English
往期目录
新闻公告
More
化学进展 2009, Vol. 21 Issue (0203): 369-376 前一篇   后一篇

• 环境化学专辑 •

全氟化合物的环境问题

史亚利;潘媛媛;王杰明;蔡亚歧**   

  1. (中国科学院生态环境研究中心环境化学与生态毒理学国家重点实验室　北京100085)
  • 收稿日期:2008-12-04 出版日期:2009-03-24 发布日期:2009-04-03
  • 通讯作者: 蔡亚歧 E-mail:caiyaqi@rcees.ac.cn
下载PDF ( 3928 ) 引用
导出 被引次数 ( 101 | 29 )

Perfluorinated Chemicals Related Environmental Problems

Shi Yali; Pan Yuanyuan; Wang Jieming; Cai Yaqi**   

  1. (State Key Laboratory of Environmental Chemistry and Ecotoxicology , Research Center for Eco-Environmental Science , Chinese Academy of Sciences , Beijing 100085 , China)
  • Received:2008-12-04 Online:2009-03-24 Published:2009-04-03
  • Contact: Cai Yaqi E-mail:caiyaqi@rcees.ac.cn

全氟化合物是一类新型有机污染物，它具有疏油、疏水特性，在环境中可以长期稳定存在，其环境污染问题已经引起了人们的广泛关注，其研究也已成为近年环境科学和分析化学的热点，但我国的研究还较少，并缺乏环境污染方面的系统性数据。本文介绍了全氟化合物的毒理效应、污染特点、污染现状和环境行为及环境修复等方面的内容，讨论了目前存在的问题，为我国全氟化合物环境污染研究提供相应参考。

关键词： 全氟化合物, 环境污染, 环境行为, 毒理, 环境修复

Perfluorinated chemicals (PFCs) are new emerging organic pollutants that can repel both water (hydrophobic) and oils (oleophobic), and very stable and difficult to be degraded in environment conditions. PFCs related environmental problems have attracted a great attention from many scientists and have become research hotspots in the field of environmental and analytical chemistry. However, few studies of PFCs pollution status have been reported in China. This paper reviews the toxicological effects, characteristics, pollution status, environmental behavior and remediation of PFCs. The currently existing problems and trends are also discussed.

Contents
1 Introduction
2 The toxicological effects of PFCs
3 The pollution status and environmental behavior of PFCs
3.1 The pollution status of PFCs in different environment
3.2 The status of PFCs in different organisms and human
4 The environmental remediation
5 Summary and Prospect

Key words: perfluorinated chemicals, environmental pollution, environmental behavior, toxicological effects, environmental remediation

中图分类号: 

()

