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化学进展 2009, Vol. 21 Issue (01): 121-127 前一篇   后一篇

• 综述与评论 •

阳极氧化法制备TiO2多孔薄膜*

陈国华;赵峰鸣**   

  1. (浙江工业大学应用化学系 杭州 310014)
  • 收稿日期:2008-03-26 修回日期:2008-05-12 出版日期:2009-01-24 发布日期:2009-01-25
  • 通讯作者: 赵峰鸣 E-mail:zhaofm@zjut.edu.cn
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Synthesis of Porous TiO2 Films by Anodic Oxidation

Chen Guohua;Zhao Fengming**   

  1. (Department of Applied Chemistry, Zhejiang University of Technology, Hangzhou 310014, China)
  • Received:2008-03-26 Revised:2008-05-12 Online:2009-01-24 Published:2009-01-25
  • Contact: Zhao Fengming E-mail:zhaofm@zjut.edu.cn

本文综述了制备TiO2薄膜的各种方法，详细介绍了阳极氧化法制备TiO2多孔膜的进展，在非含氟电解液体系中，对纯钛进行阳极氧化处理可制得表面呈无规则生长的多孔膜结构；在含氟电解液体系中，则可自组织形成高度有序的TiO2纳米管阵列，并指出阳极氧化法是可在常温低压下进行、操作工艺简单、薄膜性能稳定、再现性好的一种最具工业化应用潜力的制备方法。

关键词： 电化学, TiO2, 阳极氧化法, 多孔膜, 纳米管阵列

The various types of processes for synthesis of TiO2 films are discussed and evaluated respectively. The method of anodic oxidation is presented particularly in the aspects of the current development of the formation mechanism, the materials category and the affecting factors. The anodic oxidation has advantages over the other methods. Without the addition of fluoride, the pores are formed randomly and show no clear organization. With the addition of fluoride, self-organized nano-porous structure is produced and an ordered TiO2 nano-tube arrays is revealed. Furthermore, its simplicity and lower cost make it the promising anodic preparation in large production of porous TiO2 films.

Contents
1 Introduction
2 Synthetic methods of TiO2 films
3 TiO2 porous materials by anodic oxidation
3.1 Mechanism of TiO2 porous films by anodic oxidation
3.2 Synthesis of TiO2 porous films in different electrolyte
3.3 Effect of anodic voltage for synthesis of TiO2 porous films
4 Summary and expectation

Key words: electrochemistry, TiO2, anodic oxidation, porous films, nano-tube arrays

中图分类号: 

