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化学进展 2008, Vol. 20 Issue (0708): 1102-1107 前一篇   后一篇

• 综述与评论 •

硫代氨基甲酸酯合成方法进展*

张晓鹏1,2 荆唤芝1 苗江欢1 陆世维2**   

  1. (1.河南师范大学化学与环境科学学院 新乡453007;
    2.中国科学院大连化学物理研究所国家催化工程技术研究中心 大连116011)
  • 收稿日期:2007-09-30 修回日期:2007-11-30 出版日期:2008-08-24 发布日期:2008-08-24
  • 通讯作者: 陆世维

Advances in the Synthesis of Thiocarbamates

Zhang Xiaopeng1,2 Jing Huanzhi1 Miao Jianghuan1 Lu Shiwei2**   

  1. (1.College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China; 2. National Engineering Research Center for Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116011, China)
  • Received:2007-09-30 Revised:2007-11-30 Online:2008-08-24 Published:2008-08-24
  • Contact: Lu Shiwei
硫代氨基甲酸酯是一类分子内含有多种官能团的化合物,大多数具有生物活性,在医学 、生物 、农药等方面有广泛的应用。本文总结了合成硫代氨基甲酸酯的几种主要方法,如水解醇解法、重排反应、光气衍生物法、羰基化法等,并分析了各种方法的利弊。指出利用一氧化碳进行硒催化的硫醇与硝基化合物或苯胺的羰基化反应来合成硫代氨基甲酸酯的方法是一种比较有应用前景的方法。该方法具有环境友好、原子经济性高、步骤简短等优点,并对其做了比较详细的介绍。
Thiocarbamates, a type of compounds containing many functional groups and possessing bioactivity, have been widely applied in medicine, biology and agricultural chemicals. In this paper, the main methods to thiocarbamates such as hydrolysis or alcoholysis of thiocyanate, rearrangement reaction, phosgene derivatives method and carbonylation of nitro compounds or amines are summarized. Their advantages and disadvantages are also compared. It is pointed out that selenium-catalyzed carbonylation of nitro compounds or amines with thiols to thiocarbamates is a promising method which is characterized by benign environment, high atomic economy and “one-pot” approach.

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摘要

硫代氨基甲酸酯合成方法进展*