English
往期目录
新闻公告
More
化学进展 2009, Vol. 21 Issue (6): 1134-1140 前一篇   后一篇

• 综述与评论 •

疏水缔合聚合物稳定乳状液的研究*

尉云平1;孙文彬2;孙德军1**   

  1. (1.山东大学胶体与界面化学教育部重点实验室 |山东济南 250100；2.中石化上海石油化工研究院 |上海 |201208)
  • 收稿日期:2008-06-23 修回日期:2008-10-15 出版日期:2009-06-24 发布日期:2009-06-16
  • 通讯作者: 孙德军 E-mail:djsun@sdu.edu.cn
  • 基金资助:

    863项目

下载PDF ( 1869 ) 引用
导出

Study of Emulsions Stabilized by Hydrophobically Associating Polymers

Wei Yunping1;  |Sun Wenbin2;  |Sun Dejun1**   

  1. (1.Key Laboratory for Colloid Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China|2.Shanghai Research Institute of Petrochemical Technology,Shanghai 201208,China)
  • Received:2008-06-23 Revised:2008-10-15 Online:2009-06-24 Published:2009-06-16
  • Contact: Sun Dejun E-mail:djsun@sdu.edu.cn

本文综述了近年来疏水缔合聚合物稳定乳状液的研究进展。论述了疏水缔合聚合物水溶液的性质，由于其较复杂的分子结构以及其分子主链上疏水基团的缔合作用，使其水溶液增稠的能力比小分子表面活性剂的增稠能力强的多。另外，对疏水缔合聚合物单独稳定乳状液的研究现状进行了介绍，其稳定乳状液的机理与小分子表面活性剂不同。同时讨论了疏水缔合聚合物与表面活性剂的相互作用，此类聚合物可与小分子表面活性剂通过静电和疏水缔合发生强烈的相互作用形成复合体系，并评述了其复配体系稳定乳状液的情况。最后总结了疏水缔合聚合物稳定乳状液的机理。

关键词： 疏水缔合聚合物, 乳状液, 表面活性剂

The progress of emulsions stabilized by hydrophobically associating polymers is summarized. We discuss solution properties of hydrophobically associating polymers, whose solution shows much better thickening ability than those of low-molecular-weight surfactants due to their large molecular structures and associations of hydrophobic groups on backbone. Researches about emulsions stabilized solely by hydrophobically associating polymers are summarized, the emulsification mechanisms differ from those of the low-molecular-weight surfactants. Meanwhile, we discuss the interactions between hydrophobially associating polymers and surfactants, this kind of polymer has strong interaction with small surfactants by forming complex to stabilize emulsions. The paper summarizes their application in stabilizing emulsions. Then, the stabilization mechanism of emulsions prepared by hydrophobically associating polymer is given.

Contents
1 Introduction
2 Emulsions stabilized solely by hydrophobically associating polymers
3 Interactions between hydrophobically associating polymers and surfactants and emulsions stabilized by them
3.1 Interactions between hydrophobically associating polymers and surfactants
3.2 Emulsions stabilized by hydrophobically associating polymers and surfactants
4 Stabilization mechanism of HAP-stabilized emulsion
5 Summary

Key words: hydrophobically associating polymers, emulsions, surfactants

中图分类号: 

()