[ 1 ] 　Kissa E. Fluorinated Surfactants : Synthesis , Properties , and Applications , Vol . 50. New York : Marcel Dekker , 1994
[ 2 ] 　Olsen G W, Burris J M, Mandel J H , Zobel L R. J . Occup. Environ. Med. , 1999 , 41 : 799 —806
[ 3 ] 　Kissa E. Fluorinated surfactants and repellents , 2nd edition. New York : Marcel Dekker Inc. , 2001
[ 4 ] 　Kannan K, Tao L , Sinclair E , Pastva S D , Jude D J , Giesy J P.Arch. Environ. Contam. Toxicol . , 2005 , 48 : 559 —566
[ 5 ] 　Tomy G T, Budakowski W, Halldorson T, et al . Environ. Sci .Technol . , 2004 , 38 : 6475 —6481
[ 6 ] 　OSPAR Commission. Perfluorooctane Sulphonate (PFOS) . Hazardous Substances Series 2005 (2006 update) . [ 2008-11-12 ] http://www.ospar.org/documents/dbase/publications/P00269_BD%20on%20PFOS%20_2006%20version_.pdf
[ 7 ] 　Tittlemier S A , Pepper K, Seymour C , Moisey J , Bronson R , Cao X L , Dabeka R W. J . Agric. Food Chem. , 2007 , 55 : 3203 —3210
[ 8 ] 　Apelberg B J , Goldman L R , Calafat A M, Herbstman J B ,Kuklenyik Z, Heidler J , Needham L L , Halden R U , Witter F R.Environ. Sci . Technol . , 2007 , 41 (11) : 3891 —3897
[ 9 ] 　Young C J , Furdui V I , Franklin J , Koerner R M, Muir D C G,Mabury S A. Environ. Sci . Technol . , 2007 , 41 (10) : 3455 —3461
[10 ] 　Furdui V I , Stock N L , Ellis D A , Butt CM, Whitter D M, Crozier P W, Reiner E J , Muir D C G, Mabury S A. Environ. Sci .Technol . , 2007 , 41 : 1554 —1559
[11 ] 　Jahnke A , Berger U , Ebinghaus R , Temme C. Environ. Sci .Technol . , 2007 , 41 (9) : 3055 —3061
[12 ] 　Tang C Y, Fu Q S , Criddle C S , Leckie J O. Environ. Sci .Technol . , 2007 , 41 : 2008 —2014
[13 ] 　Guruge K S , Taniyasu S , Yamashita N , Wijeratna S , Mohotti KM,Seneviratne H R , Kannan K, Yamanaka N , Miyazaki S. J . Environ.Monitor , 2005 , 7 : 371 —377
[14 ] 　Houde M, Martin J W, Letcher R J , Solomon K R , Muir D C G.Environ. Sci . Technol . , 2006 , 40 : 3463 —3473
[15 ] 　Olsen GW, Huang H Y, Helzlsouer KJ , Hansen KJ , Butenhoff J L , Mandel J H. Environ. Health Persp. , 2005 , 113 : 539 —545
[16 ] 　Powley C R , George S W, Russell M H , Hoke R A , Buck R C.Chemosphere , 2008 , 70 : 664 —672
[17 ] 　Bossi R , Riget F F , Dietz R. Environ. Sci . Technol . , 2005 , 39 :7416 —7422
[18 ] 　Kannan K, Yun S H , Evans T J . Environ. Sci . Technol . , 2005 ,39 : 9057 —9063
[19 ] 　U. S. Environmental Protection Agency. 2010/15 PFOA Stewardship Program , 2006. [2008-10-01 ] http://www.epa.gov/opptintr/pfoa/pubs/pfoastewardship.htm.
[20 ] 　Renner R. Environ. Sci . Technol . , Policy News [On line ]2004
[21 ] 　European Parliament and The Council of the European Union.Directive 2009/122/ECOF. Off . J . Eur. Union 2006 , L372/32
[22 ] 　U. S. EPA ( Environmental Protection Agency) . Federal Register 2000 , 65 : 62319 —62333
