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化学进展 2009, Vol. 21 Issue (6): 1187-1198 前一篇   后一篇

• 综述与评论 •

Fe(II)自旋交叉分子材料*

朱敦如**;齐丽;程慧敏;沈旋;卢伟   

  1. (材料化学工程国家重点实验室  |南京工业大学化学化工学院    |南京 210009)
  • 收稿日期:2008-07-31 修回日期:2008-09-22 出版日期:2009-06-24 发布日期:2009-06-16
  • 通讯作者: 朱敦如 E-mail:zhudr@njut.edu.cn
  • 基金资助:

    国家自然科学基金

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Fe(II) Spin Crossover Molecule-Based Materials

Zhu Dunru**; |Qi Li; |Cheng Huimin; |Shen Xuan; |Lu Wei   

  1. (State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China)
  • Received:2008-07-31 Revised:2008-09-22 Online:2009-06-24 Published:2009-06-16
  • Contact: Zhu Dunru E-mail:zhudr@njut.edu.cn

自旋交叉配合物具有理想的分子双稳态，可用作新型的热开关、光开关和信息存储器件。本文对近三年来Fe(II)自旋交叉分子材料的重要研究进展进行了综述，主要讨论了转变温度在室温附近的Fe(II)自旋交叉配合物以及具有光致激发自旋态捕获(LIESST)效应和多功能的Fe(II)自旋交叉分子材料，并对Fe(II)自旋交叉分子材料的应用前景作了探讨。

关键词： 自旋交叉, Fe(II)配合物, LIESST效应, 多功能材料

Spin crossover complex has an ideal molecular bistability in which a single molecule or an assembly of molecules can be used as active elements in novel thermal switches, optical switches or information memory devices. The important progress over the past three years on Fe(II) spin crossover molecule-based materials is reviewed in this paper. These materials include the Fe(II) spin crossover complexes showing a spin transition close to room temperature, the Fe(II) spin crossover compounds with the light-induced excited spin state trapping (LIESST) effect and the multifunctional Fe(II) spin crossover materials with liquid crystalline properties, porous properties or electrical conductivity. The applications and perspectives of the Fe(II) spin crossover molecule-based materials are also discussed.

Contents
1 Introduction
2 Fe(II) spin crossover molecule-based materials showing Tc close to room temperature
3 Fe(II) spin crossover molecule-based materials with LIESST effect
4 Multifunctional Fe(II) spin crossover molecule-based materials
4.1 Fe(II) spin crossover materials with liquid crystalline properties
4.2 Porous Fe(II) spin crossover materials
4.3 Fe(II) spin crossover materials with electrical conductivity
5 Conclusions and perspectives

Key words: spin crossover, Fe(II) complexes, LIESST effect, multifunctional materials

中图分类号: 

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摘要

Fe(II)自旋交叉分子材料*