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化学进展 2009, Vol. 21 Issue (0203): 467-473 前一篇   后一篇

• 环境化学专辑 •

砷形态分析

苑春刚1,2; X. Chris Le2**   

  1. (1. 华北电力大学环境科学与工程学院　保定071003 ; 21Division of Analytical and Environmental Toxicology , Department of Laboratory Medicine and Pathology , University of Alberta , Edmonton , Alberta , T6G2G3 , Canada)
  • 收稿日期:2009-01-07 出版日期:2009-03-24 发布日期:2009-04-03
  • 通讯作者: X. Chris Le E-mail:xc.le@ualberta.ca
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Arsenic Speciation Analysis

Yuan Chungang1 ,2; X. Chris Le2**   

  1. (1. School of Environmental Science & Engineering , North China Electric Power University , Baoding 071003 , China ; 2.Division of Analytical and Environmental Toxicology , Department of Laboratory Medicine and Pathology , University of Alberta , Edmonton , Alberta , T6G2G3 , Canada)
  • Received:2009-01-07 Online:2009-03-24 Published:2009-04-03
  • Contact: X. Chris Le E-mail:xc.le@ualberta.ca

综述了近几年砷形态分析方法的最新研究进展。以常见砷形态分析方法发展为主线，讨论了不同砷形态分析方法的发展过程和应用情况，对不同方法的优缺点进行了扼要评述。早期的砷形态分析方法主要是以色谱和原子光谱联用为主要手段，随着不同的、更为有效的砷化合物检测手段的出现，砷形态分析方法也不断进行完善、发展。目前，在定量分析方面以液相色谱和电感耦合等离子体质谱联用方法为主要常规分析手段；在砷化合物定性分析方面，色谱-电感耦合等离子体质谱与电喷雾质谱相互补充的联用方法逐渐成为了主要分析手段。砷形态分析在环境健康和毒理学方面的应用是目前该领域的主要研究方向，结合国际上最新的研究进展，讨论了砷形态分析方法在环境毒理学等研究中发挥的重要作用。

关键词： 砷形态分析, 联用技术, 气态砷, 原子光谱, 电感耦合等离子体质谱, 有机质谱, 色谱

This article briefly summarizes the recent developments in arsenic speciation analysis and discusses the benefits and defects of the various speciation techniques as applied to studies of environmental and toxicological chemistry of arsenic. Coupling of highly efficient separation with highly sensitive detection is often necessary to quantify trace concentrations of arsenic species present in complex samples. The combination of high performance liquid chromatography (HPLC) separation with both inductively coupled plasma mass spectrometry (ICPMS) and electrospray tandem mass spectrometry (ES/MS/MS) detection has been shown most useful for arsenic speciation in environmental and biological studies. These new arsenic speciation techniques enable the determination of new arsenic metabolites and their interaction products with proteins, resulting in improved understanding of arsenic metabolism, toxicity, and biogeochemical cycling.

Contents
1 Hyphenated liquid chromatography and atomic spectrometry techniques for arsenic speciation
2 Liquid chromatography combined with inductively coupled plasma mass spectrometry for arsenic speciation analysis
3 Molecular mass spectrometry for arsenic speciation analysis
4 Atomic and molecular mass spectrometry techniques for arsenic speciation analysis
5 Analysis of volatile arsenic species
6 Perspective

Key words: arsenic speciation analysis, hyphenated techniques, volatile arsenic species, atomic spectrometry, inductively coupled plasma mass spectrometry, electrospray tandem mass spectrometry, chromatography

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摘要

砷形态分析