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化学进展 2009, Vol. 21 Issue (11): 2458-2464 前一篇   后一篇

• 《化学进展》创刊20周年纪念专辑 •

向高功能发展的配位聚合物*

杜淼1;卜显和2**   

  1. （1．天津师范大学化学与生命科学学院 天津 300387；2．南开大学化学系 天津 300071）
  • 收稿日期:2009-05-04 出版日期:2009-11-24 发布日期:2009-10-09
  • 通讯作者: 卜显和 E-mail:buxh@nankai.edu.cn
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Coordination Polymers towards Advanced Functions

Du Miao1; Bu Xianhe2**   

  1. (1. College of Chemistry and Life Science, Tianjin Normal University, Tianjin 300387, China; 2. Department of Chemistry, Nankai University, Tianjin 300071, China)
  • Received:2009-05-04 Online:2009-11-24 Published:2009-10-09
  • Contact: Bu Xianhe E-mail:buxh@nankai.edu.cn

运用晶体工程的经验和方法合理设计和制备具有特定网络结构和理化性能的配位聚合物是当前配位化学、超分子化学、材料化学及相关领域的研究热点之一。作为一类新型分子基晶体材料，配位聚合物（尤其是多孔配位聚合物）在客体交换与分离、气体储存、手性拆分、药物缓释、电致发光、选择性催化、分子识别及微孔器件等诸多方面均显示出潜在的应用前景。本文简要介绍了此类化合物作为具有复合性能的多功能晶体材料，在吸附、催化及光、电、磁等方面应用的最新研究进展。

关键词： 配位聚合物, 复合功能, 分子基材料, 晶体工程

The rational design and preparation of metal-organic coordination polymers with specific network structures and physicochemical properties by using the experience and method of crystal engineering has currently been a hot research topic in coordination chemistry, supramolecular chemistry, material chemistry and other related areas. As a new type of molecular-based crystalline material, coordination polymers (especially microporous coordination polymers) have displayed potential applications in many aspects such as guest exchange/separation, gas storage, chiral resolution, drug release, electroluminescence, selective catalysis, molecular recognition, and microporous devices. In this paper, the recent progress of such advanced multifunctional crystalline materials and their applications in adsorption, catalysis as well as optics, electrics, and magnetism are briefly reviewed.

Contents
1 Introduction
2 Multifunctional coordination polymers
3 Conclusion and perspectives

Key words: coordination polymers, multifunctionality, molecular-based materials, crystal engineering

中图分类号: 

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摘要

向高功能发展的配位聚合物*