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化学进展 2009, Vol. 21 Issue (05): 1040-1051 前一篇   后一篇

• 综述与评论 •

核磁共振波谱技术在室温离子液体研究中的应用*

翟翠萍1; 刘学军1; 王键吉2**   

  1. (1. 河南大学化学化工学院     开封   475001；2. 河南师范大学化学与环境科学学院    新乡  453007)
  • 收稿日期:2008-06-02 修回日期:2008-10-19 出版日期:2009-05-24 发布日期:2009-05-05
  • 通讯作者: 王键吉 E-mail:Jwang@henannu.edu.cn
  • 基金资助:

    国家自然科学基金

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Applications of NMR Techniques in the Research of Room Temperature Ionic Liquids

Zhai Cuiping1;  Liu Xuejun1 ; Wang Jianji2**   

  1. (1.College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, China; 2. College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China)
  • Received:2008-06-02 Revised:2008-10-19 Online:2009-05-24 Published:2009-05-05
  • Contact: Wang Jianji E-mail:Jwang@henannu.edu.cn

室温离子液体作为一种绿色溶剂和功能材料，越来越引起人们的重视，其研究手段也越来越多。本文着重概述了核磁共振方法在测定离子液体的结构、纯度及性质，研究离子液体阴阳离子间的相互作用、离子液体与其他化合物的相互作用、离子液体及其在混合体系中的动力学特征、离子液体在溶液中的聚集行为，以及测定离子液体的热力学参数中的应用。

关键词： 核磁共振, 室温离子液体

As new green solvents and functional materials, room temperature ionic liquids (ILs) have attracted great attention. The present paper reviews the applications of NMR techniques in the research of structure, properties, and interactions of cations with anions of ILs, interactions between ILs and the other compounds, the dynamic characteristics of ILs and their mixtures, the aggregation behavior of ILs in solutions, and the determination of thermodynamic parameters of ILs.

Contents
1 Determination of the structure, purity and properties of ionic liquids
2 Study on the interactions of cations with anions of ionic liquids
3 Study on the interactions of ionic liquids with the other compounds
4 Study on the dynamic characteristics of ionic liquids and their mixtures
4.1 Measurements of the spin-lattice relaxation time and the molecular rotation correlation time of ionic liquids
4.2 Measurements of the self-diffusion coefficients of ionic liquids
5 Study on the aggregation behavior of ionic liquids in solutions
6 Determination of the thermodynamics parameters of ionic liquids

Key words: NMR, room temperature ionic liquids

中图分类号: 

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