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化学进展 2008, Vol. 20 Issue (12): 1868-1879 前一篇   后一篇

• 综述与评论 •

阳极氧化TiO2纳米管阵列的制备与掺杂*

管东升1 方海涛1** 逯好峰2 孙涛1 李峰2 刘敏2

  

  1. （1. 哈尔滨工业大学材料科学与工程学院 哈尔滨150001；
    2. 中国科学院金属研究所 沈阳材料科学国家（联合）实验室 沈阳110016）

  • 收稿日期:2008-04-21 修回日期:2008-07-19 出版日期:2008-12-24 发布日期:2008-12-25
  • 通讯作者: 方海涛
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Preparation and Doping of Anodic TiO2 Nanotube Array

Guan Dongsheng1 Fang Haitao1** Lu Haofeng2 Sun Tao1 Li Feng2 Liu Min2

  

  1. (1.School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China; 2. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China)

  • Received:2008-04-21 Revised:2008-07-19 Online:2008-12-24 Published:2008-12-25
  • Contact: Fang Haitao
近年来，TiO2纳米管阵列的制备与应用得到了广泛的研究。阳极氧化法制备TiO2纳米管阵列具有工艺简单、成本低廉、易于放大等优点，引起了极大关注。本文综述了阳极氧化法制备TiO2纳米管阵列的研究现状，基于TiO2纳米管阵列在阳极氧化过程中的生长机理，讨论了决定阳极氧化TiO2纳米管阵列形成的主要因素。结合本组的研究工作，总结了如何通过改变电压、升压速率、电解液、温度和氧化时间，实现纳米管管径、管壁厚度、管长的有效控制，提高TiO2纳米管阵列的表面形貌质量。最后介绍了TiO2纳米管阵列掺杂改性方面的研究进展。
关键词： 阳极氧化, TiO2纳米管, 掺杂
The preparation and application of TiO2 nanotube array are widely investigated in recent years. Anodic oxidation adopted to prepare TiO2 nanotube array has attracted intensive attention due to its simplicity, low cost and easy industrialization. The preparation of TiO2 nanotube array by anodic oxidation is reviewed in this paper. Key factors affecting the formation of anodic TiO2 nanotube array are discussed based on the formation mechanism of anodic TiO2 nanotube array. In combination with the results of our research group, how to adjust tube diameter, tube length, wall thickness, and improve the quality of surface morphology of anodic TiO2 nanotube array by changing voltage, potential sweep rate, electrolyte, temperature and oxidation time is summarized. Finally, the development on the doping of anodic TiO2 nanotube array is presented.
Key words:

anodic oxidation, TiO2 nanotube, doping

中图分类号: 

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