[ 1 ] 　Evani S. US 4432881 , 1984
[ 2 ] 　Yamamoto H , Tomatsu I , Hashidzume A , et al . Macromolecules ,2000 , 33 : 7852 —7861
[ 3 ] 　Zhang Y X, Da A H , Butler G B , et al . J . Polym. Sci . Part A:Polym. Chem. , 1992 , 30 : 1383 —1391
[ 4 ] 　Tsitsilianis C , Lliopoulos L , Ducouret G. Macromolecules , 2000 ,33 : 2936 —2943
[ 5 ] 　Shalaby S W, McCormick C L , Butler GB. ACS Symposium Series 467 , Washington D C: Am. Chem. Soc. , 1991
[ 6 ] 　Taylor K C , Nasr2EI2Din H A. J . Pet . Sci . Eng. , 1998 , 19 :265 —280
[ 7 ] 　Peiffer D G. Polymer , 1990 , 31 : 2353 —2360
[ 8 ] 　Volpert E , Selb J , Candau F. Polymer , 1998 , 39 : 1025 —1033
[ 9 ] 　耿同谋(Geng TM) , 吴文辉(Wu W H) , 蔡耀烽(Cai Y F) . 功能高分子学报(Journal of Functional Polymers) , 2004 , 17 : 75 —80
[10 ] 　任鲲(Ren K) , 姜桂元(Jiang G Y) , 林梅钦(Lin M Q) 等. 功能高分子学报(Journal of Functional Polymers) , 2005 , 18 : 321 —324
[11 ] 　钟传蓉(Zhong C R) , 罗平亚(Luo P Y) , 胡晓斌(Hu X B) 等.石油学报(石油加工) (Acta Petrolet Sinica ( Petroleum Processing Sectian) ) , 2007 , 23 : 49 —54
[12 ] 　贾振福(Jia Z F) , 李早元(Li Z Y) , 罗平亚(Luo P Y) 等. 钻井液与完井液(Drilling Fluid &Completion Fluid) , 2007 , 24 : 55 —57
[13 ] 　曹宝格(Cao B G) , 罗平亚(Luo P Y) , 陈明强(Chen M Q) 等.石油钻采工艺(Oil Drilling & Production Technology) , 2007 , 29 :53 —57
[14 ] 　郭拥军(Guo Y J ) , 冯茹森(Feng R S) , 张新民(Zhang X M) 等.石油钻采工艺(Oil Drilling & Production Technology) , 2008 , 30 :98 —102
[15 ] 　郭拥军(Guo Y J ) , 张新民(Zhang X M) , 冯如森(Feng R S) 等.油田化学(Oilfield Chemistry) , 2007 , 24 : 344 —346
[16 ] 　叶仲斌(Ye Z B) , 洪楚侨(Hong C Q) , 施雷庭(Shi L T) 等. 西南石油大学学报(Journal of Southwest Petroleum Institute) . 2007 ,29 : 171 —175
[17 ] 　洪楚侨(Hong C Q) , 叶仲斌(Ye Z B) , 施雷庭(Shi L T) 等. 石油钻采工艺(Oil Drilling& Production Technology) . 2007 , 29 :61 —64
[18 ] 　钟传蓉(Zhong C R) , 黄荣华(Huang R H) , 罗平亚(Luo P Y) .应用化工(Applied Chemical Industry) , 2006 , 35 : 913 —917
[19 ] 　钟传蓉(Zhong C R) , 黄荣华(Huang R H) , 代华(Dai H) . 高分子材料科学与工程( Polymer Materials Science & Engineering) ,2007 , 23 : 88 —91
[20 ] 　Zhao GQ , Chen S B. J . Colloid Interface Sci . , 2007 , 316 : 858 —866
[21 ] 　Zhao GQ , Khin C C , Chen S B. J . Phys. Chem. B , 2005 , 109 :14198 —14204
[22 ] 　Zhao GQ , Chen S B. Langmuir , 2006 , 22 : 9129 —9134
[23 ] 　Zhao GQ , Chen S B. J . Colloid Interface Sci . , 2008 , 322 : 678 —680
[24 ] 　Santos T, Medronho B , Lindman B , et al . Colloids Surf . A , 2008 ,319 : 173 —179
[25 ] 　Almgren M, Borne J , Feitosa E , et al . Langmuir , 2007 , 23 :2768 —2777
[26 ] 　Winnik F M, Ringsdorf H , Venzmer J . Langmuir , 1991 , 7 : 905 —911
[27 ] 　刘琼(Liu Q) , 吴文辉(Wu W H) , 陈颖(Chen Y) 等. 功能高分子学报(Journal of Functional Polymers) , 2005 , 18 : 22 —27
[28 ] 　Nedyalkov M, Alexandrova L , Tadros T F , et al . Colloid Polym.Sci . , 2008 , 286 : 713 —719
[29 ] 　Bhattarai S R , Remant K C B , Aryal S , et al . J . Nanopart Res. ,2008 , 10 : 151 —162
[30 ] 　Zhang X, Ercelen S , Duportail G, et al . J . Gen. Med. , 2008 , 10 :527 —539
[31 ] 　Sun WB , Sun DJ , Wei YP. J . Colloid Interface Sci . , 2007 , 311 :228 —236
[32 ] 　Nilsson L , Bergenstahl B. Langmuir , 2006 , 22 : 8770 —8776
[33 ] 　Nilsson L , Bergenstahl B. J . Colloid Interface Sci . , 2007 , 308 :508 —513
