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化学进展 2008, Vol. 20 Issue (11): 1694-1698 前一篇   后一篇

• 综述与评论 •

环糊精在绿色有机合成中的应用

孙宏元 郝爱友 尹明静 张华承 申健   

  1. 山东大学化学与化工学院 山东大学化学与化工学院 山东大学 山东大学化学与化工学院
  • 收稿日期:2008-01-21 修回日期:2008-03-05 出版日期:2008-11-24 发布日期:2008-11-25
  • 通讯作者: 郝爱友

The Application of Cyclodextrins in Greeen Organic Synthesis

Ai-You Hao Zhang Hua-Cheng Jian Shen   

  • Received:2008-01-21 Revised:2008-03-05 Online:2008-11-24 Published:2008-11-25
  • Contact: Ai-You Hao
环糊精通过主客体相互作用能将疏水性有机分子转移到对环境友好的水中进行有机反应,还能影响分子的电性环境,使反应在温和的条件下就能获得良好的收率,几乎没有副产物,在绿色有机合成中应用十分广泛。本文就近年来环糊精在绿色有机合成中的应用现状分为氧化、加成、开环、脱保护、偶联和取代等几个反应类型作以简要概述。
Cyclodextrins, widely applied in green organic synthesis, could transfer hydrophobic molecules into water by the supramolecular interaction. As an important kind of host molecules, they could also influence the microenviroment of hydrophobic molecules by the host-guest interaction and change traditional reaction conditions to obtain good yield without byproduct. The recent developments of appliacation of cycodextrins in green organic reactions such as oxidation reaction, addition reaction, ring opening reaction, deprotection reaction, coupling reaction, substitution reaction, et al were reviewed. The catalytic mechanisms were also discussed in this manuscript.

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摘要

环糊精在绿色有机合成中的应用