish KM, Frémond L, Burdet F, et al. Journal of Inorganic Biochemistry, 2006, 100: 858—868
[ 94 ] 　MaitiN, Lee J, Kwon S J, et al. Polyhedron, 2006, 25: 1519—1530
[ 95 ] 　Kadish KM, Shao J, Ou Z, et al. Inorganic Chemistry, 2005,44 (19) : 6744—6754
[ 96 ] 　Gup ta S, Tryk D, Bae I, et al. Journal ofApp lied Electrochemistry, 1989, 19: 19—27
[ 97 ] 　OhmsD, Herzog S, Franke R, et al. Journal of Power Sources,1992, 38: 327—334
[ 98 ] 　LefèvreM, Dodelet J P, Bertrand P. Journal of Physical Chemistry B, 2002, 106: 8705—8713
[ 99 ] 　LefèvreM, Dodelet J P, Bertrand P. Journal of Physical Chemistry B, 2005, 109: 16718—16724
[ 100 ] Jaouen F, Lefèvre M, Dodelet J P, et al. Journal of Physical Chemistry B, 2006: 110, 5553—5558
[ 101 ] Lefèvre M, Dodelet J P. Electrochimica Acta, 2008, 53:8269—8276
[ 102 ] Médard C, LefèvreM, Dodelet J P, et al. Electrochimica Acta,2006, 51: 3202—3213
[ 103 ] CaféR, Lalande G, GuayD, et al. Journal of the Electrochemical Society, 1998, 145 (7) : 2411—2418
[ 104 ] Lalande G, CétèR, GuayD, et al. Electrochimica Acta, 1997,42 (9) : 1379—1388
[ 105 ] BronM, Fiechter S, HilgendorffM, et al. Journal ofApp lied Electrochemistry, 2002, 32: 211—216
[ 106 ] Wang H, CétèR, Faubert G, et al. Journal of Physical Chemistry B, 1999, 103: 2042—2049
[ 107 ] Charreteur F, Ruggeri S, Jaouen F, et al. Electrochimica Acta,2008, 53: 6881—6889
[ 108 ] Maruyama J, Abe I. Chemistry of Materials, 2005, 17:4660—4667
[ 109 ] Alonso-Vante N, Tributsch H. Nature, 1986, 323: 431—432
[ 110 ] Alonso-Vante N, Tributsch H, Solorza-Feria O. Electrochimica Acta, 1995, 40 (5) : 567—576
[ 111 ] Dassenoy F, Vogel W, Alonso-Vante N. Journal of Physical Chemistry B, 2002, 106: 12152—12157
[ 112 ] Cao D, Wieckowski A, Inukai J, et al. Journal of the Electrochemical Society, 2006, 153 (5) : A869—A874
[ 113 ] Lewera A, Inukai J, Zhou W P, et al. Electrochimica Acta,2007, 52: 5759— 5765
[ 114 ] Cheng H, YuanW, Scott K. Fuel Cells, 2007, 7: 16—20
[ 115 ] Cheng H, Yuan W, Scott K. Electrochimica Acta, 2006, 52:466—473
[ 116 ] PapageorgopoulosD C, Liu F, Conrad O. Electrochimica Acta,2007, 52: 4982—4986
[ 117 ] Colmenares L, Jusys Z, Behm R J. Journal of Physical Chemistry C, 2007, 111: 1273—1283
[ 118 ] Gonzalez-Huerta R G, Chavez-Carvayar J A, Solorza-Feria O.Journal of Power Sources, 2006, 153: 11—17
[ 119 ] Liu G, Zhang H. Journal of Physical Chemistry C, 2008, 112:2058—2065
[ 120 ] Gochi-ponce Y, Alonso-Nunez G, Alonso-Vante N. Electrochemistry Communications, 2006,
[ 121 ] Gong K, Du F, Xia Z, et al. Science, 2009, 323: 760—764
[1] 李佳烨, 张鹏, 潘原. 在大电流密度电催化二氧化碳还原反应中的单原子催化剂[J]. 化学进展, 2023, 35(4): 643-654.
[2] 邵月文, 李清扬, 董欣怡, 范梦娇, 张丽君, 胡勋. 多相双功能催化剂催化乙酰丙酸制备γ-戊内酯[J]. 化学进展, 2023, 35(4): 593-605.
[3] 徐怡雪, 李诗诗, 马晓双, 刘小金, 丁建军, 王育乔. 表界面调制增强铋基催化剂的光生载流子分离和传输[J]. 化学进展, 2023, 35(4): 509-518.
[4] 杨越, 续可, 马雪璐. 金属氧化物中氧空位缺陷的催化作用机制[J]. 化学进展, 2023, 35(4): 543-559.
[5] 叶淳懿, 杨洋, 邬学贤, 丁萍, 骆静利, 符显珠. 钯铜纳米电催化剂的制备方法及应用[J]. 化学进展, 2022, 34(9): 1896-1910.
[6] 王乐壹, 李牛. 从铜离子、酸中心与铝分布的关系分析不同模板剂制备Cu-SSZ-13的NH3-SCR性能[J]. 化学进展, 2022, 34(8): 1688-1705.
[7] 杨启悦, 吴巧妹, 邱佳容, 曾宪海, 唐兴, 张良清. 生物基平台化合物催化转化制备糠醇[J]. 化学进展, 2022, 34(8): 1748-1759.
[8] 贾斌, 刘晓磊, 刘志明. 贵金属催化剂上氢气选择性催化还原NOx[J]. 化学进展, 2022, 34(8): 1678-1687.
[9] 朱月香, 赵伟悦, 李朝忠, 廖世军. Pt基金属间化合物及其在质子交换膜燃料电池阴极氧还原反应中的应用[J]. 化学进展, 2022, 34(6): 1337-1347.
[10] 乔瑶雨, 张学辉, 赵晓竹, 李超, 何乃普. 石墨烯/金属-有机框架复合材料制备及其应用[J]. 化学进展, 2022, 34(5): 1181-1190.
[11] 张明珏, 凡长坡, 王龙, 吴雪静, 周瑜, 王军. 以双氧水或氧气为氧化剂的苯羟基化制苯酚的催化反应机理[J]. 化学进展, 2022, 34(5): 1026-1041.
[12] 刘洋洋, 赵子刚, 孙浩, 孟祥辉, 邵光杰, 王振波. 后处理技术提升燃料电池催化剂稳定性[J]. 化学进展, 2022, 34(4): 973-982.
[13] 沈树进, 韩成, 王兵, 王应德. 过渡金属单原子电催化剂还原CO2制CO[J]. 化学进展, 2022, 34(3): 533-546.
[14] 楚弘宇, 王天予, 王崇臣. MOFs基材料高级氧化除菌[J]. 化学进展, 2022, 34(12): 2700-2714.
[15] 景远聚, 康淳, 林延欣, 高杰, 王新波. MXene基单原子催化剂的制备及其在电催化中的应用[J]. 化学进展, 2022, 34(11): 2373-2385.
阅读次数
全文


摘要

低温燃料电池氧电极催化剂*