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化学进展 2009, Vol. 21 Issue (6): 1107-1117 前一篇   后一篇

• 综述与评论 •

DSA电极电催化性能研究及尚待深入探究的几个问题*

孔德生**;吕文华;冯媛媛;毕思玮   

  1. (曲阜师范大学化学科学学院    |曲阜 |273165)
  • 收稿日期:2008-06-26 修回日期:2008-08-17 出版日期:2009-06-24 发布日期:2009-06-16
  • 通讯作者: 孔德生 E-mail:kongdscn@eyou.com
  • 基金资助:

    省级资助

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Advances and Some Problems in Electrocatalysis of DSA Electrodes

Kong Desheng**;  |Lu Wenhua ;  |Feng Yuanyuan ;  |Bi Siwei   

  1. (Department of Chemistry, Qufu Normal University, Qufu 273165, China)
  • Received:2008-06-26 Revised:2008-08-17 Online:2009-06-24 Published:2009-06-16
  • Contact: Kong Desheng E-mail:kongdscn@eyou.com

钛基氧化物涂层电极(DSA®)由于其对阳极析氯、阳极析氧、有机污染物电化学降解等具有优异的电催化活性而受到研究者的广泛关注，但DSA电极电催化现象背后的一些重要而基础性的问题仍未被人们完全认识。本文针对目前国内外有关DSA电极电催化研究领域中的几个研究热点、不足之处、以及尚待深入探究的问题，进行了简要介绍、分析和讨论。DSA电极的电催化活性主要是来自于其表面的金属氧化物涂层。本文强调对“氧化物涂层”自身固体物理-化学性能或过程的研究，有助于深入揭示钛基活性氧化物涂层电极电催化现象的微观作用机制和内在本质，并反过来指导人们更加理性地通过设计和优化DSA电极的制备方法和条件，调控表面氧化物涂层的化学组成与结构，进而达到增强钛基涂层电极电催化活性之目的。

关键词： 钛基氧化物涂层电极, 电催化, 金属氧化物, 电荷传递, 电子结构, 阳极失效

Titanium anodes coated with transient metal oxides, so-called dimensionally stable anodes (DSA®) have been studied extensively due to their excellent electrocatalytic activity for chlorine and oxygen evolutions and electrooxidation degradation of toxic organic compounds. But some fundamental and important questions in close relation with the electrocatalysis phenomenon of DSA have not been completely understood yet. After a short review of the recent progress of electrocatalysis of DSA, some deficiencies in the related studies are raised and discussed. Since the oxide coating plays an esential role in the electrocatalytic activity of DSA, it is emphasized that the solid state physicochemical properties (e.g. the electronic structure, potential distribution, charge transfer mechanisms, conductivity, etc.) of the bulk metal oxide coating in DSA electrode need to be further investigated in future studies. Both for understanding the essentiality of the electrocatalysis phenomena of DSA and for improving the electrocatalytic activity of DSA electrode by changing the chemical composition of its oxide coating more rationally, it is desired to establish more correlations of the electro-catalytic activity of DSA electrode with the solid state physico-chemical properties of the oxide coating bulk.

Contents
1 Introduction
2 Recent progress in the field of DSA electro-catalysis studies
2.1 Studying on electro-catalytic activity of DSA electrodes with different chemical compositions
2.2 Developing new methods for preparation of DSA electrodes
2.3 For the pretreatment of the substrate Ti
2.4 For the electro-catalytic degradation of organic pollutants
2.5 Studying on the electro-catalytic mechanisms at the electrode/solution interface
3 Some deficiencies in DSA electro-catalysis studies
4 Some topics needs to be further investigated in future studies
4.1 About the solid physico-chemical and electric properties of the oxide coatings
4.2 About the charge transfer and potential distribution at the Ti/oxide coating/solution interfaces
4.3 About the nano-size effect on the conductivity and charge-transfer mechnism
5 Concluding remarks

Key words: DSA, electrocatalysis, metal oxides, charge transfer, electronic structure, anodic degradation

中图分类号: 

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