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化学进展 2009, Vol. 21 Issue (0708): 1523-1533 前一篇   后一篇

• 综述与评论 •

异卟啉研究进展*

王全国;曾凡花;解永树**;朱为宏   

  1. (华东理工大学结构可控先进功能材料及其制备教育部重点实验室 精细化工研究所 上海 200237)
  • 收稿日期:2008-12-04 修回日期:2009-01-16 出版日期:2009-08-24 发布日期:2009-06-30
  • 通讯作者: 解永树 E-mail:yshxie@ecust.edu.cn
  • 基金资助:

    国家自然科学基金

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A Brief Review of Recent Progress in Porphyrinoids

Wang Quanguo; |Zeng Fanhua; |Xie Yongshu**; |Zhu Weihong   

  1. (Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science &|Technology, Shanghai 200237, China)
  • Received:2008-12-04 Revised:2009-01-16 Online:2009-08-24 Published:2009-06-30
  • Contact: Xie Yongshu E-mail:yshxie@ecust.edu.cn

异卟啉是通过改变卟啉大环结构而得到的卟啉类似物。由于具有独特的结构和性能，如阴离子识别、稳定异常价态金属离子、Möbius芳香性、构建新型超分子体系、电子转移以及近红外荧光等特性，异卟啉已引起人们越来越多的兴趣。本文简要介绍了异卟啉研究的意义，异卟啉的命名以及分类，并重点介绍了 N-错位卟啉、扩展卟啉和氧化卟啉原等异卟啉的研究现状及最新进展。同时对咔咯、氧化咔咯原、卟啉烯、核修饰卟啉、亚卟啉和杯吡咯等异卟啉的发展现状及其性能作了简要概述。通过对异卟啉化合物研究，可得到很多普通卟啉难以实现的性能，并有望在相关领域获得实际应用。本文在介绍异卟啉研究的同时，还尝试翻译了一些相关专业术语。

关键词： 异卟啉, N-混乱卟啉, 扩展卟啉, Mö, bius芳香性, 超分子, 阴离子识别

Porphyrinoids are compounds with macrocyclic structures similar to those of porphyrins. They continue to attract the attention of chemists due to their unique structures and properties, such as anion binding, stabilization of metal ions with unusual oxidation states, Möbius aromaticity, construction of interesting supramolecular assemblies, electron transfer, and NIR emission. Significance, nomenclature and classification of porphyrinoids are briefly introduced in this paper. Then recent progress of N-confused porphyrins, expanded porphyrins, and oxoporphyrinogens are highlighted and reviewed. Furthermore, corroles, oxocorrologens, porphycenes, core-modified porphyrins, subporphyrins, calixpyrroles and some other porphyrinoids are also introduced. Researches on porphyrinoids provide the possibilities of interesting properties and relevant applications that might be totally different from normal porphyrin compounds.

Contents
1 Introduction
2 Progress in porphyrinoids
2.1 Porphyrinoids with various linkage of pyrrole units
2.2 Core modified porphyrins
2.3 Porphyrinoids with various macrocycle size
2.4 Porphyrinoids with various saturation states
3 Summary and outlook

Key words: porphyrinoids, N-confused porphyrin, expanded porphyrin, Mö, bius aromaticity, supramolecules, anion binding

中图分类号: 

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摘要

异卟啉研究进展*