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化学进展 2008, Vol. 20 Issue (12): 1972-1979 前一篇   后一篇

• 综述与评论 •

连接子化学在聚合物-缀合物中的应用*

闫强 袁金颖** 康燕 袁伟忠   

  1. （清华大学化学系 有机光电子与分子工程教育部重点实验室 北京100084）

  • 收稿日期:2008-03-26 修回日期:2008-05-08 出版日期:2008-12-24 发布日期:2008-12-25
  • 通讯作者: 袁金颖
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Application of Linkage Chemistry in Polymer-Conjugation System

Yan Qiang; Yuan Jinying**; Kang Yan; Yuan Weizhong

  

  1. (Key Lab of Organic Optoelectronic and Molecular Engineer of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China)
  • Received:2008-03-26 Revised:2008-05-08 Online:2008-12-24 Published:2008-12-25
  • Contact: Yuan Jinying
聚合物的缀合物化学近年来发展迅速，其反应产物既具有聚合物良好的稳定性、力学性能与特殊的结构形貌特点，亦因缀合各种分子而体现出完全不同的物理化学特性与独特的功能性。连接子化学是一类新型的具有高活性、高产率、高选择性的化学反应，对官能团位点敏感程度极高，对于聚合物与缀合分子的连接非常适合，适用于多种不同分子的缀合。本文旨在结合一些近年来具创新性的研究成果，介绍并总结连接子化学在聚合物缀合物中的应用进展，并对其广泛的前景进行合理的展望。
关键词： 连接子化学, 功能聚合物, 功能缀合分子, 聚合物-缀合物体系
The study on polymer-conjugation chemistry developed so rapidly in recent years, since the product of polymer-conjugation not only possesses stability, mechanical property and special structure or morphology character for the polymer, but also presents different physical-chemical properties and extraordinary functionalization. Linkage chemistry is a kind of novel chemical reaction, which possesses high activity, high yield, high selectivity and sensitive on the specifically groups, fit for the link or ligation of the polymer and connect with molecules. Further more, this review also combines with the later scientific literatures to introduce and summarize the development of polymer-conjugation, and rationally expects the foreground of their application.
Key words: linkage chemistry, functional polymers, functional conjugated molecules, polymer-conjugate system

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