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化学进展 2008, Vol. 20 Issue (0708): 1122-1127 前一篇   后一篇

• 综述与评论 •

无机纳米材料表面引发自由基可控聚合反应*

隋晓锋 袁金颖** 袁伟忠 周密   

  1. （清华大学化学系有机光电子与分子工程教育部重点实验室 北京 100084）
  • 收稿日期:2007-08-28 修回日期:2007-09-27 出版日期:2008-08-24 发布日期:2008-08-24
  • 通讯作者: 袁金颖
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Surface-Initiated Living Radical Polymerization from Inorganic Nanomaterials

Sui Xiaofeng Yuan Jinying** Yuan Weizhong Zhou Mi   

  1. （Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China）
  • Received:2007-08-28 Revised:2007-09-27 Online:2008-08-24 Published:2008-08-24
  • Contact: Yuan Jinying
无机纳米-高分子杂化材料具有优异的性能及广阔的应用前景，引起人们的广泛关注。文本综述了无机纳米材料表面引发自由基可控聚合反应在合成无机-高分子杂化材料方面的广泛应用，包括表面引发原子转移自由基聚合（ATRP）、表面引发可逆加成-断裂链转移自由基聚合（RAFT）、表面引发稳定氮氧自由基聚合（NMP）。着重总结了近年来这类杂化材料在功能性研究上新的进展，并对今后研究的发展趋势进行了展望。
关键词： 无机纳米材料, 表面引发聚合, 引发体系

The inorganic-polymer hybrid nanomaterials have many excellent properties. So they are becoming increasingly important for various applications ranging from biomaterials to semiconductors in many fields and arouse much interest of scientists all over the world. This review highlights the development of surface-initiated living radical polymerizations from the inorganic materials including surface-initiated atom transfer radical polymerization(ATRP), surface-initiated addition-fragmentation chain transfer radical polymerization(RAFT), surface-initiated nitroxide-medicated polymerization(NMP) in thr preparation of inorganic-polymer hybrid nanomaterials. The emphasis is put upon the new developments of various approaches taken to prepare hybrid nanomaterials in the recent years. Also, new research trends are pointed out.

Key words: inorganic nanomaterials, surface initiated polymerization, initiation systems

中图分类号: 

