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化学进展 2009, Vol. 21 Issue (11): 2445-2457 前一篇   后一篇

• 《化学进展》创刊20周年纪念专辑 •

润滑材料摩擦化学*

薛群基**;张俊彦   

  1. (中国科学院兰州化学物理研究所固体润滑国家重点实验室 兰州 730000)
  • 收稿日期:2009-08-21 出版日期:2009-11-24 发布日期:2009-10-09
  • 通讯作者: 薛群基 E-mail:qjxue@lzb.ac.cn
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Tribochemistry of Lubricating Materials

Xue Qunji**; Zhang Junyan   

  1. (State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemcial Physics, Chinese Academy of Sciences, Lanzhou 730000, China)
  • Received:2009-08-21 Online:2009-11-24 Published:2009-10-09
  • Contact: Xue Qunji E-mail:qjxue@lzb.ac.cn

外界机械能能够引发的化学反应称为摩擦化学反应。当两个接触的表面进行相对运动时，在界面发生物理和化学变化或反应。润滑材料在服役过程中发生的摩擦化学反应对于其性能的具有正面或负面的影响。通过了解摩擦化学反应机理和反应产物结构及组成，对于理解润滑材料失效机制、性能调控原理具有指导意义。本文针对润滑材料的主要类型：润滑添加剂、纳米添加剂、离子液体、稀土、陶瓷、类金刚石薄膜、有机薄膜、聚合物，综述了近几十年来在相关润滑材料方面开展和取得的摩擦化学研究结果。

关键词： 润滑, 材料, 摩擦化学

Tribochemistry is defined as the reaction induced by mechanical energy. The physical or chemical reaction would be happened at the interface when two contact surfaces sliding against each other. The tribochemistry reaction of the lubricants in the service process has positive or negative impact to their properties. It is valuable through probing the tribochemistry reaction mechanism, the structure and composition of reaction products to understand the failure mechanism and the theory of property regulation of lubricants . Aiming at main kinds of lubricants including oil additives, nanoparticles additives, ionic liquids, rare earth, ceramics, diamond like carbon films, organic thin films, and polymers, the studies on the tribochemistry of the lubricants in the last few decades are reviewed.

Contents
1 Introduction
2 Tribochemistry of oil additives
3 Tribochemistry of nanoparticle additives
4 The structure and tribology of ionic liquids
5 Tribochemistry of rare earth
6 Tribochemistry of ceramics
7 Tribochemistry of diamond-like carbon films
8 Molecular structures and tribology of organic thin films
9 Tribochemistry of polymers

Key words: lubrication, materials, tribolochemistry

中图分类号: 

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摘要

润滑材料摩擦化学*