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化学进展 2008, Vol. 20 Issue (12): 2083-2092 前一篇   

• 综述与评论 •

直接甲醇燃料电池的交流阻抗谱分析*

齐亮 谢晓峰** 金宝舵 郭建伟 徐景明   

  1. ( 清华大学核能与新能源技术研究院 北京 100084)

  • 收稿日期:2008-01-10 修回日期:1900-01-01 出版日期:2008-12-24 发布日期:2008-12-25
  • 通讯作者: 谢晓峰
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AC Impedance Spectroscopy in DMFC diagnosis

Qi Liang; Xie Xiaofeng**; Jin Baoduo; Guo Jianwei; Xu Jingming

  

  1. (Institute of Nuclear and New Energy Technology, Beijing 100084, China)
  • Received:2008-01-10 Revised:1900-01-01 Online:2008-12-24 Published:2008-12-25
  • Contact: Xie Xiaofeng
由于能够提供比直流测试方法更为丰富的信息，交流阻抗图谱近些年被广泛的用于直接甲醇燃料电池的研究中。同PEMFC相比，直接甲醇燃料电池具有更为复杂的电极体系。本文通过对交流阻抗技术在直接甲醇燃料电池领域应用的几个关键技术问题的分析，并按照阻抗分析过程的具体的实施步骤加以组织，结合具体的应用实例以阐述交流阻抗谱在直接甲醇燃料电池的各个应用方面，包括电池的原位极化分析，反应机理的剖析，材料性能评估等。
关键词： 直接甲醇燃料电池, 电化学阻抗谱, 交流阻抗谱, 等效电路, 参比电极
Because the AC impedance spectroscopy, also called as electrochemical impedance spectroscopy(EIS), can provide more detailed information than other impedance measurement methods, it becomes the most popular method for the research on the fuel cell and is being used widely in the fuel cell research field recently. The paper mainly deals with the all aspects of application in DMFC field including in-situ polarization analyst, reaction mechanism details, material performance evaluation, etc. Several key technical problems about EIS including electrochemical system establishment, the reference electrode selection, the equivalent-circuits model for analysis for spectroscopy are discussed.
Key words: direct methanol fuel cells(DMFC), electrochemical impedance spectroscopy(EIS), AC impedance spectroscopy, equivalent circuit model spectroscopy, reference electrode

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