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化学进展 2009, Vol. 21 Issue (12): 2525-2535 前一篇   后一篇

• 综述与评论 •

氮氧自由基-金属配合物磁性分子材料*

张旭红;王淑萍**   

  1. （河北师范大学化学与材料科学学院  石家庄 050016）
  • 收稿日期:2008-11-21 修回日期:2009-03-03 出版日期:2009-12-24 发布日期:2009-12-01
  • 通讯作者: 王淑萍 E-mail:pingwsh@mail.hebtu.edu.cn
  • 基金资助:

    省级资助

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Molecular Magnetic Materials of Nitroxide Radical-Metal Complexes

Zhang Xuhong; Wang Shuping**   

  1. (College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China)
  • Received:2008-11-21 Revised:2009-03-03 Online:2009-12-24 Published:2009-12-01
  • Contact: Wang Shuping E-mail:pingwsh@mail.hebtu.edu.cn

氮氧自由基-金属配合物的合成和功能性研究，已成为分子磁性材料的一个热点课题。本文主要介绍了近年来氮氧自由基-金属配合物型分子基磁体、单分子磁体、单链磁体、分子自旋转换配合物等的最新研究成果，并就这一领域的发展前景做一展望。

关键词： 氮氧自由基, 分子基磁体, 单分子磁体, 单链磁体, 分子自旋转换配合物

The syntheses and studies of nitroxide radical-metal complexes is one of the hotspots for molecular magnetic materials. The research progress of molecule-based magnets, single-molecular magnets, single-chain magnets and molecular spin-transition complexes in this field is summarized, and the prospects is also discussed in this paper.

Contents
1 Introduction
2 Molecule-based magnets
2.1 Monoradicals-metal complexes
2.2 Nitroxide radical cation-metal complexes
2.3 Polyradicals-metal complexes
3 Single-molecular magnets
4 Single-chain magnets
5 Molecular spin-transition complexes
6 Conclusion

Key words: nitroxide radical, molecule-based magnets, single-molecular magnets, single-chain magnets, molecular spin-transition complexes

中图分类号: 

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