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[ 1 ] 　Gratzel M. Nature , 2001 , 414 : 338 —241
[ 2 ] 　Pfaff G, Reynders P. Chem. Rev. , 1999 , 99 : 1963 —1977
[ 3 ] 　Trapalis C C , Keivanidis P , Kordas G, et al . Thin Solid Films ,2003 , 433 (1/2) : 186 —192
[ 4 ] 　Chen X B , Mao S S. Chem. Rev. , 2007 , 107 : 2891 —2959
[ 5 ] 　Assen A. Mater. Chem. Phy. , 2002 , 76 : 274 —278
[ 6 ] 　Yakovleva N M, Anicai L , Yakovlev A N , et al . Thin Solid Films ,2002 , 416 : 16 —23
[ 7 ] 　Su Y C , Cui B Z, Martínez L , et al . Thin Solid Films , 2002 , 406 :64 —69
[ 8 ] 　周圆( Zhou Y) , 李长虹(Li C H) . 电镀与精饰( Plating and Finishing) , 2007 , 29 (3) : 23 —26
[ 9 ] 　姜妍彦(Jiang Y Y) , 钟萍(Zhong P) , 王承遇(Wang C Y) 等. 材料导报(Materials Review) , 2000 , 14 (6) : 38 —40
[10 ] 　Piveteau I D , Girona M I , Achlapbach L. J . Mater. Sci . Mater.Med. , 1999 , 10 : 161 —167
[11 ] 　Varghese O K, Gong D W, Paulose M, et al . Sensors and Actuators B : Chemical , 2003 , 93 : 338 —344
[12 ] 　Prida V M, Hernandez V M, Cerverac M, et al . J . Magnetism and Magnetic Materials , 2005 , 294 : e69 —e72
[13 ] 　Kim D S , Han S J , Kwak S Y. J . Colloid and Interface Science ,2007 , 316 : 85 —91
[14 ] 　Pourmanda M, Taghavinia N. Materials Chemistry and Physics ,2008 , 107 : 449 —455
[15 ] 　Shindea P S , Sadalec S B , Patilb P S , et al . Solar Energy Materials&Solar Cells , 2008 , 92 : 283 —290
[16 ] 　Toku H , Pesso R S , Maciel H S , et al . Surface & Coatings Technology , 2008 , 202 : 2126 —2131.
[17 ] 　Maekawa T, Kurosaki K, Tanaka T, et al . Surface & Coatings Technology , 2007 , 202 (13) : 3067 —3071
[18 ] 　Radice S , Kerna P , Dietschb H , et al . J . Colloid and Interface Science , 2008 , 318 : 264 —270
[19 ] 　Kern P , Schwaller P , Michler J . Thin Solid Films , 2006 , 494 :279 —286
[20 ] 　Zwilling V. Surf . Interface Anal . , 1999 , 27 : 629 —637
[21 ] 　王炜(Wang W) , 陶杰(Tao J ) , 章伟伟(Zhang WW) 等. 钛工业进展(Titanium Industry Progress) , 2005 , 22 (2) : 30 —33
[22 ] 　王周成(Wang Z C) , 黄龙门(Wang L M) , 唐毅(Tang Y) . 厦门大学学报(自然科学版) ( Journal of Xiamen University (Natural Science) ) , 2006 , 45 (5) : 677 —682
[23 ] 　田甜(Tian T) , 肖秀峰(Xiao X F) , 刘榕芳(Liu R F) . 传感技术学报(Chinese Journal of Sensors and Actuators) , 2006 , 19 (5) :2310 —2313
[24 ] 　李贺(Li H) , 姚素微(Yao S W) , 张卫国(Zhang W G) 等. 无机材料学报(Journal of Inorganic Materials) , 2007 , 22 (2) : 349 —353
[25 ] 　Jaeggi C , Kern P , Michler J , et al . Surface &Coatings Technology ,2005 , 200 : 1913 —1919.
[26 ] 　Yang C L , Chen F L. Materials Chemistry and Physics , 2006 , 100 :268 —274
[27 ] 　Capek D , Gigandet M P , Masmoudi M, et al . Surface & Coatings Technology , 2008 , 202 : 1379 —1384
[28 ] 　Schweinsberg M, Kudelka S , Michaelis A , et al . Materials and Corrosion , 1998 , 49 : 161 —168
[29 ] 　Wang S , Wu X H , Qin W, et al . Materials Letters , 2008 , 62 :1078 —1081
[30 ] 　Aikaterini G M, Mamas I P. Electroanalysis , 2005 , 17 ( 20 ) :1878 —1885
[31 ] 　Brunella M F , Diamanti M V , Pedeferri M P. Thin Solid Films ,2007 , 515 : 6309 —6313
[32 ] 　Iwata T, Ishikawa M, Ichino R , et al . Surface and Coatings Technology , 2003 , 169P170 : 703 —706
