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化学进展 2008, Vol. 20 Issue (0708): 1128-1135 前一篇   后一篇

• 综述与评论 •

新型链转移剂黄原酸酯调控的RAFT自由基聚合*

蒋波1 易玲敏1,2** 詹晓力1** 陈碧1 陈丰秋1   

  1. (1. 浙江大学化学工程与生物工程学系 杭州 310027；
    2. 浙江理工大学先进纺织材料与制备技术教育部重点实验室 杭州 310018）
  • 收稿日期:2007-09-30 修回日期:2007-12-16 出版日期:2008-08-24 发布日期:2008-08-24
  • 通讯作者: 詹晓力
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Reversible Addition Fragmentation Chain Transfer Polymerization Mediated by Xanthate

Jiang Bo1 Yi Lingmin1,2** Zhan Xiaoli1** Chen Bi1 Chen Fengqiu1   

  1. (1. Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou, 310027, China; 2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China)
  • Received:2007-09-30 Revised:2007-12-16 Online:2008-08-24 Published:2008-08-24
  • Contact: Zhan Xiaoli
本文综述了以黄原酸酯为链转移剂进行的共轭乙烯基单体与非共轭乙烯基单体的RAFT自由基聚合研究进展。由于黄原酸酯的Z基团为烷氧基，它使得黄原酸酯自由基中心电荷密度增加，通过共轭效应稳定双硫酯产物，因此可以很好地调控非共轭乙烯基单体的活性自由基聚合。在黄原酸酯的Z基团中引入氟原子后，它通过降低加成自由基的稳定性而不是通过稳定双硫酯产物来促进随后的断裂，可以用于共轭乙烯基单体的活性自由基聚合，用含氟的黄原酸酯化合物还可以制备共轭乙烯基单体与非共轭乙烯基单体的嵌段共聚物。
关键词： 黄原酸酯, 可逆加成断裂链转移, 醋酸乙烯酯, 苯乙烯
The RAFT radical polymerization of non-conjugated vinyl monomers and conjugated vinyl monomers mediated by xanthate are reviewed in this paper. Because the alkyloxy in xanthate (Z group) increases the electron density on central carbon atom of xanthate and stabilizes the fragmentation product, the RAFT radical polymerization of non-conjugated vinyl monomers mediated by xanthate could proceed in a living way. Introducing fluorin atom into Z group of xanthate improves fragmentation of intermedia by decreasing the stabilization of intermedia, instead of stabilizing the fragmentation product. Mediated by this kind of xanthate, conjugated vinyl monomers could be polymerized in a living radical way. Moreover, block copolymers comprised of non-conjugated vinyl monomer and conjugated vinyl monomer can be prepared by fluorinated xanthate.
Key words: xanthate, reversible addition fragmentation chain transfer(RAFT), vinyl acetate, styrene

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