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化学进展 2009, Vol. 21 Issue (6): 1364-1372 前一篇   

• 综述与评论 •

溴系阻燃剂在环境及人体中的存在和代谢转化*

张帆1;余应新1,2**;张东平1;吴明红3;盛国英1,2;傅家谟1,2   

  1. （1. 上海大学环境与化学工程学院环境污染与健康研究所 上海 200072；2. 中国科学院广州地球化学研究所有机地球化学国家重点实验室 广州 510640；3. 上海大学环境与化学工程学院上海射线应用研究所 上海 200444）
  • 收稿日期:2008-06-17 修回日期:2008-07-07 出版日期:2009-06-24 发布日期:2009-06-16
  • 通讯作者: 余应新 E-mail:yuyingxin@staff.shu.edu.cn
  • 基金资助:

    省级资助;国家自然科学基金

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Metabolism and Transformation of Brominated Flame Retardants Existing in Environment and Human Body

Zhang Fan1;Yu Yingxin1,2**;Zhang Dongping1;Wu Minghong3;Sheng Guoying1,2;Fu Jiamo1,2   

  1. (1. Institute of Environmental Pollution and Health, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200072, China|2. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China|3. Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China)
  • Received:2008-06-17 Revised:2008-07-07 Online:2009-06-24 Published:2009-06-16
  • Contact: Yu Yingxin E-mail:yuyingxin@staff.shu.edu.cn

溴系阻燃剂的广泛使用及其对环境和人体的危害，受到人们的广泛关注。本文简要介绍了在环境与生态系统及人体中存在的三种主要溴系阻燃剂：多溴联苯醚、六溴环十二烷和四溴双酚A，重点评述了它们在环境介质（污水、淤泥及沉积物）、生物体（微生物及动物）、人体中及光热作用下的代谢与转化，并详细介绍了其代谢途径及代谢产物。

关键词： 溴系阻燃剂, 多溴联苯醚, 六溴环十二烷, 四溴双酚A, 代谢转化

Brominated flame retardants (BFRs) are of great concern due to their widely use and adverse effects to environment and human. The existence for polybrominated diphenyl ethers(PBDEs), hexabromocyclododecanes(HBCDs), and tetrabromobisphenol A(TBBPA), three major kinds of BFRs found in environment and ecosystems and in human body are reviewed briefly. The degradation and biotransformation of them in environmental medium (wastewater, sludge and sediment), organism (microorganism and animals) and human body are focused. The degradation and biotransformation of them under light and heat are of concern also. The degradation pathway and metabolites of BFRs are introduced in detail. In addition, the future research and prospects are also discussed.

Contents
1 Introduction
2 Existing in the environment
2.1 PBDEs
2.2 HBCDs
2.3 TBBPA
3 Metabolism and transformation
3.1 PBDEs
3.2 HBCDs
3.3 TBBPA
4 Prospects

Key words: BFRs, PBDEs, HBCDs, TBBPA, metabolism and transformation

中图分类号: 

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