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[ 1 ] Roduner E. Chem. Soc. Rev. , 2006 , 35 : 583 —592
[ 2 ] Descalzo A B , Martinez-Manez R , Sancenon R , et al . Angew.Chem. Int . Ed. , 2006 , 45 : 5924 —5948
[ 3 ] Braunecker W A , Matyjaszewski K. Prog. Polym. Sci . , 2007 ,32 : 93 —146
[ 4 ] 陈小平(Chen X P) , 丘坤元(Qiu K Y) . 化学进展(Progress in Chemistry) , 2001 , 13 : 224 —233
[ 5 ] Pyun J , Matyjaszewski K. Chem. Mat . , 2001 , 13 : 3436 —3448
[ 6 ] 倪刚(Ni G) , 杨武(Yang W) , 何晓燕(He X Y) 等. 化学进展(Progress in Chemistry) , 2005 , 17 : 1074 —1080
[ 7 ] Tsujii Y, Ohno K, Yamamoto S , et al . Adv. Polym. Sci . ,2006 , 197 : 1 —45
[ 8 ] Wang J S , Matyjaszewski K. J . Am. Chem. Soc. , 1995 , 117 :5614 —5615
[ 9 ] Tsarevsky N V , Matyjaszewski K. Chem. Rev. , 2007 , 107 :2270 —2299
[10] Pyun J , Kowalewski T , Matyjaszewski K. Macromol . Rapid.Commun. , 2003 , 24 : 1043 —1059
[11] Ejaz M, Yamamoto S , Ohno K, et al . Macromolecules , 1998 ,31 : 5934 —5936
[12] Von Werne T , Patten T E. J . Am. Chem. Soc. , 1999 , 121 :7409 —7410
[13] Pyun J , Matyjaszewski K, Kowalewski T , et al . J . Am. Chem.Soc. , 2001 , 123 : 9445 —9446
[14] Mandal T K, Fleming M S , Walt D R. Nano Lett . , 2002 , 2 :3 —7
[15] Pyun J , Jia S J , Kowalewski T , et al . Macromolecules , 2003 ,36 : 5094 —5104
[16] Szleifer I , Yerushalmi-Rozen R. Polymer , 2005 , 46 : 7803 —7818
[17] Tasis D , Tagmatarchis N , Bianco A , et al . Chem. Rev. , 2006 ,106 : 1105 —1136
[18] Gao C , Muthukrishnan S , Li W W, et al . Macromolecules ,2007 , 40 (6) : 1803 —1815
[19] Morinaga T , Ohkura M, Ohno K, et al . Macromolecules , 2007 ,40 : 1159 —1164
[20] Shanmugharaj A M, Bae J H , Nayak R R , et al . J . Polym.Sci . , Part A: Polym. Chem. , 2007 , 45 : 460 —470
[21] 王国建(Wang G J) , 屈泽华(Qu Z H) . 化学进展(Progress in Chemistry) , 2006 , 18 : 1305 —1312
[22] Gao C , Li W W, Morimoto H , et al . J . Phys. Chem. B , 2006 ,110 : 7213 —7220
[23] Narain R , Housni A , Lane L. J . Polym. Sci . , Part A: Polym.Chem. , 2006 , 44 : 6558 —6568
[24] Xing X Y, Zheng K B , Xu H H , et al . Micron , 2006 , 37 :370 —373
[25] Rupert B L , Mulvihill M J , Arnold J . Chem. Mater. , 2006 , 18 :5045 —5051
[26] Cai Q J , Fu G D , Zhu F R , et al . Angew. Chem. Int . Ed. ,2005 , 44 : 1104 —1107
[27] Zhou M, Yuan J Y, Yuan W Z , et al . Nanotechnology , 2007 ,18 , 405704
[28] Jin Y Z , Gao C , Kroto H W, et al . Macromol . Rapid.Commun. , 2005 , 26 : 1133 —1139
[29] Liu T Q , Jia S J , Kowalewski T , et al . Macromolecules , 2006 ,39 : 548 —556
[30] Liu T Q , Casado-Portilla R , Belmont J , et al . J . Polym. Sci . ,Part A: Polym. Chem. , 2005 , 43 : 4695 —4709
[31] Li L , Davidson J L , Lukehart C M. Carbon , 2006 , 44 : 2308 —2315
[32] Radhakrishnan B , Ranjan R , Brittain W J . Soft Matter. , 2006 ,2 : 386 —396
[33] Nystrêm D , Antoni P , Malmstrêm E. et al . Macromol . Rapid Commun. , 2005 , 26 : 524 —528
[34] Morinaga T , Ohkura M, Ohno K, et al . Macromolecules , 2007 ,40 : 1159 —1164
[35] Zhou L L , Yuan W Z , Yuan J Y, et al . Mater. Lett . , 2008 , 62 :1372 —1375
[36] Lattuada M, Hatton T A. Langmuir , 2007 , 23 : 2158 —2168
[37] Lu A H , Salabas E L , Schuth F. Angew. Chem. Int . Ed. ,2007 , 46 : 1222 —1244
[38] Marutani E , Yamamoto S , Ninjbadgar T , et al . Polymer , 2004 ,45 : 2231 —2235
[39] Sun Y B , Ding X B , Zheng Z H , et al . Eur. Polym. J . , 2007 ,43 : 762 —772
[40] Garcia I , Zafeiropoulos N E , Janke A , et al . J . Polym. Sci . ,Part A: Polym. Chem. , 2007 , 45 : 925 —932
[41] Gelbrich T , Feyen M, Schmidt A M. Macromolecules , 2006 , 39 :3469 —3472
[42] Bai Y P , Teng B , Chen S H , et al . Macromol . Rapid Commun. ,2006 , 27 : 2107 —2112
[43] Ninjbadgar T , Yamamoto S , Fukuda T. Solid State Sci . , 2004 ,6 : 879 —885
[44] Wang Y, Teng X W, Wang J S , et al . Nano Lett . , 2003 , 3 :789 —793
[45] Gravano S M, Dumas R , Liu K, et al . J . Polym. Sci . , Part A:Polym. Chem. , 2005 , 43 : 3675 —3688
[46] Eustis S , El-Sayed M A. Chem. Soc. Rev. , 2006 , 35 : 209 —217
[47] Kim D J , Kang S M, Kong B , et al . Macromol . Chem. Phys. ,2005 , 206 : 1941 —1946
[48] Li D X, He Q , Cui Y, et al . Chem. Mater. , 2007 , 19 : 412 —417
[49] Lou X H , Wang C Y, He L. Biomacromolecules , 2007 , 8 :1385 —1390
[50] Li D X, He Q , Cui Y, et al . Chem. Eur. J . , 2007 , 13 :2224 —2229
[51] Kotal A , Mandal T K, Walt D R. J . Polym. Sci . , Part A:Polym. Chem. , 2005 , 43 : 3631 —3642
[52] Duan H W, Kuang M, Wang D Y, et al . Angew. Chem. Int .Ed. , 2005 , 44 : 1717 —1720
[53] Chiefari J , Chong Y K, Ercole F , et al . Macromolecules , 1998 ,31 : 5559 —5562
[54] Moad G, Rizzardo E , Thang S H. Aust . J . Chem. , 2006 , 59 :669 —692
[55] Hong C Y, You Y Z , Pan C Y. Macromol . Rapid Commun. ,2006 , 27 : 2001 —2006
[56] Hong C Y, You YZ , Pan C Y. J . Polym. Sci . , Part A: Polym.Chem. , 2006 , 44 : 2419 —2427
[57] Hong C Y, You Y Z , Pan C Y. Chem. Mater. , 2005 , 17 :2247 —2254
[58] Hong C Y, You Y Z , Wu D C , et al . Macromolecules , 2005 ,38 : 2606 —2611
[59] Zhang B Q , Pan C Y, Hong C Y, et al . Macromol . Rapid Commun. , 2006 , 27 : 97 —102
[60] Li C Z , Benicewicz B C. Macromolecules , 2005 , 38 : 5929 —5936
[61] Wang W C , Neoh K G, Kang E T. Macromol . Rapid Commun. ,2006 , 27 , 1665 —1669
[62] Georges M K, Veregin R P N , Kazmaier P M, et al .Macromolecules , 1993 , 26 : 2987 —2988
[63] Ghannam L , Parvole J , Laruelle G, et al . Polym. Int . , 2006 ,55 : 1199 —1207
[64] Zhao X D , Fan X H , Chen X F , et al . J . Polym. Sci . Pol .Chem. , 2006 , 44 : 4656 —4667
[65] Zhao X D , Lin W R , Song N H , et al . J . Mater. Chem. , 2006 ,16 : 4619 —4625
[66] Ilhanli O B , Erdogan T , Tunca U , et al . J . Polym. Sci . Pol .Chem. , 2006 , 44 : 3374 —3381
[67] Dehonor M, Varlot-Masenelli K, Gonzalez-Montiel A , et al .Chem. Commun. , 2005 , 5349 —5351
[68] Sill K, Emrick T. Chem. Mater. , 2004 , 16 : 1240 —1243
[69] Matsuno R , Yamamoto K, Otsuka H , et al . Macromolecules ,2004 , 37 : 2203 —2209
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