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化学进展 2009, Vol. 21 Issue (05): 982-989 前一篇   后一篇

• 综述与评论 •

基于杂多酸的固体高质子导体*

刘镇; 吴庆银**; 宋小莉; 马赛   

  1. (浙江大学化学系 杭州310027)
  • 收稿日期:2008-06-10 修回日期:2008-09-01 出版日期:2009-05-24 发布日期:2009-05-05
  • 通讯作者: 吴庆银 E-mail:qywu@zju.edu.cn
  • 基金资助:

    国家自然科学基金

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Solid High-Proton Conductors Based on Heteropoly Acids

Liu Zhen ;  Wu Qingyin** ;  Song Xiaoli ;  Ma Sai   

  1. (Department of Chemistry, Zhejiang University, Hangzhou  310027, China)
  • Received:2008-06-10 Revised:2008-09-01 Online:2009-05-24 Published:2009-05-05
  • Contact: Wu Qingyin E-mail:qywu@zju.edu.cn

杂多酸固体高质子导体在燃料电池、传感器和电显色装置等方面具有潜在的应用前景。本文概述了杂多酸的质子导电性，归纳了其质子导电性的一些规律，以表格形式列举了各类杂多酸的电导率。将不同质量分数的杂多酸固载在各类固体基质上，可以对杂多酸质子导电材料改性以便于工业中实际应用。这些杂化材料兼有杂多酸的高质子导电性以及基质的稳定性与机械延展性。本文综述了近几年来新型杂多酸，杂多酸-无机基质复合材料，杂多酸-有机基质复合材料，杂多酸-多元基复合材料的质子电导率、稳定性、结构形态等等方面的研究进展，详细介绍了杂多酸在质子交换膜燃料电池中的应用，并对杂多酸固体高质子导体的应用前景进行了展望。

关键词： 杂多酸, 高质子导体, 质子导电, 质子交换膜燃料电池

Heteropoly acids (HPAs) solid high-proton conductors have received increasing attention over the last few years owing to their applications in fuel cells, sensors and electrochemical chromogenic devices etc. The present paper summarizes and reviews the current development in the area of the conductivities of HPAs, HPAs-inorganic matrix composite materials, HPAs-organic hybrid materials and HPAs-multiple composite materials. The conductivities of these materials are listed in the corresponding tables. Some laws of proton conductivity are summarized. By loading various weight percentages of HPAs onto different solid matrixs, the stability and mechanical ductility of solid proton conducting materials can be increased. The composite materials combine the high thermal and structural stability of matrixs with outstanding conductivity of HPAs, which place them among one of the most promising solid proton conductors. The higher the humidity is and the more the doping amount of HPAs is, the higher the conductivities of the composite materials are. The applications of HPAs in proton exchange membrane fuel cell are described in detail. The future development and research trends of HPAs solid high-proton conductors are prospected.

Contents
1 Introduction
2 Proton conductivity of heteropoly acids(HPAs)
3 Proton conductivity of HPAs-inorganic matrix composite materials
4 Proton conductivity of HPAs-organic hybrid materials
5 Proton conductivity of HPAs-multiple composite materials
6 The applications of HPAs in proton exchange membrane fuel cells(PEMFC)
7 Summary and forecast

Key words: heteropoly acids, high proton conductors, proton conduction, proton exchange membrane fuel cells(PEMFC)

中图分类号: 

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摘要

基于杂多酸的固体高质子导体*