[34 ] 　Perrin P , Lafuma F. J . Colloid Interface Sci . , 1998 , 197 : 317 —326
[35 ] 　Lochhead R Y, Rulison C J . Colloids Surf . A , 1994 , 88 : 27 —32
[36 ] 　Perrin P , Devaux N , Sergot P , et al . Langmuir , 2001 , 17 : 2656 —2663
[37 ] 　Perrin P , Monfreux N , Lafuma F. Colloid Polym. Sci . , 1999 , 277 :89 —94
[38 ] 　Karlberg M, Thuresson K, Lindman B. Colloids Surf . A , 2005 ,262 : 158 —167
[39 ] 　Rouzes C , Durand A , Leonard M, et al . J . Colloid Interface Sci . ,2002 , 253 : 217 —223
[40 ] 　Sadtler V M, Imbert P , Dellacherie E. J . Colloid Interface Sci . ,2002 , 254 , 355 —361
[41 ] 　Durand A , Marie E , Rotureau E , et al . Langmuir , 2004 , 20 :6956 —6963
[42 ] 　Akiyama E , Kashimoto A , Fukuda K. J . Colloid Interface Sci . ,2005 , 282 : 448 —457
[43 ] 　Akiyama E , Yamamoto T, Yago Y. J . Colloid Interface Sci . , 2007 ,311 : 438 —446
[44 ] 　Tadros T F , Vandamme A , Levecke B. Adv. Colloid Interface Sci . ,2004 , 108P109 : 207 —226
[45 ] 　Tadros T F , Vandamme A , Booten K. Colloids Surf . A , 2004 , 250 :133 —140
[46 ] 　Exerowa D , Gotchev G, Kolarov T, et al . Langmuir , 2007 , 23 :1711 —1715
[47 ] 　Esquena J , Dominguez F J , Solans C , et al . Langmuir , 2003 , 19 ,10463 —10467
[48 ] 　Nilsson L , Bergenstahl B. J . Agric. Food Chem. , 2007 , 55 :1469 —1474
[49 ] 　Nilsson L , Leeman M, Wahlund K G, et al . Langmuir , 2007 , 23 :2346 —2351
[50 ] 　Biggs S , Selb J , Candau F. Langmuir , 1992 , 8 : 838 —847
[51 ] 　Panmai S , Prudhomme K R , Peiffer D G, et al . Langmuir , 2002 ,18 : 3860 —3864
[52 ] 　Panmai S , Prudhomme K R , Peiffer D G. Colloids Surf . A. , 1999 ,147 : 3 —15
[53 ] 　Pons R , Taylor P , Tadros T F. Colloid. Polym. Sci . , 1997 , 275 :769 —776
[54 ] 　Nestor J , Esquena J , Solans C , et al . J . Appl . Polym. Sci . , 2008 ,108 : 811 —815
[55 ] 　Akiyama E , Kashimoto A , Hotta H , et al . J . Colloid Interface Sci . ,2006 , 300 : 141 —148
[56 ] 　Philip J , Prakash G G, Jaykumar T, et al . Langmuir , 2002 , 18 :4625 —4631
[1] 尹晓庆, 陈玮豪, 邓博苑, 张佳路, 刘婉琪, 彭开铭. 超润湿膜在乳化液破乳中的应用及作用机制[J]. 化学进展, 2022, 34(3): 580-592.
[2] 刘宁, 刘水林, 伍素云, 付琳, 吴智, 李来丙. 金属基介孔固体碱催化剂的制备与应用[J]. 化学进展, 2020, 32(5): 536-547.
[3] 赵剑曦, 顾攀攀, 曾慧, 邓生禄. 表面活性剂在非极性有机溶剂中的自组装[J]. 化学进展, 2019, 31(5): 643-653.
[4] 冯盛, 杨芳, 刘梦瑶, 范红显, 徐念. 抗癌药物多烯紫杉醇载体[J]. 化学进展, 2019, 31(2/3): 368-380.
[5] 黄翔峰, 娜雅, 熊永娇, 王旭慧, 彭开铭*. 颗粒膜的结构及对乳状液稳定性的影响机制[J]. 化学进展, 2016, 28(12): 1743-1752.
[6] 赵剑曦. 表面活性剂在非极性有机溶剂中的复杂反相聚集体[J]. 化学进展, 2015, 27(2/3): 168-173.
[7] 周妍, 赵雪冰, 刘德华. 非离子型表面活性剂对木质纤维素酶催化水解的影响及机理[J]. 化学进展, 2015, 27(11): 1555-1565.
[8] 张文彬, 王晓曼, 王晓威, 刘栋, 韩帅元, 程正迪. 基于分子纳米粒子的巨型分子[J]. 化学进展, 2015, 27(10): 1333-1342.
[9] 赵剑曦. Gemini表面活性剂：联接链在自组织中的作用及意义[J]. 化学进展, 2014, 26(08): 1339-1351.
[10] 陈景飞, 郝京诚. 表面活性剂溶液行为的粗粒化模拟[J]. 化学进展, 2012, (10): 1890-1896.
[11] 赵学艳, 郑利强, 曹桂荣, 肖瑞杰. 离子液体参与构建的胶束[J]. 化学进展, 2012, 24(05): 686-695.
[12] 赵剑曦, 谢丹华. 阴离子蠕虫胶束[J]. 化学进展, 2012, 24(04): 456-462.
[13] 孟雅莉, 李臻, 陈静, 夏春谷. 离子液体微乳液体系的应用研究[J]. 化学进展, 2011, 23(12): 2442-2456.
[14] 张永民, 郭赞如, 张继超, 冯玉军, 王碧清, 王九霞. 智能型蠕虫状胶束体系[J]. 化学进展, 2011, 23(10): 2012-2020.
[15] 王九霞 苏鑫 Philip G. Jessop 冯玉军. CO2开关型溶剂、溶质及表面活性剂*[J]. 化学进展, 2010, 22(11): 2099-2105.