PDF(860 KB)
PDF(860 KB)
PDF(860 KB)
向高功能发展的配位聚合物*
- 杜淼1;卜显和2**
作者信息
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Coordination Polymers towards Advanced Functions
- Du Miao1; Bu Xianhe2**
Author information
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文章历史
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摘要
运用晶体工程的经验和方法合理设计和制备具有特定网络结构和理化性能的配位聚合物是当前配位化学、超分子化学、材料化学及相关领域的研究热点之一。作为一类新型分子基晶体材料，配位聚合物（尤其是多孔配位聚合物）在客体交换与分离、气体储存、手性拆分、药物缓释、电致发光、选择性催化、分子识别及微孔器件等诸多方面均显示出潜在的应用前景。本文简要介绍了此类化合物作为具有复合性能的多功能晶体材料，在吸附、催化及光、电、磁等方面应用的最新研究进展。
Abstract
The rational design and preparation of metal-organic coordination polymers with specific network structures and physicochemical properties by using the experience and method of crystal engineering has currently been a hot research topic in coordination chemistry, supramolecular chemistry, material chemistry and other related areas. As a new type of molecular-based crystalline material, coordination polymers (especially microporous coordination polymers) have displayed potential applications in many aspects such as guest exchange/separation, gas storage, chiral resolution, drug release, electroluminescence, selective catalysis, molecular recognition, and microporous devices. In this paper, the recent progress of such advanced multifunctional crystalline materials and their applications in adsorption, catalysis as well as optics, electrics, and magnetism are briefly reviewed.
Contents
1 Introduction
2 Multifunctional coordination polymers
3 Conclusion and perspectives
关键词
配位聚合物 / 复合功能 / 分子基材料 / 晶体工程 {{custom_keyword}} /
Key words
coordination polymers / multifunctionality / molecular-based materials / crystal engineering {{custom_keyword}} /
中图分类号：
O631.3
O641.3
O647.32
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