[23 ] 　OECD report , ENVPJ MPRD(2002) 17/FINAL , 21 Nov. 2002
[24 ] 　OSPAR Commission. The Hague , 2003 , [ 2008-11-12 ] http://www.ospar.org/v-meetings/download.asp
[25 ] 　3M Company. US EPA Administrative Record , 2003
[26 ] 　Kennedy J G L , Butenhoff J L , Olsen G W, et al . Crit . Rev.Toxicol . , 2004 , 34 (4) : 351 —384
[27 ] 　Lau C , Thibodeaux J R , Hanson R G, et al . Toxicol . Sci . , 2003 ,74 (2) : 382 —392
[28 ] 　Luebker D J , Case M T, York R G, Moore J A , Hansen K J ,Butenhoff J L. Toxicology , 2005 , 215 (1/2) : 126 —148
[29 ] 　Luebker D J , York R G, Hansen KJ , Moore J A , Butenhoff J L.Toxicology , 2005 , 215 (1P2) : 149 —169
[30 ] 　Thibodeaux J R , Hanson R G, Rogers J M, Grey B E , Barbee B D ,Richards J H , et al . Toxicol . Sci . , 2003 , 74 (2) : 369 —381
[31 ] 　Lau C , Thibodeaux J R , Hanson R G, et al . Toxicol . Sci . , 2006 ,90(2) : 510 —518
[32 ] 　Wolf C J , Fenton S E , Schmid J E , et al . Toxicol . Sci . , 2007 , 95(2) : 462 —473
[33 ] 　Abbott B D , Wolf CJ , Schmid J E , et al . Toxicol . Sci . , 2007 , 98(2) : 571 —81
[34 ] 　Abbott B D , Wolf CJ , Schmid J E , et al . Reproductive Toxicology ,2008 , doi : 10.1016/j . reprotox. 2008. 05. 061
[35 ] 　Kudo N , Suzuki E , Katakura M, Ohmori K, Noshiro R , Kawashima Y. Chem. Biol . Interact . , 2001 , 134 : 203 —216
[36 ] 　Pastoor T P , Lee P K, Perri MA , Gillies P J . Exp. Mol . Pathol . ,1987 , 47 : 98 —109
[37 ] 　Chinje E , Kentish P , Jarnot B , George M, Gibson G. Toxicol .Lett . , 1994 , 71 : 69 —75
[38 ] 　Van Refelghem M J , Inhorn S L , Peterson R E. Toxicol . Appl .Pharmacol . , 1987 , 87 : 430 —439
[39 ] 　Davis J W, Vanden Heuve J P , Peterson R E. Lipids , 1991 , 26 :857 —859
[40 ] 　Liao C , Li X, Wu B , Duan S , Jiang G. Environ. Sci . Technol . ,2008 , 42 : 5335 —5341
[41 ] 　刘冰(Liu B) , 于棋麟( Yu Q L) , 金一和(Jin Y H) , 赵翠霞(Zhao C X) , 王静(Wang J ) , 王柯(Wang K) , 翟成(Zhai C) . 毒理学杂志(Journal of Toxicology) , 2005 , 19 : 225 —225
[42 ] 　Liu C S , Yu K, Shi XJ , Wang J X, Lam P KS , Wu R S S , Zhou B S. Aquatic Toxicology , 2007 , 82 : 135 —143
[43 ] 　Liu C S , Du YB , Zhou B S. Aquatic Toxicology , 2007 , 85 : 267 —277
[44 ] 　Shi X, Du YB , Lam P KS , Wu R S S , Zhou B S. Toxicology and Applied Pharmacology , 2008 , 230 : 23 —32
[45 ] 　Wei Y H , Chan L L , Wang D Z, Zhang H X, Wang J S , Dai J Y.J . Proteome. Research , 2008 , 7 : 1729 —1739
[46 ] 　范轶欧(Fan YO) , 金一和(Jin Y H) , 麻懿馨(Ma Y X) , 张颖花(Zhang Y H) , 张晓　(Zhang X P) , 齐藤宪光(Saitou N) . 卫生研究(Journal of Hygiene Research) , 2005 , 34 (1) : 37 —39
[47 ] 　王昕(Wang X) , 陈誉华(Chen Y H) . 中国现代医学杂志(China Journal of Modern Medicine) , 2006 , 16 : 1646 —1650
[48 ] 　Newsted J L , Beach S A , Gallagher S , Giesy J P. Arch. Environ.Contam. Toxicol . , 2005 , 50 : 411 —420
