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化学进展 2009, Vol. 21 Issue (12): 2753-2759 前一篇   后一篇

• 综述与评论 •

聚合物膜燃料电池阴极非Pt催化剂

赵东江1,3;尹鸽平1,2*;魏杰1   

  1. （1. 哈尔滨工业大学化工学院 哈尔滨  150001；2. 哈尔滨工业大学城市水资源与水环境国家重点实验室 哈尔滨 150001；3. 绥化学院化学与制药工程系 绥化  152061）
  • 收稿日期:2008-12-17 修回日期:2009-02-20 出版日期:2009-12-24 发布日期:2009-12-01
  • 通讯作者: 尹鸽平 E-mail:yingphit@hit.edu.cn
  • 基金资助:

    无

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导出 被引次数 ( 8 | 3 )

Non-platinum Cathode Electrocatalysts in Polymer Electrolyte Membrane Fuel Cells

Zhao Dongjiang1,3;  Yin Geping1,2*;  Wei Jie1   

  1. (1. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China；2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150001, China; 3. Department of Chemical and Medical Engineering, Suihua University, Suihua 152061, China)
  • Received:2008-12-17 Revised:2009-02-20 Online:2009-12-24 Published:2009-12-01
  • Contact: Yin Geping E-mail:yingphit@hit.edu.cn

简要介绍了聚合物膜燃料电池（PEMFC）的特点及其存在的主要技术问题。综述了PEMFC阴极非Pt催化剂的研究进展，重点讨论了过渡金属硫族化合物、过渡金属合金、过渡金属氮化物、过渡金属氧化物以及过渡金属大环化合物等非Pt催化剂对氧还原反应（ORR）的催化活性、化学或电化学稳定性以及耐甲醇能力等性能，提出了阴极非Pt催化剂存在的问题以及发展趋势。Ru基硫族化合物、Pd基合金和过渡金属大环化合物催化剂具有良好的性能，有望成为PEMFC阴极Pt基催化剂的替代材料。

关键词： 聚合物膜燃料电池, 非铂催化剂, 氧还原, 耐甲醇

The advantages and major technical problems of polymer electrolyte membrane fuel cell (PEMFC) are briefly introduced. The research progress of non-platinum cathode catalysts of PEMFC is reviewed. In particular, the catalytic activity for oxygen reduction reaction (ORR), chemical or electrochemical stability and methanol-tolerant of the non-platinum catalysts (transition metal chalcogenides, transition metal alloys, transition metal nitrides, transition metal oxides, transition metal macrocyclic complexes, etc.) are focused upon. The existing problems and the development trends of the non-platinum catalysts are proposed. The ruthenium-based chalcogenides, palladium-based alloys and transition metal macrocyclic complexes catalysts displayed good performances and are expected to become the substitutes for the PEMFC cathode platinum-based catalysts.

Contents
1 Introduction
2 Transition metal chalcogenides
2.1 Binary compounds
2.2 Ternary compounds
3 Transition metal alloys
4 Transition metal nitrides
5 Transition metal oxides
6 Transition metal macrocyclic complexes
7 Epilogue

Key words: PEMFC, non-platinum catalysts, oxygen reduction, methanol-tolerant

中图分类号: 

