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化学进展 2008, Vol. 20 Issue (10): 1524-1533 前一篇   后一篇

• 综述与评论 •

以芳胺为电子给体的D-π-A有机光敏染料---- 染料敏化太阳电池中的应用*

宋晓睿1,2 王雪松1** 张宝文1**

  

  1. （1. 中国科学院理化技术研究所 北京100080; 2. 中国科学院研究生院 北京 100039)
  • 收稿日期:2008-01-21 修回日期:2008-02-25 出版日期:2008-10-24 发布日期:2008-10-25
  • 通讯作者: 王雪松
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D-π-A Type Organic Photosensitizers with Aromatic Amine as Electron-Donating Group---- Application in Dye-Sensitized Solar Cells

Song Xiaorui1,2 Wang Xuesong1** Zhang Baowen1**

  

  1. (1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, China; 2. Graduate University of Chinese Academy of Sciences, Beijing 100039, China)
  • Received:2008-01-21 Revised:2008-02-25 Online:2008-10-24 Published:2008-10-25
  • Contact: Wang Xuesong
不含金属的有机染料在染料敏化太阳电池（DSC）中的应用愈加广泛，以芳胺为电子给体的D-π-A分子是其中重要的一类。本文依据芳香胺的结构，将近5年来应用于DSC中一百多个D-π-A分子分成四类，包括：基于N-烷基-苯胺的D-π-A光敏染料，基于三苯胺的D-π-A光敏染料，由包含芴基团的三芳胺构建的D-π-A光敏染料，包含芳胺基团的其它结构类型的D-π-A光敏染料。评述了它们的光电转换性能。
关键词： 染料敏化太阳电池, 有机光敏染料, D-π-A分子, 芳香胺
Metal-free organic photosensitizers were widely used in dye-sensitized solar cells (DSCs), of which D-π-A molecules with aromatic amine as electron donor (D) represent one of the most important types. On the basis of the structures of the aromatic amine moiety, more than 100 D-π-A type organic photosensitizers utilized in DSCs over the past five years were classified into 4 categories, including D-π-A dyes based on N-alkyl-aniline, D-π-A dyes based on triphenylamine, D-π-A dyes based on fluorene-containing triphenylamine, and other types of aromatic amine-containing D-π-A dyes, and their photoelectric conversion properties are reviewed.
Key words: dye-sensitized solar cells(DSCs), organic photosensitizer, D-π-A molecule, aromatic amine

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