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化学进展 2010, Vol. 22 Issue (01): 113-118 前一篇   后一篇

• 综述与评论 •

聚萘的合成及其光电器件*

黄美荣;高鹏;李新贵**   

  1. (同济大学材料学院 先进土木工程材料教育部重点实验室 材料化学研究所 上海 200092)
  • 收稿日期:2009-01-13 修回日期:2009-06-04 出版日期:2010-01-24 发布日期:2010-01-07
  • 通讯作者: 李新贵 E-mail:adamxgli@yahoo.com
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Synthesis and Photoelectric Device of Polynaphthalene

Huang Meirong; Gao Peng; Li Xingui**   

  1. (Institute of Materials Chemistry, Key Laboratory of Advanced Civil Engineering Materials of the Ministry of Education, College of Materials Science and Engineering, Tongji University, Shanghai 200092，China)
  • Received:2009-01-13 Revised:2009-06-04 Online:2010-01-24 Published:2010-01-07
  • Contact: Li Xingui E-mail:adamxgli@yahoo.com

本文系统回顾和总结了化学方法制备聚萘的历史进程和研究成果， 包括上世纪六十年代的Lewis酸直接氧化萘单体缩聚法和最近的萘衍生物的Yamamoto法和Suzuki法。指出萘基格氏试剂中介法是高产率获得各种具有确定结构聚萘的有效方法；等离子体沉积法等可直接制备聚萘膜，从而避免了因聚萘的难溶、难熔而引起的加工成型问题；而Yamamoto法和Suzuki法则是合成可溶性聚萘衍生物的有效途径，且聚合物产物具有优异的荧光性能，荧光量子效率最高达0.96。对于萘在1,4- 和5,8-位同时链接形成的规整的一维石墨结构具有非常高的菲边缘碳和边缘碳密度，有望显示出比二维石墨材料更高的锂掺杂能力，另外其较强的蓝色荧光发射特性以及高温稳定性，聚萘在锂离子二次电池电极材料、聚合物发光二极管、耐高温材料等领域都将显示出诱人的应用前景。

关键词： 聚萘, 发光二极管, 二次电池

The development progress and the achievements in chemical preparation of polynaphthalene are systematically reviewed and summarized, including oxidative polycondensation of naphthalene monomer by Lewis acid catalysts developed in the last century and Yamamoto and Suzuki methods of naphthalene derivatives developed recently. It is pointed out that naphthalene-based Grignard metathesis is the effective way to obtain polynaphthalene having definite structure with high yield, while plasma deposition can directly form film which accordingly avoids the intractability arising from difficult dissolution and melting of polynaphthalene. Especially through Yamamoto and Suzuki methods, polynaphthalene derivatives with excellent solubility and high PL quantum efficiency up to 0.96 can be obtained. Polynaphthalene with one-dimensional graphite structure can be produced by coupling naphthalene unit at 1,4- and 5,8- simultaneously. The kind of polynaphthalene possesses high densities of both phenanthrene-edge carbon and edge carbon, which could be expected a higher Li doping capacity. Together with the strong blue fluorescence emitting characteristics and high thermal stability, the polymer reveals the promising future in fields of electrode material for Li-ion rechargeable battery, polymer light-emitting diode and high-temperature-resistant materials.

Contents
1 Introduction
2 Synthesis of polynaphthalene
2.1 Oxidative polycondensation of naphthalene by Lewis acid catalysts
2.2 Dehalogenation polycondensation of dihalogenated naphthalene catalysed by sodium
2.3 Grignard metathesis catalysed by Ni(Ⅱ)-complex
2.4 Plasma polymerization
2.5 Yamamoto and Suzuki polymerizations
3 Performance of polynaphthalene
3.1 High thermal stability of polynaphthalene
3.2 Fluorescence of polynaphthalene
4 Application of polynaphthalene
4.1 Polynaphthalene light-emitting diode
4.2 Polynaphthalene Li-ion rechargeable battery
5 Outlook

Key words: polynaphthalene, light emitting diode, rechargeable battery

中图分类号: 

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摘要

聚萘的合成及其光电器件*