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化学进展 2009, Vol. 21 Issue (11): 2474-2482 前一篇   

• 《化学进展》创刊20周年纪念专辑 •

磁性催化剂与磁稳定床反应器

谢文华; 宗保宁*   

  1. (中国石油化工股份有限公司石油化工科学研究院催化材料和反应工程国家重点实验室 北京 100083)
  • 收稿日期:2009-04-21 出版日期:2009-11-24 发布日期:2009-10-09
  • 通讯作者: 宗保宁 E-mail:zongbn@ripp-sinopec.com
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导出 被引次数 ( 29 | 1 )

Magnetic Catalysts and Magnetically Stabilized Bed Reactor

Xie Wenhua;  Zong Baoning*   

  1. (State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China)
  • Received:2009-04-21 Online:2009-11-24 Published:2009-10-09
  • Contact: Zong Baoning E-mail:zongbn@ripp-sinopec.com

将非晶态Ni加氢性能和磁性与磁稳定床反应器相结合，工业应用于已内酰胺加氢精制过程，实现了加氢反应过程的强化。在此基础上制备了系列磁性催化剂，包括金属氧化物催化剂、负载型双金属催化剂和强酸性磁性树脂催化剂等。上述磁性催化剂与磁稳定床反应器相结合，用于CO加氢、乙炔选择性加氢、烯烃叠合和醚化等反应，同样表现出反应过程强化的特点。本文结合我们自己的研究工作，对近年来磁稳定床反应器与磁性催化剂的研究进展进行了评述，并展望了未来磁性催化剂与磁稳定床反应器的发展趋势。

关键词： 磁性催化剂, 磁稳定床反应器, 过程强化

A new hydrogenation technology for caprolactam purification using amorphous Ni alloy catalyst and magnetically stabilized bed reactor has been developed by Sinopec. It shows significant advantages in industrial applications. Encouraged by this progress, a series of magnetic catalysts with both high catalytic activity and magnetic properties have been investigated, including amorphous metal alloy, metal oxides, bimetallic catalyst with magnetic metal oxide support and polymer magnetic catalytic materials. They have either metal active sites or proton active sites. Following reactions with these magnetic catalysts in magnetically stabilized reactor are evaluated: (1) hydrogenation of carbon monoxide for removing CO from hydrogen, (2) selective hydrogenation of alkynes in the olefins which are produced from hydrocarbon steam cracking for forming ethylene, (3) olefins oligomerization to produce diesel, (4) magnetic cation resin and isobutene ethterification. Above researches are reviewed in this article. The future development on magnetic catalysts and magnetic stabilized bed reactor is also discussed.

Contents
1 Introduction
2 Magnetically stabilized bed reactor
3 Magnetic catalysts
4 Amorphous Ni alloy catalyst and magnetically stabilized bed reactor
4.1 Amorphous alloy
4.2 Amorphous Ni alloy hydrogenation catalysts
4.3 Process intensification of amorphous Ni alloy and magnetically stabilized bed reactor
5 Magnetic catalysts and magnetically stabilized bed reactor
5.1 Selective hydrogenation of acetylene over a magnetic core-shell Pd catalyst in a magnetically stabilized bed
5.2 Olefins oligomerization over magnetic oxide catalysts in a magnetically stabilized bed
5.3 Etherification over magnetic sulfonic acid resin in a magnetically stabilized bed
6 Prospects

Key words: magnetic catalysts, magnetically stabilized bed reactor, process intensification

中图分类号: 

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磁性催化剂与磁稳定床反应器