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化学进展 2009, Vol. 21 Issue (0708): 1678-1686 前一篇   后一篇

• 综述与评论 •

金属锂二次电池锂负极改性

高鹏1*;韩家军1;朱永明1;张翠芬2;李宁1,2   

  1. (1. 哈尔滨工业大学（威海）海洋学院应用化学系  威海 264209；2. 哈尔滨工业大学化工学院应用化学系  哈尔滨 150001)
  • 收稿日期:2008-08-29 修回日期:2008-09-16 出版日期:2009-08-24 发布日期:2009-06-30
  • 通讯作者: 高鹏 E-mail:gaofei5075@sina.com
  • 基金资助:

    无

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Surface Treatment on Lithium Electrode in Rechargeable Lithium Metal Batteries

Gao Peng1*|Han Jiajun1|Zhu Yongming1|Zhang Cuifen2|Li Ning1, 2   

  1. (1. Department of Applied Chemistry, School of Ocean, Harbin Institute of Technology at Weihai, Weihai 264209, China|2.Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China)
  • Received:2008-08-29 Revised:2008-09-16 Online:2009-08-24 Published:2009-06-30
  • Contact: Gao Peng E-mail:gaofei5075@sina.com

本文综述了金属锂二次电池中提高锂负极性能的研究进展。分别介绍了以下改性方法：对金属锂表面进行预处理，使其表面预先形成性能良好的固体电解质界面膜，或直接在其表面制备保护膜；在电解液中加入添加剂对锂电极进行表面改性；采用新型有机溶剂、离子液体、聚合物电解质、玻璃态固体电解质、塑晶固体电解质等电解质体系提高界面相容性；改进金属锂电极的制备工艺，如制备金属锂粉末多孔电极和电沉积锂电极、制造全固态薄膜锂电池以及利用物理方法处理锂电极。并在此基础上对今后的发展趋势进行了展望。

关键词： 金属锂二次电池, 锂电极, 表面改性, 添加剂, 电解质, 制备工艺

The research progress for improving the properties of lithium metal electrode in rechargeable lithium metal batteries is reviewed. The treatment methods are introduced respectively as follow: either making surface pretreatment on lithium metal, to form better solid electrolyte interface in advance, or producing the protecting coating directly; adding additives in electrolyte to improve the surface properties; improving the interfacial compatibility by applying new type organic solvents, ionic liquid, polymer electrolyte, glass-based solid electrolyte and plastic crystal solid electrolyte as the electrolyte systems; improving the fabrication process of lithium electrode, such as lithium powder electrode, electrodeposited lithium electrode and all solid-state thin film lithium battery as well as utilization of physical methods. The future development in the research is also prospected.

Contents
1 Introduction
2 Making surface pretreatment on lithium metal electrode
2.1 Forming SEI in advance
2.2 Producing surface protecting coating 
3 Adding electrolyte additives to improve the surface properties 
4 Changing the electrolyte systems to improve the interfacial compatibility
4.1 Novel organic solvent
4.2 Ionic liquid
4.3 Polymer electrolyte
4.4 Glass-based solid electrolyte
4.5 Plastic crystal solid electrolyte 
5 Improving the fabrication process of lithium electrode
5.1 Lithium powder electrode
5.2 Electrodeposited lithium electrode
5.3 All solid-state thin film lithium battery
5.4 Treating lithium electrode by physical methods
6 Conclusion

Key words: rechargeable lithium battery, lithium metal electrode, surface treatment, additive, electrolyte, fabrication process

中图分类号: 

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摘要

金属锂二次电池锂负极改性