[49 ] 　Newsted J L , Coady K K, Beach S A , et al . Environ. Toxico. & Pharm. , 2007 , 23 : 1 —9
[50 ] 　Stock N L , Furdui V I , Muir D C G, Mabury S A. Environ. Sci .Technol . , 2007 , 41 : 3529 —3536
[51 ] 　Wallington TJ , Hurley M D , Xia J , Wuebbles D J , Sillman S , Ito A , Penner J E , Ellis D A , Martin J , Mabury S A , Nielsen O J ,Andersen M P S. Environ. Sci . Technol . , 2006 , 40 : 924 —930
[52 ] 　Shoeib M, Harner T, Vlahos P. Environ. Sci . Technol . , 2006 , 40 :7577 —7583
[53 ] 　Armitage J , Cousins I T, Buck R C , Prevedouros K, Russell M H ,MacLeod M, Korzeniowski , S H. Environ. Sci . Technol . , 2006 ,40 : 6969 —6975
[54 ] 　Wania F. Environ. Sci . Technol . , 2007 , 41 : 4529 —4535
[55 ] 　Yamashita N , Taniyasu S , Petrick G, Wei S , Gamo T, Lam P KS ,Kannan K. Chemosphere , 2008 , 70 (7) : 1247 —1255
[56 ] 　Rhoads K R , Janssen E M L , Luthy R G, Criddle C S. Environ.Sci . Technol . , 2008 , 42 (8) : 2873 —2878
[57 ] 　Sinclair E , Kannan K. Environ. Sci . Technol . , 2006 , 40 ( 5) :1408 —1414
[58 ] 　Becker A M, Gerstmann S , Frank H. Chemosphere , 2008 , 72 (1) :115 —121
[59 ] 　Boulanger B , Vargo J D , Schnoor J L , Hornbuckle K C. Environ.Sci . Technol . , 2005 , 39 (15) : 5524 —5530
[60 ] 　Wang N , Szostek B , Buck R C , et al . Environ. Sci . Technol . ,2005 , 39 : 7516 —7528
[61 ] 　Moriwaki H , Takatah Y, Arakawa R. J . Environ. Monit . , 2003 ,5 : 753 —757
[62 ] 　Nakata A , Katsumata T, Iwasaki Y, Ito R , Saito K, Izumi S ,Makino T, Kishi R , Nakazawa H. Organohalogen Compd. , 2007 ,69 : 2844 —2846
[63 ] 　Kubwabo C S B , Zhu J , Marro L. J . Environ. Monit . , 2005 , 7 :1074 —1078
[64 ] 　Strynar M J , Lindstrom A B. Environ. Sci . Technol . , 2008 , 42(10) : 3751 —3756
[65 ] 　Fromme H , Nitschke L , Kiranoglu M, Albrecht M, Vêlkel W.Organohalogen Compounds , 2008 , 70 : 1048 —1050
[66 ] 　金一和(Jin Y H) , 丁梅(Ding M) , 翟成(Zhai C) , 王列(Wang L) , 董光辉(Dong G H) , 舒为群(Shu W Q) , 张颖花(Zhang Y H) , 齐藤宪光(Saitou N) , 佐佐木和明(Sasaki K) . 生态环境(Ecology and Environment) , 2006 , 15 : 486 —489
[67 ] 　刘冰(Liu B) , 金一和(Jin Y H) , 于棋麟(Yu Q L) , 王柯(Wang K) , 董光辉(Dong G H) , 李洪源(Li H Y) , 齐藤宪光(Saitou N) , 佐佐木和明( Sasaki K) . 环境科学学报(Acta Scientiae Circumstantia) , 2007 , 27 : 480 —486
[68 ] 　刘薇(Liu W) , 金一和(Jin Y H) , 全燮(Quan X) , 董光辉(Dong G H) , 刘冰(Liu B) , 王静(Wang J ) , 王柯(Wang K) , 于棋麟(Yu Q L) , 齐藤宪光(Saitou N) . 环境科学(Chinese Journal of Environmental Science) , 2007 , 28 : 2068 —2073
[69 ] 　Ju X D , Jin Y H , Sasaki K, Saito N. Environ. Sci . Technol . ,2008 , 42 : 3538 —3542
[70 ] 　So M K, Miyake Y, Yeung W Y, Ho YM, Taniyasu S , Rostkowski P , Yamashita N , Zhou B S , Shi XJ , Wang J X, Giesy J P , Yu H ,Lam P K S. Chemosphere , 2007 , 68 : 2085 —2095