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[ 1 ] 　Cremers C , Scholz M, Seliger W, et al . Fuel Cells , 2007 , 7 (1) :21 —31
[ 2 ] 　Oszcipok M, Zedda M, Hesselmann J , et al . J . Power Sources ,2006 , 157 : 666 —673
[ 3 ] 　Song S Q , Zhou W J , Li W Z, et al . Ionics , 2004 , 10 : 458 —462
[ 4 ] 　Kamarudin S K, Daud W R W, Ho S L , et al . J . Power Sources ,2007 , 163 : 743 —754
[ 5 ] 　Chatzitheodorou G. DE 38 02 236 Al , 1988
[ 6 ] 　Alonso-Vante N , Malakhov I V , Nikitenko S G, et al . Electrochim.Atca , 2002 , 47 (22/23) : 3807 —3814
[ 7 ] 　Neergat M, Leveratto D , Stimming U. Fuel Cells , 2002 , 2 (1) :25 —30
[ 8 ] 　Dassenoy F , Vogel W, Alonso-Vante N. J . Phys. Chem. B , 2002 ,106 (47) : 12152 —12157
[ 9 ] 　Schulenburg H , Hilgendorff M, Dorbandt I , et al . J . Power Sources , 2006 , 155 (1) : 47 —51
[10 ] 　Cao D , Wieckowski A , Inukai J , et al . J . Electrochem. Soc. ,2006 , 153 (5) : A869 —A874
[11 ] 　Kulesza P J , Miecznikowski K, Baranowska B , et al . Electrochem.Commun. , 2006 , 8 (5) : 904 —908
[12 ] 　Kulesza P J , Miecznikowski K, Baranowska B , et al . J . Appl .Electrochem. , 2007 , 37 : 1439 —1446
[13 ] 　Kolary-Zurowska A , Zieleniak A , Miecznikowski K, et al . J . Solid State Electrochem. , 2007 , 11 : 915 —921
[14 ] 　Cheng H , Yuan W, Scott K. Electrochim. Atca , 2006 , 52 (2) :466 —473
[15 ] 　Zehl G, Bogdanoff P , Wipperman K, et al . J . Appl . Electrochem. ,2007 , 37 : 1475 —1484
[16 ] 　Wippermann K, Richter B , Klafki K, et al . J . Appl .Electrochem. , 2007 , 37 : 1399 —1411
[17 ] 　Alonso-Vante N , Tributsch H. Nature , 1986 , 323 : 431 —432
[18 ] 　Alonso-Vante N , Jaegermann W, Tributsch H , et al . J . Am. Chem.Soc. , 1987 , 109 (11) : 3251 —3257
[19 ] 　Solorza-Feria O , Ellmer K, Gierstig M, et al . Electrochim. Atca ,1994 , 39 (11/12) : 1647 —1653
[20 ] 　Alonso-Vante N , Tributsch H , Solorza-Feria O. Electrochim. Atca ,1995 , 40 (5) : 567 —576
[21 ] 　Alonso-Vante N , Bogdanoff P , Tributsch H. J . Catalysis , 2000 , 190(2) : 240 —246
[22 ] 　Schmidt TJ , Paulus U A , Gasteiger H A , et al . J . Electrochem.Soc. , 2000 , 147 (7) : 2620 —2624
[23 ] 　Lee J W, Popov B N. J . Solid State Electrochem. , 2007 , 11 :1355 —1364
[24 ] 　Ozenler S S , Kad￥ rgan F. J . Power Sources , 2006 , 154 (2) : 364 —369
[25 ] 　Fischer C , Alonso-Vante N , Fiechter S , et al . J . Appl .Electrochem. , 1995 , 25 (11) : 1004 —1008
[26 ] 　Reeve R W, Christensen P A , Hamnett A , et al . J . Electrochem.Soc. , 1998 , 145 (10) : 3463 —3471
[27 ] 　Reeve R W, Christensen P A , Dickinson A J , et al . Electrochim.Acta , 2000 , 45 (25P26) : 4237 —4250
[28 ] 　Solorza-Feria O , Ramírez-Raya S , Rivera-Noriega R , et al . Thin Solid Films , 1997 , 311 (1P2) : 164 —170
[29 ] 　Cheng H , Yuan W, Scott K, et al . J . Power Sources , 2007 , 172 :597 —603
[30 ] 　Ceré S , Vazquez M, Sánchez S R , et al . J . Electroanal . Chem. ,2001 , 505 (1/2) : 118 —124
[31 ] 　Lee K, Ishihara A , Mitsushima S , et al . Electrochim. Atca , 2004 ,49 (21) : 3479 —3485
[32 ] 　Lee K, Zhang L , Zhang J . J . Power Sources , 2007 , 170 ( 2 ) :291 —296