[33 ] 　Das K, Bose S , Bandyopadhyay A. Acta Biomaterialia , 2007 , 3 :573 —585
[34 ] 　Velten D , Biehl V , Aubertin F , et al . J . Biomed. Mater. Res. ,2002 , 59 : 18 —28
[35 ] 　Zorn G, Lesman A , Gotman I. Surface & Coatings Technology ,2006 , 201 : 612 —618
[36 ] 　Onoda K, Yoshikawa S. Applied Catalysis B : Environmental , 2008 ,89 : 277 —285
[37 ] 　Onoda K, Yoshikawa S. J . Solid State Chemistry , 2007 , 180 :3425 —3433
[38 ] 　Onoda K, Yoshikawa S. Ceramics International , 2008 , 34 : 1453 —1457
[39 ] 　Oh H J , Lee J H , Kimc Y J . Materials Chemistry and Physics ,2008 , 109 (1) : 10 —14
[40 ] 　Aggour M, Dittrich T, Belaidi A , et al . Phys. Stat . Sol . , 2005 , 2 (9) : 3344 —3348
[41 ] 　Crawford GA , Chawla N , Das K, et al . Acta Biomaterialia , 2007 ,3 : 359 —367
[42 ] 　Paramasivam I , Macak J M, Ghicov A , et al . Chemical Physics Letters , 2007 , 445 (4P6) : 233 —237
[43 ] 　Tsuchiya H , Macak J M, Muller L , et al . J . Biomed. Mater. Res. ,2006 , 77A: 534 —541
[44 ] 　Vitiello R P , Macak J M, Ghicov A , et al . Electrochem. Commun. ,2006 , 8 : 544 —548
[45 ] 　Macak J M, Tsuchiya H , Berger S , et al . Chemical Physics Letters ,2006 , 428 : 421 —425
[46 ] 　Macak J M, Barczuk P J , Tsuchiya H , et al . Electrochem.Commun. , 2005 , 7 : 1417 —1422
[47 ] 　Tsuchiya H , Macak J M, Ghicov A , et al . Corrosion Science , 2005 ,47 : 3324 —3335
[48 ] 　Macak J M, Stein F S , Schmuki P. Electrochem. Commun. , 2007 ,9 : 1783 —1787
[49 ] 　Park Y J , Shin K H , Song H J . Applied Surface Science , 2007 ,253 : 6013 —6018
[50 ] 　Das K, Bose S , Bandyopadhyay A. Acta Biomaterialia , 2007 , 3 :573 —585
[51 ] 　Baea S , Shimb E , Yoon J . Solar Energy Materials & Solar Cells ,2008 , 92 : 402 —409
[52 ] 　Raja K S , Mahajan V K, Misra M. J . Power Sources , 2006 , 159 :1258 —1265
[53 ] 　Raja K S , Misra M, Mahajan V K. J . Power Sources , 2006 , 161 :1450 —1457
[54 ] 　Bauer S , Kleber S , Schmuki P. Electrochem. Commun. , 2006 , 8 :1321 —1325
[55 ] 　Ghicov A , Tsuchiya H , Macak J M. Electrochem. Commun. , 2005 ,7 : 505 —509
[56 ] 　Yang Y, Wang X H , Li L T. Materials Science and Engineering B ,2008 , 149 (1) : 58 —62
[57 ] 　Kang S H , Kim. Y, Kim H S. J . Industrial and Engineering Chemistry , 2008 , 14 : 52 —59
[58 ] 　Mato S , Alcal G, Skeldon P , Thompson G E. Surf . Interface Anal . ,2003 , 35 : 477 —482
[59 ] 　Habazaki H , Uozumi M, Konno H , et al . Electrochim. Acta , 2003 ,48 : 3257 —3266
[60 ] 　Ruan C , Paulose M, Varghese O K. Solar Energy Materials & Solar Cells , 2006 , 90 : 1283 —1295
[61 ] 　Si H Y, Sun Z H , Zhang H L. Colloids and Surfaces A:Physicochem. Eng. Aspects , 2008 , 313P314 : 604 —607
[62 ] 　Balasundaram G, Yao C , Webster T J . J . Biomed Mater. Res. ,2008 , 84A: 447 —453
[63 ] 　Oh S , Daraio C , Chen L H. J . Biomed Mater. Res. , 2006 , 78A:97 —103
[64 ] 　Zhang Z H , Yuan Y, Fa Y. J . Electroanal . Chem. , 2007 , 610 :179 —185
[65 ] 　Arakelyan V M, Aroutiounian V M, Shahnazaryan G E , et al .Renewable Energy , 2008 , 33 : 299 —303
[66 ] 　Chen X B , Schriver M, Suen T. Thin Solid Films , 2007 , 515 :8511 —8514
