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化学进展 2009, Vol. 21 Issue (05): 964-970 前一篇   后一篇

• 综述与评论 •

稀燃NOx储存－还原催化剂*

郭丽红; 刘咏; 孟明**   

  1. （天津市应用催化科学与工程重点实验室     天津大学化工学院催化科学与工程系    天津 300072）
  • 收稿日期:2008-05-14 修回日期:2008-06-28 出版日期:2009-05-24 发布日期:2009-05-05
  • 通讯作者: 孟明 E-mail:mengm@tju.edu.cn
  • 基金资助:

    863项目;国家自然科学基金

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NOx Storage-Reduction Catalysts Used for Lean-Burn NOx Removal

Guo Lihong; Liu Yong; Meng Ming**   

  1. (Tianjin Key Laboratory of Applied Catalysis Science and Engineering, Department of Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China)
  • Received:2008-05-14 Revised:2008-06-28 Online:2009-05-24 Published:2009-05-05
  • Contact: Meng Ming E-mail:mengm@tju.edu.cn

NOx 储存-还原（NSR）技术是最有前景的稀燃氮氧化物消除技术，自从日本丰田公司1996年首次提出NOx 储存还原这一概念后，一直受到研究者的广泛关注。本文综述了近十余年来NSR催化剂（PBA型、水滑石型、钙钛矿型）的研究进展，重点概述了目前比较公认的NOx储存－还原的反应路径，以及NSR催化剂的失活机制，包括H2O和CO2的负面影响，热失活和硫中毒问题，最后展望了NOx 储存还原技术未来的发展趋势。

关键词： 稀燃, 氮氧化物, 储存-还原

The NOx storage and reduction (NSR) technology will be the most promising way to reduce the NOx emission from lean-burn engines. Since the concept of NOx storage and reduction was firstly proposed by Toyota Co. in 1996, the NSR catalysts have attracted much attention in environmental catalysis area. The main advances in different formulated NSR catalysts (PBA-type、hydrotalcite-type、perovskite-type) in the last decade are systematically reviewed in this paper. The emphases are put on the commonly recognized NOx storage and reduction pathway and the NSR catalysts deactivation mechanism, including the negative effect of H2O and CO2, the thermal aging and SO2 poisoning. At last, the developing tendency for NSR technology is proposed.

Contents
1 PBA –type NSR catalysts
1.1 Precious metals
1.2 Storage components
1.3 Supports
2 Other materials and structures for NSR catalysts
3 Mechanisms of NOx storage-reduction reaction
4 Deactivation of NSR catalysts
5 Problems and Outlook

Key words: lean-burn, nitrogen oxides, storage-reduction

中图分类号: 

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摘要

稀燃NOx储存－还原催化剂*