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化学进展 2008, Vol. 20 Issue (10): 1474-1486 前一篇   后一篇

• 综述与评论 •

甘油的催化选择氧化*

李明燕1 周春晖1** Jorge N Beltramini2 俞卫华1 范永仙1   

  1. （1.浙江工业大学化工与材料学院 杭州 310032; 2. 昆士兰大学化工系 澳大利亚国家功能纳米材料中心　布里斯班 4072）

  • 收稿日期:2007-11-12 修回日期:2007-12-18 出版日期:2008-10-24 发布日期:2008-10-25
  • 通讯作者: 周春晖
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Catalytical Selective Oxidation of Glycerol

Li Mingyan1 Zhou Chunhui1** Jorge N Beltramini2 Yu Weihua1 Fan Yongxian1   

  1. (1.College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China; 2. ARC Centre of Excellence for Functional Nanomaterials, The Australian Institute for Bioengineering and Nanotechnology and School of Engineering, The University of Queensland, St. Lucia, QLD 4072, Australia)

  • Received:2007-11-12 Revised:2007-12-18 Online:2008-10-24 Published:2008-10-25
  • Contact: Zhou Chunhui
综述了近年来生物柴油主要副产物甘油的催化选择氧化的研究进展。分析了甘油的化学催化选择氧化的反应网络；介绍了催化甘油选择氧化反应主要的催化剂如负载型金属催化剂、多孔催化剂以及有机酰基-TEMPO催化剂的催化性能及其催化机理；评述了甘油催化氧化过程中各反应条件等对产物选择性和反应物转化率的影响；概括了甘油的电催化氧化、甘油催化氧化聚合生成新型聚合物-聚丙酮二酸盐（Polyketomalonate）等新催化反应及其机理，总结了甘油生物催化氧化的产物二羟基丙酮（DHA）的新进展。最后提出了甘油的催化氧化存在的一些问题，并展望了甘油催化氧化的研究和发展方向。
关键词： 甘油, 催化选择氧化, 电催化氧化, 氧化聚合, 生物氧化, 聚丙酮酸盐, 二羟基丙酮
With the rapid development of biodiesel worldwide, the amount of glycerol, as by-product of biodiesel processes, is increasing so greatly that the effective utilization of glycerol becomes a challenging topic with great significance. Here the recent progress of research and development on the catalytic selective oxidation of glycerol, are specifically reviewed. The reaction networks of catalytic oxidation of glycerol, and related products and their potential applications are summarized. Especially, the catalysts and catalytic mechanism during the process of chemoselective catalytic oxidation of the glycerol are discussed The influence of different catalysts, supported noble or non-noble metal catalysts, porous oxides, and reaction conditions on selectivity, conversion during the oxidation processes of glycerol are summarized and remarked, together with the discussion of catalytic mechanism. The present situation of electrocatalytic selective oxidation of glycerol and novel oxidation-assisted polymerization of glycerol to Polyketomalonate and related catalytic mechanism are introduced. The recent progress of research and process development on production of dihydroxyacetone (DHA) by biocatalytic oxidation of glycerol is summarized. The pending problems and the prospects in the catalytic oxidation of glycerol are stated.
Key words: glycerol, catalytically selective oxidation, electrocatalytic oxidation, oxidation-assisted polymerization, biocatalytic oxidation, polyketomalonate, dihydroxyacetone

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甘油的催化选择氧化*