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化学进展 2009, Vol. 21 Issue (6): 1164-1170 前一篇   后一篇

• 综述与评论 •

环境刺激响应型表面活性剂*

解战峰1,2;冯玉军1**   

  1. (1. 中科院成都有机化学研究所|成都 610041;2. 中科院研究生院| 北京 100049)
  • 收稿日期:2008-06-16 修回日期:2008-11-10 出版日期:2009-06-24 发布日期:2009-06-16
  • 通讯作者: 冯玉军 E-mail:yjfeng@cioc.ac.cn
  • 基金资助:

    中科院“百人计划”、中科院“西部之光”在职博士生培养计划、四川省青年科技基金(07ZQ026-122)、四川省科技支撑计划(2008GZ0004)资助项目。;省级资助

Environmentally Stimuli-Responsive Surfactants

Xie Zhanfeng1,2|Feng Yujun1**   

  1. (1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China|2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China)
  • Received:2008-06-16 Revised:2008-11-10 Online:2009-06-24 Published:2009-06-16
  • Contact: Feng Yujun E-mail:yjfeng@cioc.ac.cn

表面活性剂在溶液中可通过自组装形成胶束、囊泡、液晶等多种有序结构。这些有序自组装结构在催化化学、材料制备、生物医药等领域有着重要而广泛的用途。控制和改变表面活性剂在溶液中的聚集方式对表面活性剂的应用具有重要的意义。近年来,通过对外界环境的调控来改变表面活性剂的物理化学性能如表面张力、聚集形式等研究已成为表面活性剂研究的一个新方向。本文以外界环境变化对表面活性剂在溶液中的聚集方式的影响为基础,介绍了可对环境刺激产生响应的表面活性剂的种类、结构、性能及研究进展,并总结了它们的结构与环境刺激响应性能之间的关系。

Surfactants can be self-assembled into organized structures such as micelles, vesicles, liquid-crystals in the solution. These organized structures have found broad applications ranging from catalysis, preparation of novel materials to biopharmaceutics. Controlling and changing the surfactant aggregation plays an important role for their applications. Recently, tuning the physicochemical properties of surfactants through regulating environmental condition represents a new direction in surfactant science. The recent progress of six types of environmentally stimuli-responsive surfactants, i.e., pH-, electrolyte-, organic molecule-, temperature-, photo-, and redox-stimuli responsive surfactants are reviewed, and the relationship between their responsive properties and molecular structures is discussed. The future trends of these surfactants are outlooked in this review.

Contents
1 The classification of stimuli-responsive surfactants
1.1 pH stimuli-responsive surfactants
1.2 Electrolyte stimuli-responsive surfactants
1.3 Organic molecule stimuli-responsive surfactants
1.4 Temperature stimuli-responsive surfactants
1.5 Photo stimuli responsive surfactants
1.6 Redox stimuli responsive surfactants
2 The application perspective of stimuli-responsive surfactants
2.1 Application in modifying solution rheology
2.2 Application in enhanced oil recovery
2.3 Application in chemical separation
2.4 Application in gene transfer
2.5 Application in cosolubilization
3 Conclusions

中图分类号: 

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摘要

环境刺激响应型表面活性剂*