[33 ] 　Shao M H , Huang T, Liu P , et al . Langmuir , 2006 , 22 : 10409 —10415
[34 ] 　Lin C , Carlos M, Sánchez-Sánchez CM, et al . Electrochem. Solid State Lett . , 2008 , 11 (8) : B136 —B139
[35 ] 　Mustain W E , Kepler K, Prakash J . Electrochim. Atca , 2007 , 52 :2102 —2108
[36 ] 　Zhang L , Lee K, Zhang J . Electrochim. Atca , 2007 , 52 ( 28) :7964 —7971
[37 ] 　Zhang L , Lee K, Zhang J . Electrochim. Atca , 2007 , 52 ( 9 ) :3088 —3094
[38 ] 　Shao M, Sasaki K, Adzic R R. J . Am. Chem. Soc. , 2006 , 128 :3526 —3527
[39 ] 　Tarasevich M R , Zhutaeva G V , Bogdanovskaya V A , et al .Electrochim. Atca , 2007 , 52 : 5108 —5118
[40 ] 　Shao M, Liu P , Zhang J , et al . J . Phys. Chem. B , 2007 , 111 :6772 —6775
[41 ] 　Lee K, Savadogo O , Ishihara A , et al . J . Electrochem. Soc. ,2006 , 153 : A20 —A24
[42 ] 　Walsh D A , Fernández J L , Bard A J . J . Electrochem. Soc. ,2006 , 153 : E99 —E103
[43 ] 　Wang X, Kariuki N , Vaughey J T, et al . J . Electrochem. Soc. ,2008 , 155 (6) : B602 —B609
[44 ] 　Raghuveer V , Manthiram A , Bard A J . J . Phys. Chem. B , 2005 ,109 : 22909 —22912
[45 ] 　Fernandez J , Raghuveer V , Manthiram A , et al . J . Am. Chem.Soc. , 2005 , 127 : 13100 —13101
[46 ] 　Mazza F , Trassatti S. J . Electrochem. Soc. , 1963 , 110 (7) : 847 —849
[47 ] 　Zhong H , Zhang H , Liu G, et al . Electrochem. Commun. , 2006 , 8(5) : 707 —712
[48 ] 　Xia D , Liu S , Wang Z, et al . J . Power Sources , 2008 , 177 : 296 —302
[49 ] 　Liu L , Kim H , Lee J W, et al . J . Electrochem. Soc. , 2007 , 154 :A123
[50 ] 　Liu L , Lee J W, Popov B N. J . Power Sources , 2006 , 162 :1099 —1103
[51 ] 　Manoharan R , Goodenough J B. Electrochim. Atca , 1995 , 40 (3) :303 —307
[52 ] 　Hayashi M, Uemura H , Shimanoe K, et al . Electrochem. Solid-State Lett . , 1998 , 1 (6) : 268 —270
[53 ] 　Prakash J , Tryk D A , Yeager E B. J . Electrochem. Soc. , 1999 ,146 (11) : 4145 —4151
[54 ] 　Cong H N , El Abbassi K, Chartier P. Electrochem. Solid2State Lett . , 2000 , 3 (4) : 192 —195
[55 ] 　Suresh K, Panchapagesan T S , Patil KC. Solid State Ionics , 1999 ,126 (3/4) : 299 —305
[56 ] 　Liu Y, Ishihara A , Mitsushima S , et al . Electrochem. Solid-State Lett . , 2005 , 8 (8) : A400 —A402
[57 ] 　Liu Y, Ishihara A , Mitsushima S , et al . J . Electrochem. Soc. ,2007 , 154 (7) : B664 —B669
[58 ] 　Jasinski R. Nature , 1964 , 201 : 1212 —1213
[59 ] 　Wiesener K, Ohms D , Neumann V , et al . Mater. Chem. Phys. ,1989 , 22 (3/4) : 457 —475
[60 ] 　Sun G Q , Wang J T, Savinell R F. J . Appl . Electrochem. , 1998 ,28 : 1087 —1093
[61 ] 　Sun G Q , Wang J T, Gupta S , et al . J . Appl . Electrochem. ,2001 , 31 : 1025 —1031
[62 ] 　Gojkovic′S L , Gupta S , Savinell R F. J . Electroanal . Chem. ,1999 , 462 : 63 —72
[63 ] 　Bagotzky V S , Tarasevich M R , Radyushkina K A , et al . J . Power Sources , 1978 , 2 : 233 —240
[64 ] 　Mocchi1 C , Trasatti S. J . Molecular Catalysis A: Chemical , 2003 ,204/205 : 713 —720
[65 ] 　Ma Z, Xie X, Ma X, et al . Electrochem. Commun. , 2006 , 8 :389 —394
[66 ] 　Deng X, Wang X, Ma Z. J . Power Sources , 2008 , 183 : 604 —608
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