[71 ] 　So M K, Taniyasu S , Yamashita N , Giesy J P , Zheng J , Fang Z, Im S H , Lam P KS. Environ. Sci . Technol . , 2004 , 38 : 4056 —4061
[72 ] 　Fromme H , Tittlemier S A , Vêkel W, Wilhelm M, Twardella D.Int . J . Hyg. Environ. Health , 2008 , doi :10. 1016Pj . ijheh. 2008.04. 007
[73 ] 　Verreault J , Berger U , Gabrielsen G. Environ. Sci . Technol . ,2007 , 41 : 6671 —6677
[74 ] 　Holmstrom K E , Jornberg U , Bignert A. Environ. Sci . Technol . ,2005 , 39 : 80 —84
[75 ] 　Wang Y, Yeung L , Taniyasu S , Yamashita N , Lam J , Lam P.Environ. Sci . Technol . , 2008 , 42 : 8146 —8151
[76 ] 　Yoo H , Kannan K, Kim S K, Lee K T, Newsted J L , Giesy J P.Environ. Sci . Technol . , 2008 , 42 (15) : 5821 —5827
[77 ] 　Reiner J L , Nakayama S F , Delinsky A D , Strynar MJ , Lindstrom A B. Environ. Sci . Technol . , 2008 , doi : 10. 1021Pes800770f
[78 ] 　Gruber L , Schlummer M, Ungewiss J , Wolz G, Moeller A , Weise N , Sengl M, Frey S , Gerst M, Schwaiger J . Organohalogen Compd. , 2007 , 69 : 3
[79 ] 　Falandysz J , Taniyasu S , Gulkowska A , Yamashita N , Schulte-Oehlmann U. Environ. Sci . Technol . , 2006 , 40 : 748 —751
[80 ] 　Hê lzer J , Midasch O , Rauchfuss K, Kraft M, Reupert R , Angerer J , Kleeschulte P , Marschall N , Wilhelm M. Environ. Health Perspect . , 2008 , 116 : 651 —657
[81 ] 　Weihe P , Kato K, Calafat A M, Nielsen F , Wanigatunga A A ,Needham L L , Grandjean P. Environ. Sci . Technol . , 2008 , 42(16) : 6291 —6295
[82 ] 　Gulkowska A , Jiang Q , So M K, Taniyasu S , Lam P KS , Yamashita N. Environ. Sci . Technol . , 2006 , 40 : 3736 —3741
[83 ] 　Fromme H , Midasch O , Twardella D , Angerer J , Boehmer S , Liebl B. Int . Arch. Occup. Environ. Health , 2007 , 80 : 313 —319
[84 ] 　Midasch O , Schettgen T, Angerer J . Int . J . Hyg. Environ. Health ,2006 , 209 : 489 —496
[85 ] 　Wilhelm M, Angerer J , Fromme H , Hêzer J . Int . J . Hyg. Environ.Health , 2008 , 2009 , 212 (1) : 56 —60
[86 ] 　Karrman A , Mueller J F , van Bavel B , Harden F , Toms L M L ,Lindstrom G. Environ. Sci . Technol . , 2006 , 40 ( 12) : 3742 —3748
[87 ] 　Leo W Y, So YM K, Jiang G, Taniyasu S , Yamashita N , Song M,Wu Y, Li J , Giesy J P , Guruge K S , Lam P K S. Environ. Sci .Technol . , 2006 , 40 : 715 —720
[88 ] 　金一和(Jin Y H) , 刘晓(Liu X) , 张迅(Zhang X) , 李彤(Li T) ,张颖花(Zhang Y H) , 齐藤宪光(Saitou N) , 佐佐木和明(Sasaki K) . 中国公共卫生(China Public Health) , 2003 , 19 : 1200 —1201
[89 ] 　金一和(Jin Y H) , 舒为群(Shu W Q) , 丁梅(Ding M) , 翟成(Zhai C) , 齐藤宪光(Saitou N) , 佐佐木和明(Sasaki K) . 毒理学杂志(Journal of Toxicology) , 2005 , 19 : 318 —319
[90 ] 　Kuklenyik Z, Reich J A , Tully J S , Needham L L , Calafat A M.Environ. Sci . Technol . , 2004 , 38 : 3698 —3704
[91 ] 　K? rrman A , Ericson I , van Bavel B , Darnerud P O , Aune M, Glynn A , Lignell S , Lindstrêm G. Environ. Health Perspect . , 2007 , 115 :226 —230