[67 ] 　Hahn R , Macak J M, Schmuki P. Electrochem. Commun. , 2007 ,9 : 947 —952
[68 ] 　Zwilling V , Ceretti E D , Forveille A B. Surf . Interface Anal . ,1999 , 27 : 629 —637
[69 ] 　Zwilling V , Aucouturier M, Ceretti E D. Electrochim. Acta , 1999 ,45 : 921 —925
[70 ] 　Chenga F T, Shia P G, Pang K H , et al . J . Alloys and Compounds ,2007 , 438 : 238 —242
[71 ] 　Tsuchiya H , Macak J M, Taveira L , et al . Electrochem. Commun. ,2005 , 7 : 576 —580
[72 ] 　Su Y, Zhang X W, Han S , et al . Electrochem. Commun. , 2007 ,9 : 2291 —2298
[73 ] 　Su YL , Zhang XW, Zhou M H. J . Photochemistry and Photobiology A: Chemistry , 2007 , 185 (2P3) : 338 —344
[74 ] 　Lei L , Su YL , Zhou M H. Materials Research Bulletin , 2007 , 42 :2230 —2236
[75 ] 　Zhang H , Zhao H J , Zhang S. Chem. Phys. , 2008 , 9 : 117 —123
[76 ] 　Mohapatra S K, Raja K S , Misra M, et al . Electrochimica Acta ,2007 , 53 : 590 —597
[77 ] 　Zhang G, Huang H T, Zhang Y, Electrochem. Commun. , 2007 , 9 :2854 —2858
[78 ] 　Raja K S , Gandhi T, Misra M. Electrochem. Commun. , 2007 , 9 :1069 —1076
[79 ] 　Yang D J , Kim H G, Cho S J , et al . Materials Letters , 2008 , 62 :775 —779
[80 ] 　Macak J M, Albu S P , Schmuki P. Phys. Stat . sol . , 2007 , 1 (5) :181 —183
[81 ] 　Zlamal M, Macak J M, Schmuki P. Electrochem. Commun. , 2007 ,9 : 2822 —2826
[82 ] 　Tsuchiya H , Berger S , Macak J M, et al . Electrochem. Commun. ,2007 , 9 : 545 —550
[83 ] 　Macak J M, Tsuchiya H , Ghicov A. Electrochem. Commun. , 2005 ,7 : 1133 —1137
[84 ] 　Hahn R , Stergiopoulus T, Macak J M. Phys. Stat . Sol . , 2007 , 1 (4) : 135 —137
[85 ] 　Yu X F , Li YX, Wlodarski W. Sensors and Actuators B , 2007 , 127 (1) : 168 —178
[86 ] 　Cai Q Y, Yang L X, Yu Y. Thin Solid Films , 2006 , 515 : 1802 —1806
[87 ] 　Macak J M, Hildebrand H , Jahns U M. J . Electroanalytical Chemistry , 2008 , 621 (2) : 254 —266
[88 ] 　Tsuchiya H , Macaka J M, Ghicov A. Electrochim. Acta , 2006 , 52 :94 —101
[89 ] 　Ghicov A , Macak J M, Tsuchiya H , et al . Chem. Phy. Lett . ,2006 , 419 : 426 —429
[90 ] 　Ghicov A , Tsuchiya H , Hahn R , et al . Electrochem. Commun. ,2006 , 8 : 528 —532
[91 ] 　Macak J M, Schmuki P. Electrochim. Acta , 2006 , 52 : 1258 —1264
[92 ] 　Macak J M, Sirotnal K, Schmuki P. Electrochim. Acta , 2005 , 50 :3679 —3684
[93 ] 　Fini M, Cigada A , Rondelli G, et al . Biomaterials , 1999 , 20 :1587 —1594
[94 ] 　Chenga F T, Shia T P , Man H C. Mater. Lett . , 2005 , 59 : 1516 —1520
[95 ] 　Habazaki H , Oikawa Y, Fushimi K, et al . Electrochim. Acta ,2007 , 53 : 1775 —1781
[96 ] 　Paramasivam I , Macak J M, Schmuki P , Electrochem. Commun. ,2008 , 10 : 71 —75
[97 ] 　Macak J M, Aldabergerova S , Ghicov A. Phys. Stat . Sol . , 2006 ,203 (10) : R67 —R69
[98 ] 　Albu S P , Ghicov A , Macak J M, et al . Phys. Stat . Sol . , 2007 , 1 (2) : R65 —R67
[99 ] 　Huang H H , Pan S J , Lai Y L , et al . Scripta Materialia , 2004 , 51 :1017 —1021
[100 ]  Eswaramoorthi I , Hwang L P. Diamond & Related Materials , 2007 ,16 : 1571 —1578
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摘要

阳极氧化法制备TiO2多孔薄膜*