[92 ] 　Tao L , Kannan K, Wong CM, Arcaro KF , Butenhoff J L. Environ.Sci . Technol . , 2008 , 42 (8) : 3096 —3101
[93 ] 　Tao L , Ma J , Kunisue T, Libelo E L , Tanabe S , Kannan K.Environ. Sci . Technol . , 2008 , 42 (22) : 8597 —8602
[94 ] 　Vêlkel W, Genzel-Boroviczény O , Demmelmair H , Gebauer C ,Koletzko B , Verdugo-Raab U , Twardella D , Fromme H. Int . J .Hyg. Environ. Health , 2008 , 211 (3/4) : 440 —446
[95 ] 　Bernsmann T, Fürst P. Organohalogen Compounds , 2008 , 70 :718 —721
[96 ] 　So M K, Yamashita N , Taniyasu S , Jiang Q , Giesy J P , Chen K,Lam P K S. Environ. Sci . Technol . , 2006 , 40 : 2924 —2929
[97 ] 　Hori H , Hayakawa E , Einaga H , Kutsuna S , Koike K, Ibusuki T,Kitagawa H , Arakawa R. Environ. Sci . Technol . , 2004 , 38 :6118 —6124
[98 ] 　Hori H , Yamamoto A , Hayakawa E , Taniyasu S , Yamashita N ,Kutsuna S , Kitagawa H , Arakawa R. Environ. Sci . Technol . ,2005 , 39 : 2383 —2388
[99 ] 　Hori H , Yamamoto A , Kutsuna S. Environ. Sci . Technol . , 2005 ,39 : 7692 —7697
[100 ] Moriwaki H , Takagi Y, Tanaka M, Tsuruho K, Okitsu K, Maeda Y.Environ. Sci . Technol . , 2005 , 39 : 3388 —3392
[101 ] Vecitis C D , Park H , Cheng J , Mader B T, Hoffmann M R. J .Phys. Chem. A , 2008 , 112 (18) : 4261 —4270
[102 ] Hori H , Nagaoka Y, Yamamoto A , Sano T, Yamashita N , Taniyasu S , Kutsuna S. Environ. Sci . Technol . , 2006 , 40 : 1049 —1054
[103 ] Ochoa-Herrera V , Sierra-Alvarez R , Somogyi A , Jacobsen N E ,Wysocki V H , Field J A. Environ. Sci . Technol . , 2008 , 42 (9) :3260 —3264
[1] 周晋, 陈鹏鹏. 二维纳米材料的改性及其环境污染物治理方面的应用[J]. 化学进展, 2022, 34(6): 1414-1430.
[2] 孙义民, 李厚燊, 陈振宇, 王东, 王展鹏, 肖菲. MXene在电化学传感器中的应用[J]. 化学进展, 2022, 34(2): 259-271.
[3] 谢勇, 韩明杰, 徐钰豪, 熊晨雨, 王日, 夏善红. 荧光内滤效应在环境检测领域的应用[J]. 化学进展, 2021, 33(8): 1450-1460.
[4] 雷雨洋, 李方方, 欧阳洁, 李敏杰, 郭良宏. 浙江地区抗生素残留的环境分布特征及来源分析[J]. 化学进展, 2021, 33(8): 1414-1425.
[5] 吕维扬, 孙继安, 姚玉元, 杜淼, 郑强. 层状双金属氢氧化物的控制合成及其在水处理中的应用[J]. 化学进展, 2020, 32(12): 2049-2063.
[6] 张安睿, 艾玥洁. 共价有机框架(COFs)材料的结构控制及其在环境化学中的应用[J]. 化学进展, 2020, 32(10): 1564-1581.
[7] 丁星, 杨祥龙, 熊中亮, 陈浩, 张礼知. 铋系光催化剂去除环境污染物[J]. 化学进展, 2017, 29(9): 1115-1126.
[8] 鲍恋君, 郭英, 刘良英, 曾永平*. 珠江三角洲典型有机污染物的环境行为及人群暴露风险[J]. 化学进展, 2017, 29(9): 943-961.
[9] 李忠民, 郭良宏. 氟调醇的环境污染与毒理学研究[J]. 化学进展, 2016, 28(7): 993-1005.
[10] 尹立娜, 王斌, 马瑞雪, 袁宏林, 余刚. 手性PPCPs环境行为与效应的对映体选择性[J]. 化学进展, 2016, 28(5): 744-753.
[11] 史亚利, 蔡亚岐. 全氟和多氟化合物环境问题研究[J]. 化学进展, 2014, 26(04): 665-681.
[12] 许杰龙, 周顺桂, 袁勇, 王跃强, 庄莉*. 有“生命”的电线:浅析微生物纳米导线电子传递机制及其应用[J]. 化学进展, 2012, (9): 1794-1800.
[13] 单国强, 孙怀华, 侯征, 祝凌燕. 衍生化技术用于全氟烷酸化合物色谱分析的现状与趋势[J]. 化学进展, 2012, (10): 2019-2027.
[14] 张智勇, 赵宇亮, 柴之芳. 纳米毒理学研究中的放射分析方法[J]. 化学进展, 2011, 23(7): 1527-1533.
[15] 曲颖, 李玉锋, 陈春英. 同步辐射及相关核分析技术在纳米材料生物效应研究中的应用[J]. 化学进展, 2011, 23(7): 1534-1546.
阅读次数
全文


摘要

全氟化合物的环境问题